TBAI/TBHP mediated oxidative cross coupling of aryl alkyl ketones with H-phosphonates and H-phosphine oxides in water: facile access to ketol phosphates and phosphinates
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- 作者：G. Saidulu ; R. Arun Kumar ; T. Anitha ; P. Santhosh Kumar ; K. Rajender Reddy ; rajender@iict.res.in" class="auth_mail" title="E-mail the corresponding author ; rajenderkallu@yahoo.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Tetrabutylammonium iodide ; Oxidative coupling ; Phosphonate ; Aryl alkyl ketone ; Ketol phosphate
- 刊名：Tetrahedron Letters
- 出版年：2016
- 出版时间：13 April 2016
- 年：2016
- 卷：57
- 期：15
- 页码：1648-1652
- 全文大小：846 K
文摘
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Transition metal free oxidative cross coupling reaction is demonstrated.
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The present protocol offers direct and facile access to ketol-phosphates and phosphinates.
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Performing the reactions in aqueous media makes this methodology greener.