Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane
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- 作者：Sisi Liang ; Liang Xu ; Zhenshan Jia ; Liangbing Gan
- 刊名：Journal of Organic Chemistry
- 出版年：2014
- 出版时间：June 20, 2014
- 年：2014
- 卷：79
- 期：12
- 页码：5794-5798
- 全文大小：305K
- 年卷期：v.79,no.12(June 20, 2014)
- ISSN：1520-6904
文摘
Unlike the extensively studied perfluoroalkyl fullerene adducts, perfluorophenyl fullerene adducts are quite difficult to prepare by known methods. Trispentafluorophenylborane was found to react with fullerene epoxide to form the 1,2-perfluorophenylfullerenol. The method can be applied to both the simple epoxide C60(O) and fullerene multiadducts containing an epoxide moiety. Single crystal X-ray structure analysis confirmed the addition of the pentafluorophenyl group.