ChemInform Abstract: Hydrogenation-Induced Structure and Property Changes in the Rare-Earth Metal Gallide NdGa: Evolution of a [GaH]2— Polyanion Containing Peierls-Like Ga—H Chains.
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- 作者：Jonas Aangstroem ; Robert Johansson ; Tapati Sarkar ; Magnus H. Soerby ; Claudia Zlotea ; Mikael S. Andersson ; Per Nordblad ; Ralph H. Scheicher ; Ulrich Haeussermann and Martin Sahlberg
- 关键词：structure (solids and liquids) ; neodymium ; Nd ; gallium ; Ga ; hydrogen ; H ; hydrogen storage ; storage of gases
- 刊名：ChemInform
- 出版年：2016
- 出版时间：March, 2016
- 年：2016
- 卷：47
- 期：13
- 全文大小：25K
- ISSN：1522-2667
文摘
NdGaH1.66 and its deuterated analogue are obtained by heating NdGa with H2 or D2 (autoclave, 10—20 bar, 300 °C, up to 48 h) and characterized by powder neutron diffraction, thermal desorption mass spectrometry, and magnetic measurements.