Liquid-liquid equilibrium of 2-methyltetrahydrofuran/water over wide temperature range: Measurements and rigorous regression

详细信息    查看全文

• 作者：Moll Glass^a ; Maximilian Aigner^b ; Jö ; rn Viell^a ; Andreas Jupke^b ; Alexander Mitsos^a ; ^{amitsos@alum.mit.edu}
• 关键词：Parameter fitting ; NRTL model ; Multiphase reaction systems ; Raman spectroscopy ; Immiscibility ; FT-IR spectroscopy
• 刊名：Fluid Phase Equilibria
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：433
• 期：Complete
• 页码：212-225
• 全文大小：1702 K
• 卷排序：433

文摘

LLE data for water-2MTHF from 293 to 423 K are reported. NRTL parameter values for water-2MTHF are obtained. Data regression with conventional tools may violate stability. Aspen reports saddle point of Gibbs free energy as phase split. BOARPET guarantees thermodynamic stability in regression.