The glass fusion beads sample preparation, the establishment of the X-ray fluorescence spectrometric determination of manganese ore in TMn of TFe, of SiO₂, Al₂O₃, and CaO and MgO and K₂O and TiO₂ and P₂O₅ and other minor components. Determine the optimal parameters of the instrument, using series of standard calibration curve. Decomposition of sample melting method effectively eliminates the sample particle size effect, and accuracy of several accuracy tests showed that the fluorescence on the glass melting tablets to meet the analysis requirements of the elements manganese ore.