A green route to 1,2-cyclohexanediol via the hydrolysis of cyclohexene oxide catalyzed by water
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- 作者：Qiusheng Yang (1)
Xue Yang (1)
Yanji Wang (1) yqiusheng@sina.com
Haiou Wang (1)
Qingyan Cheng (1) - 关键词：Hydrolysis – ; Water – ; Cyclohexene oxide – ; 1 ; 2 ; Cyclohexanediol – ; Polymer
- 刊名：Research on Chemical Intermediates
- 出版年：2012
- 出版时间：November 2012
- 年：2012
- 卷：38
- 期：9
- 页码：2277-2284
- 全文大小：358.8 KB
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- ISSN：1568-5675
文摘
Effective hydrolysis of cyclohexene oxide (CHO) was conducted by heating in water between 100 and 140 掳C without another catalyst. It provided 100 % purity and 100 % yield of trans-1,2-cyclohexanediol (1,2-CHD) with five times of H2O to CHO at 120 掳C for 6 h. These intermediates of polyether polyols could be totally decomposed to 1,2-CHD (monomer) by hot water under the same condition. The improved process eliminates the purification and markedly reduces the cost of 1,2-CHD in the follow-up industrial production. The main factors, such as reaction temperature, time, and water volume, were investigated. It was proposed that water acted as a modest acid catalyst, reactant, and solvent in the hydrolysis of CHO and polymers.