Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones

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• 作者：Masanobu Nagano ; Mitsunobu Doi ; Masaaki Kurihara ; Hiroshi Suemune ; Masakazu Tanaka
• 刊名：Organic Letters
• 出版年：2010
• 出版时间：August 6, 2010
• 年：2010
• 卷：12
• 期：15
• 页码：3564-3566
• 全文大小：191K
• 年卷期：v.12,no.15(August 6, 2010)
• ISSN：1523-7052

文摘

Chiral cyclic α-amino acid containing oligopeptide catalyzed highly enantioselective epoxidation of α,β-unsaturated ketones and the α-helical secondary structure of the peptide catalyst were revealed by X-ray crystallographic analysis.