Sandwich type organic-inorganic hybrid of 3d-4f heterometallic containing germanotungstates [{Cu₂(1,10-phen)₂(μ-CH₃COO)₂}Ln(α-GeW₁₁O₃₉)₂]^{11 −}: Syntheses, crystal structures, magnetic and photoluminescence properties

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• 关键词：Polyoxometalates ; Germanotungstates ; Organic-inorganic hybrid ; Single crystal XRD ; Magnetism ; Photoluminescence
• 刊名：Inorganic Chemistry Communications
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：74
• 期：Complete
• 页码：72-78
• 全文大小：1431 K
• 卷排序：74

文摘

Synthesized 3d–4f organic-inorganic hybrids of germanotungstates following by one pot reaction procedure Characterized with SC-XRD, FTIR, powder-XRD and elemental analysis The Pr, Sm and Eu-POMs show good photoluminescence properties at room temperature. The Gd-POM shows weak ferromagnetic behavior on the applied magnetic field.