Self-Assembly of a Tetrapodal Adamantane with Carbazole Branches into Hollow Spherical Aggregates in Organic Media

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• 作者：Masahide Tominaga ; Tetsuro Yoneta ; Kazuaki Ohara ; Kentaro Yamaguchi ; Tsutomu Itoh ; Chihiro Minamoto ; Isao Azumaya
• 刊名：Organic Letters
• 出版年：2014
• 出版时间：September 5, 2014
• 年：2014
• 卷：16
• 期：17
• 页码：4622-4625
• 全文大小：329K
• ISSN：1523-7052

文摘

A hydrophobic tetrapodal molecule is composed of carbazole units at the periphery linked by a phenyl spacer on an adamantane core. Tetrapodal adamantane self-assembles into hollow spherical aggregates with a multilayer membrane in organic media. The spherical assembly size is dependent on the organic solvent used. Hollow spheres can entrap guest molecules within their internal spaces. By increasing the concentrations of tetrapodal molecules, hollow spheres fused into necklace-shaped nanostructures and two-dimensional networks were obtained.