Synthesis of meso-Polyphosphorylporphyrins and Example of Self-Assembling

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• 作者：Yulia Y. Enakieva ; Alla G. Bessmertnykh ; Yulia G. Gorbunova ; Christine Stern ; Yoann Rousselin ; Aslan Y. Tsivadze ; Roger Guilard
• 刊名：Organic Letters
• 出版年：2009
• 出版时间：September 3, 2009
• 年：2009
• 卷：11
• 期：17
• 页码：3842-3845
• 全文大小：219K
• 年卷期：v.11,no.17(September 3, 2009)
• ISSN：1523-7052

文摘

Pd-catalyzed coupling reactions have been used to prepare meso-phosphorylporphyrins. A 2D metal−organic network formed via P═O···Zn axial supramolecular coordination of 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrin is the first example of a 2D framework based on phosphorylporphyrin derivatives.