Equation of state of adamite up to 11?GPa: a synchrotron X-ray diffraction study
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  • 作者:Jingui Xu (1) (2)
    Maining Ma (2) (3)
    Shuyi Wei (1) (2)
    Xianxu Hu (1) (2)
    Yonggang Liu (1)
    Jing Liu (4)
    Dawei Fan (1)
    Hongsen Xie (1)
  • 关键词:Adamite ; High pressure ; Synchrotron X ; ray diffraction ; Equation of state ; Diamond anvil cell
  • 刊名:Physics and Chemistry of Minerals
  • 出版年:2014
  • 出版时间:July 2014
  • 年:2014
  • 卷:41
  • 期:7
  • 页码:547-554
  • 全文大小:624 KB
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  • 作者单位:Jingui Xu (1) (2)
    Maining Ma (2) (3)
    Shuyi Wei (1) (2)
    Xianxu Hu (1) (2)
    Yonggang Liu (1)
    Jing Liu (4)
    Dawei Fan (1)
    Hongsen Xie (1)

    1. Laboratory for High Temperature and High Pressure Study of the Earth’s Interior of Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550002, China
    2. University of Chinese Academy of Sciences, Beijing, 100049, China
    3. Key Laboratory of Computational Geodynamics, Chinese Academy of Sciences, Beijing, 100049, China
    4. Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China
  • ISSN:1432-2021
文摘
The compression behavior of natural adamite [Zn2AsO4OH] has been investigated up to 11.07?GPa at room temperature utilizing in situ angle-dispersive X-ray diffraction and a diamond anvil cell. No phase transition has been observed within the pressure range investigated. A third-order Birch–Murnaghan equation of state fitted to all of the data points yielded V 0?=?430.1(4)??3, K 0?=?80(3)?GPa, K-/em> 0?=?1.9(5). The K 0 was obtained as 69(1)?GPa when K-/em> 0 was fixed at 4. Analysis of axial compressible moduli shows the intense compression anisotropy of adamite: K a0?=?37(3)?GPa, K b0?=?153(6)?GPa, K c0?=?168(8)?GPa; hence, a axis is the most compressible and the compressibility of b and c axis is comparable. Furthermore, the comparisons among the compressional properties of adamite, libethenite (Cu2PO4OH, also belongs to olivenite group), and andalusite (Al2SiO4O has the similar structure with adamite) at high pressure were made.

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