Thermal decomposition of inclusion compounds on the base of the metal–organic framework [Zn4(DMF)(ur)2(ndc)4]
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- 作者：Vladimir A. Logvinenko ; Sergey A. Sapchenko…
- 关键词：Coordination compounds ; Inclusion compounds ; Kinetic stability ; Metal–organic frameworks ; Non ; isothermal kinetics
- 刊名：Journal of Thermal Analysis and Calorimetry
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：123
- 期：1
- 页码：697-702
- 全文大小：586 KB
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38.Solomons TWG, Fryhle CB. Organic chemistry. 9th ed. New York: Wiley; 2006. - 作者单位：Vladimir A. Logvinenko (1) (2)
Sergey A. Sapchenko (1) (2)
Vladimir P. Fedin (1) (2)
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave 3, 630090, Novosibirsk-90, Russia
2. Novosibirsk State University, Pirogova St 2, 630090, Novosibirsk-90, Russia - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Sciences
Polymer Sciences
Physical Chemistry
Inorganic Chemistry
Measurement Science and Instrumentation - 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
- ISSN：1572-8943
文摘
Inclusion compounds based on metal–organic frameworks (MOFs) have promising practical applications in gas storage, the separation and fine purification of substances and also in catalysis. These MOFs are crystalline compounds consisting of metal ions coordinated by bridging organic ligands with the formation of porous structures. Here, we study the thermal stability of two inclusion compounds on the base of the new framework: [Zn4(DMF)(ur)2(ndc)4]·5DMF·H2O and [Zn4(DMF)(ur)2(ndc)4]·4ferrocene (ndc2−= 2,6-naphthalenedicarboxylate, ur = hexamethylenetetramine, DMF = N,N′-dimethylformamide, ferrocene = Fe(C5H5)2). The first compound decomposition includes water removal, DMF removal and complex pyrolysis of the empty framework; the kinetics of DMF release is studied. The second compound does not lose the guest molecules before full pyrolysis. The stability of the inclusion compounds with DMF guest molecules on the base of the different host frameworks is considered.