Novel Pyridinium Inner Salt Dye and its Complexes: Synthesis, Crystal Structures and Photophysical Properties
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- 作者：Yong-Hong Zhou ; Na-Li Wang ; Ti-Fang Miao ; Juan-Gang Wang…
- 关键词：Two ; photon absorption ; Metal complex ; Pyridinium inner salt dye ; Two ; photon excited fluorescence
- 刊名：Journal of Fluorescence
- 出版年：2015
- 出版时间：March 2015
- 年：2015
- 卷：25
- 期：2
- 页码：473-479
- 全文大小：1,142 KB
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文摘
Two novel metal complexes, namely [Tb2(L)6(H2O)4]?NO3)6?L2?H2O)18 (1) and [Hg(L)Cl2]n (2), were obtained by the reaction of D-π-A (D-?donor, π-?conjugated spacer, A-?acceptor) type pyridinium inner salt dye, trans-4-[(p-N,N-dimethylamino)styryl]-N-(2-propanoic-acid) pyridinium (L) with corresponding metal salts. Single crystal X-ray diffraction analyses reveal that compound 1 possesses dinuclear motif in which two Tb(III) ions are linked by four carboxylate groups while complex 2 exhibits 1D chain structure based on Hg(II) ions bridged by carboxylate groups. The linear and non-linear optical properties of complexes 1 and 2 have been studied. Both 1 and 2 exhibit intense single-photon excited fluorescence (SPEF) and two-photon excited fluorescence (TPEF) in the red range. Results show that the replacement of central ions from Hg2+ to Tb3+ influence the two-photon absorption cross-section significantly through increasing the density of the chromophore. However, the peak positions of two-photon excited fluorescence are only slightly affected. Compared with L molecule, complex 1 shows enhanced two-photon absorption cross-section and decreased fluorescent lifetime.