Photophysical and photochemical properties of manganese complexes with cationic porphyrin ligands: Effects of alkyl substituents and micellar environment
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- 作者：Melinda A. Fodora ; amfor89@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Ottó ; Horvá ; tha ; otto@mk.uni-pannon.hu" class="auth_mail" title="E-mail the corresponding author ; Lajos Fodora ; lajos@vegic.uni-pannon.hu" class="auth_mail" title="E-mail the corresponding author ; Katarina Vazdarb ; katarina.vazdar@irb.hr" class="auth_mail" title="E-mail the corresponding author ; Gü ; nter Gramppc ; grampp@tugraz.at" class="auth_mail" title="E-mail the corresponding author ; Alexander Wankmü ; llerc ; a.wankmueller@tugraz.at" class="auth_mail" title="E-mail the corresponding author
- 关键词：Cationic manganese(III) porphyrins ; Amphiphilic ; Micellar ; Fluorescence ; Photocatalysis ; Triplet state
- 刊名：Journal of Photochemistry & Photobiology, A: Chemistry
- 出版年：2016
- 出版时间：1 September 2016
- 年：2016
- 卷：328
- 期：Complete
- 页码：233-239
- 全文大小：852 K
文摘
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Cationic manganese(III) porphyrins display characteristic fluorescence.
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They proved to be efficient photocatalysts in generation of MV●+.
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Long-lived triplet states play key roles in these photocatalytic systems.
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Both emission and photocatalytic features depend on their alkyl substituents.
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Micelles also considerably affect the photoinduced behavior of these complexes.