Melting range of recently developed TiCuZrPd amorphous alloys was determined. Effect of time, temperature and Pd content on TiCuZrPd wetting on Ti-6Al-4V was studied. TiCuZrPd amorphous alloys wet Ti-6Al-4V at temperatures below their liquidus. Three intermediate layers were identified at solidified TiCuZrPd/Ti-6Al-4V interface.