Palladium-Catalyzed Oxidative Carbonylation of Aromatic C−H Bonds with Alcohols using Molybdenum Hexacarbonyl as the Carbon Monoxide Source

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• 作者：Zechao Wang ; Yahui Li ; Fengxiang Zhu and Xiao-Feng Wu
• 刊名：Advanced Synthesis & Catalysis
• 出版年：2016
• 出版时间：September 1, 2016
• 年：2016
• 卷：358
• 期：17
• 页码：2855-2859
• 全文大小：390K
• ISSN：1615-4169

文摘

With molybdenum hexacarbonyl as the carbon monoxide source, a general palladium-catalyzed carbonylative transformation of the C−H bond on aromatic rings to produce esters has been developed. Good yields of the corresponding products have been obtained with wide functional group tolerance and excellent regioselectivity. A variety of aliphatic alcohols are suitable reactants here.