Solid- and gas-phase structures and spectroscopic and chemical properties of tris(pentafluorosulfanyl)amine, N(SF5)3, and bis(pentafluorosufanyl)aminyl radical, N(SF5)2
Mechanism of formation and thermal decay of N(SF5)3 and N(SF5)2. Gas electron diffraction of N(SF5)3 and N(SF5)2. Single crystal X-ray diffraction of N(SF5)3. Vibrational and UV–vis spectra of N(SF5)3 and N(SF5)2. Quantum chemical calculations of N(SF5)3 and N(SF5)2.