Hexacoordinate Complexes of Silacyclobutane: Spontaneous Ring Opening and Rearrangement

详细信息    查看全文

• 作者：Boris Gostevskii ; Inna Kalikhman ; Claire A. Tessier ; Matthew J. Panzner ; Wiley J. Youngs ; and Daniel Kost
• 刊名：Organometallics
• 出版年：2005
• 出版时间：November 21, 2005
• 年：2005
• 卷：24
• 期：24
• 页码：5786 - 5788
• 全文大小：91K
• 年卷期：v.24,no.24(November 21, 2005)
• ISSN：1520-6041

文摘

The title compounds were prepared and werefound to undergo ring opening and molecular rearrangement under mild conditions and no catalysis, forminga carbon-carbon bond and closing a new chelate ring.The rearrangement product depends on whether -protons are present. Reactants and products are characterized by crystal structures.