Quantification of Selected Volatile Constituents and Anions in Mexican Agave Spirits (Tequila, Mezcal, Sotol, Bacanora)
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文摘
A large collection (n = 95) of Mexican Agave spirits with protected appellations of origin (Tequila,Mezcal, Sotol, and Bacanora) was analyzed using ion and gas chromatography. Because of theirproduction from oxalate-containing plant material, all Agave spirits contained significant concentrationsof oxalate (0.1-9.7 mg/L). The two Tequila categories ("100% Agave" and "mixed") showed differencesin the methanol, 2-/3-methyl-1-butanol, and 2-phenylethanol concentrations with lower concentrationsin the mixed category. Mezcal showed no significant differences in any of the evaluated parametersthat would allow a classification. Sotol showed higher nitrate concentrations and lower 2-/3-methyl-1-butanol concentrations. Bacanora was characterized by exceptionally high acetaldehyde concentrations and a relatively low ethyl lactate content. The methanol content was the most problematiccompound regarding the Mexican standards: two Tequilas (4%), five Sotols (31%), and six Bacanoras(46%) had levels above the maximum methanol content of 300 g/hL of alcohol. In conclusion, thecomposition of Mexican Agave spirits was found to vary over a relatively large range.Keywords: Agave; Agavaceae; Tequila; Mezcal; Sotol; Bacanora; volatile compounds; ion chromatography; gas chromatography

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