Bulky Bisphenol Ligand-Supported Aluminum−Sodium Inverse Crown Ether Complex
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- 作者：Jincai Wu ; Xiaobo Pan ; Ning Tang ; Chu-Chieh Lin
- 刊名：Inorganic Chemistry
- 出版年：2010
- 出版时间：June 21, 2010
- 年：2010
- 卷：49
- 期：12
- 页码：5362-5364
- 全文大小：730K
- 年卷期：v.49,no.12(June 21, 2010)
- ISSN：1520-510X
文摘
A mixed aluminum−sodium phenolate ring compound with an oxo core has been synthesized and crystallographically characterized as a new inverse crown ether complex, together with some of its precursors. The experimental results showed that the Al−Na inverse crown ether can be obtained from two different approaches: (1) hydrolysis of [(EDBP)Al(CH3)2Na(THF)2] (1), followed by condensation with [(EDBP)Al(CH3)(μ2-OH)Na(THF)3] (2); (2) fast redox reaction by oxidation of a methyl group on complex 1 and reduction of molecular oxygen to oxide.