An experimental and computational investigation of the site selective and lattice driven cycloaddition reactions of SNS+ salts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone and 1,1,2,2-tet
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- 作者：Andreas Decken ; H. Donald B. Jenkins ; Aaron Mailman ; Jack Passmore ; Konstantin V. Shuvaev
- 关键词：1 ; 3 ; 2 ; 4-Dithiadiazolium ; Symmetry allowed cycloaddition ; Thermodynamics ; DFT ; VBT (volume-based thermodynamics) ; Calculated energetics ; SNS+ ; DDQ
- 刊名：Inorganica Chimica Acta
- 出版年：2008
- 出版时间：15 January 2008
- 年：2008
- 卷：361
- 期：2
- 页码：521-539
- 全文大小：987 K
文摘
Reaction of SNSSbF6 and DDQ (2,3-dichloro-5,6-dicyano-1,4-benzoquinone (1)) in SO2 solution in a 2:1 ratio afforded the dicycloaddition product 1(SNS)2(SbF6)2 · SO2 in 85 % isolated yield. The dicycloaddition product 1(SNS)2(SbF6)2 · SO2 was fully characterized by IR, Raman, NMR, elemental analysis, and single crystal X-ray crystallography. The product of the site selective dicycloaddition of SNS+ at the nitrile functionalities of 1 represents the first structurally characterized ortho-bis-1,3,2,4-dithiadiazolylium salt which adopts a conformation that utilizes the intramolecular Sδ+–Oδ− electrostatic interactions. The reaction of 1 and SNS[Al(OC(CF3)4] in a 1:1 ratio yielded only the monocycloaddition product 1(SNS)[Al(OC(CF3)3)4] indentified by multinuclear 13C, 14N, 19F, 27Al NMR in SO2 solution. The assignment of the 13C NMR of 1(SNS)+ in SO2 solution, were supported by comparison of the calculated (MPW1PW91/6-31G*) 13C NMR and experimental chemical shifts, and by comparison of the observed chemical shifts of the related 2(SNS)+ produced on reacting the mono-nitrile CDMQ (2-cyano-5,6-dichloro-3-methoxy-1,4-benzoquinone (2)) with SNS+ (as the ![]()
salt). The reaction of SNSSbF6 with TCNE (1,1,2,2-tetracyanoethylene (3)) gave the tri-cycloaddition product 3(SNS)3(SbF6)3 · SO2 (IR, Raman microscopy and X-ray crystallography) in 40 % yield.
The energetics of the cycloaddition reactions of SNS+ with 1–3 and other multifunctional unsaturated centers (e.g. HCC–CN, NC–CN,
, o,m,p-(CN)2C6H4, 1,3,5-(NC)3C6H3, 4–10, previously reported, see Chart 1), were estimated in the gas phase (MPW1PW91/6-31G*), solution (PBE0/6-311G*) and in the solid state by the ‘volume based thermodynamics’ (VBT) approach. The general thermodynamic trends associated with the stepwise cycloaddition of SNS+ with multifunctional nitriles were established. The 1:1 cycloaddition products were calculated to be stable in the gas phase and solution, while in the solid state the larger lattice enthalpy of the 1:2 salt, relative to twice that of the 1:1 salt, favored the 1:2 cycloaddition product.