Dynamic Entangled Framework Based on an Iridium鈥揙rganic Unit Showing Reversible Luminescence Turn-On Sensing

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• 作者：Lina Li ; Shuquan Zhang ; Yingying Xu ; Sangen Zhao ; Zhihua Sun ; Junhua Luo
• 刊名：Inorganic Chemistry
• 出版年：2015
• 出版时间：September 21, 2015
• 年：2015
• 卷：54
• 期：18
• 页码：8872-8874
• 全文大小：230K
• ISSN：1520-510X

文摘

A new entangled metal鈥搊rganic framework shows reversible structural dynamics and luminescence changing in response to the loss of guest H₂O molecules. Furthermore, an intense and sensitive luminescence turn-on sensing was observed by the naked eye for 1 upon detection of the volatile organic solvent molecule CH₃CN, accompanied by reversible structural transformation.