Impact of micro-alloying on the plasticity of Pd-based bulk metallic glasses

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• 作者：Niklas Nollmann ; Isabelle Binkowski ; Vitalij Schmidt ; Harald Rö ; sner ; ^{rosner@uni-muenster.de" class="auth_mail" title="E-mail the corresponding author} ; Gerhard Wilde
• 关键词：Bulk metallic glass ; Mechanical properties ; Plastic deformation ; Ductility ; Shear bands
• 刊名：Scripta Materialia
• 出版年：2016
• 出版时间：15 January 2016
• 年：2016
• 卷：111
• 期：Complete
• 页码：119-122
• 全文大小：884 K

文摘

Micro-alloying was performed using additions of Co and Fe to monolithic Pd₄₀Ni₄₀P₂₀ bulk metallic glass. Compression tests showed a plastic strain of 13% for the Co addition (1 at.%), whereas the Fe addition (0.6 at.%) led to immediate failure after reaching the elastic limit. Plasticity is not reflected by the high Poisson’s ratio of 0.4 since it remained unaffected by minor alloying. Applying the fictive temperature concept to analyze the impact of minor alloying suggests that the total amount of free volume frozen-in during vitrification is less important for the mechanical properties of bulk metallic glasses than its local distribution.