Crystal and molecular structure of [5,10,15,20-tetrakisphenyl-2-ethoxy-3-oxa-chlorinato]Ag(II)
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- 作者：Matthias Zeller ; Allen D. Hunter ; Jason R. McCarthy ; Steven H. Capetta and Christian Br¨¹ckner
- 关键词：Porphyrin ; analogs ; chlorins ; silver(II) complexes ; disorder
- 刊名：Journal of Chemical Crystallography
- 出版年：2005
- 出版时间：December 2005
- 年：2005
- 卷：35
- 期：12
- 页码：935-942
- 全文大小：306 KB
文摘
The silver(II) complex of the chlorin-like derivativev [5,10,15,20-tetrakisphenyl-2-ethoxy-3-oxa-chlorinato]Ag(II) (1Ag), formally formed by substitution of one pyrrolic subunit in silvermeso-tetraphenylporphyrin by one ethoxy-substituted hydrooxazole moiety, crystallizes in the tetragonal space groupI4/m witha = 13.4811(10) ?,c = 9.7361(13) ?, andZ = 2. The molecule, which is asymmetric, accommodates the high-symmetry space group by rotational disorder with the silver atom located on the four-fold axis.