Four CoII-GdIII mixed-metal phosphonate clusters as molecular magnetic refrigerants
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- 作者：Xiaoyan Tang ; Wenpeng Ye ; Jingkun Hua ; Ming Chen ; Hongjian Cheng ; Yunsheng Ma ; myschem@hotmail.com" class="auth_mail" title="E-mail the corresponding author ; Rongxin Yuan ; yuanrx@cslg.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Phosphonate ; Fluorenyl ; Co-Gd cluster ; Magnetocaloric effect
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 November 2016
- 年：2016
- 卷：453
- 期：Complete
- 页码：142-148
- 全文大小：1491 K
文摘
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Three phosphonic acids with large steric groups were synthesized.
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The formation of Co-Gd clusters is dependent on the steric group of ligand.
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All clusters show magnetocaloric effects.