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生活垃圾和农业秸秆共热解及液体产物分离研究
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摘要
生活垃圾热解液因含氧较高、含水量高、热值较低等问题,直接作为燃料尚存一定的困难。生活垃圾热解气主要是H2、CO、CH4和CO2等气体,但可燃成分含量较低。基于上述认识,本文主要研究:催化剂对热解油脱氧的影响;添加农业秸秆对生活垃圾热解中能量及产物性质的影响;研究热解液的性质和组成,并采用分级萃取方式对热解液进行油水分离。研究结果表明:催化剂有助于热解油脱氧及热值的提高,生活垃圾热解中添加1wt%的Na2CO3,热解油的含氧量由22.49wt%降低为20.11wt%,热值提高了1.64MJ/kg;在一定的混合比下,生活垃圾和农业秸秆共热解可提高液气产物产率及热值,增加热解过程的能量输出,生活垃圾热解中添加20wt%木薯茎,热解液产率从33.7wt%提高到46.0wt%,能量输出由0.90MJ/kg增大到1.90MJ/kg,添加20wt%玉米秸秆,热解气可燃成分增大了0.14L/g,能量输出由0.90MJ/kg增大到2.10MJ/kg;垃圾热解液分级萃取分离后热值为原来的2.5倍,分级萃取可以有效分离热解液并提高其热值。
There are still many difficulties inpyrolysis liquid of MSW directly as a fuel produced by theengine due to higher oxygen and low calorific value.Pyrolysis gases from MSW such as H2,CO,CH4and CO2,but low combustible gas content.Based on the above understanding,thispaper carried out research in the following aspects: the effects of catalyst on deoxidation ofMSW pyrolysis oil;influences of agricultural stalkon MSW pyrolysis energy and theproperties of the product;research of pyrolysis liquid properties and composition,andfractional extraction of oil-water separatorof pyrolysis liquid.It showed that the catalyst wasimproved the pyrolytic oil deoxidation and the heating value of MSW pyrolysis.AddedNa2CO3with1wt%,the oxygen content of the pyrolysis oil was reduced from22.49wt%to8.52wt%and the calorific value was improved1.64MJ/kg.In a certain mixing ratio of MSWand agricultural stalk,co-pyrolysis can improve the yieldsand calorific value of liquid and gasproduct and increase the energy of the pyrolysis process.Added20wt%cassava stalk,theMSW pyrolysis liquid yield was increasedfrom33.7wt%to46.0wt%and energy output from0.90MJ/kg to1.90MJ/kg.Added20wt%corn stalk,the combustible component of MSWpyrolysis gas was increased0.14L/g and energy output from0.90MJ/kg to2.10MJ/kg.Afterthe separation of fractional extraction,the heat value of pyrolysis liquid was2.5timescomparedwith the original.Fractional extraction separation of pyrolysis liquid was effectiveand increased its calorific value.
引文
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