Anion-dependent micelle formation using electro-generated ferrocene surfactants

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• 作者：Louise A. Evans ; Daniela Apreutesei ; Georg H. Mehl ; Jay D. Wadhawan
• 关键词：Microdroplets ; Three-phase junction ; Electrochemically-controlled release
• 刊名：Electrochemistry Communications
• 出版年：2008
• 出版时间：November 2008
• 年：2008
• 卷：10
• 期：11
• 页码：1720-1723
• 全文大小：354 K

文摘

The syntheses and characterization of two ferrocene oils, 4-octyloxy-2-{5-[1,1,3,3-tetramethyl-3-(11-oxo-11-ferrocenyl-undecyl)-disiloxanyl]-pentyloxy}-benzoic acid 4′-undecyloxy-biphenyl-4-yl ester, Fc₁SiM and an octakis(ferrocene) species, Fc₈Si₈M′ are reported, and their biphasic aqueous voltammetry contrasted. Surprisingly, both hydrophobic species undergo single-wave electrochemical dissolution. This can be advantageous to electroanalytical applications.