TMSCl-promoted selective oxidation of sulfides to sulfoxides with hydrogen peroxide

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• 作者：Kiumars Bahrami ; Mohammad M. Khodaei ; Behrooz H. Yousefi ; Mehdi Sheikh Arabi
• 刊名：Tetrahedron Letters
• 出版年：2010
• 出版时间：29 December 2010
• 年：2010
• 卷：51
• 期：52
• 页码：6939-6941
• 全文大小：584 K

文摘

Selective oxidation of sulfides to sulfoxides is achieved using H₂O₂ and TMSCl as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and in short reaction times. Different functional groups including ketone, alkene, ester, and alcohol are tolerated.