Influence of gas-liquid mass transfer on kinetic modeling: Carbonation of epoxidized vegetable oils

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• 作者：Xiaoshuang Cai^a ; Jun Liu Zheng^a ; Johan Wä ; rn&aring ; ^b ; Tapio Salmi^b ; Bechara Taouk^a ; Sebastien Leveneur^a ; ^b ; ^{sebastien.leveneur@insa-rouen.fr}
• 关键词：Cottonseed oil ; Biomass valorization ; CO2 ; Vegetable oils ; Epoxide ; Kinetic modeling ; Mass transfer
• 刊名：Chemical Engineering Journal
• 出版年：2017
• 出版时间：1 April 2017
• 年：2017
• 卷：313
• 期：Complete
• 页码：1168-1183
• 全文大小：3899 K
• 卷排序：313

文摘

Valorization of biomass and CO2 process: production of carbonated vegetable oils. Mass transfer study: evolution of gas-liquid mass transfer and Henry’s coefficients with reaction advancement. Kinetic study: influence of catalyst concentration, CO2 pressure and epoxide concentration. Validation of the kinetic model including mass transfer parameter was done.