Rh-Ni nanoparticles immobilized on Ce(OH)CO3 nanorods as highly efficient catalysts for hydrogen generation from alkaline solution of hydrazine
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- 作者：Jianmin Chen1 ; Qilu Yao1 ; Jia Zhu ; Xiangshu Chen ; cxs66cn@jxnu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Zhang-Hui Lu ; luzh@jxnu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Hydrous hydrazine ; RhNi nanoparticles ; Decomposition ; Hydrogen production
- 刊名：International Journal of Hydrogen Energy
- 出版年：2016
- 出版时间：19 February 2016
- 年：2016
- 卷：41
- 期：6
- 页码：3946-3954
- 全文大小：1787 K
文摘
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Rh–Ni/Ce(OH)CO3 were synthesized by a facile co-reduction method.
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Rh55Ni45/Ce(OH)CO3 showed high activity and H2 selectivity for decomposition of hydrazine.
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A high TOF value of 150 h−1 at 30 °C was obtained.
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Activation energy of Rh55Ni45/Ce(OH)CO3 was measured to be 38.8 kJ/mol.