Surface-Initiated Atom Transfer Radical Polymerization

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• 关键词：Controlled radical polymerization ; Elementary reactions ; Mechanism ; Grafting density ; Surface geometry
• 刊名：Advances in Polymer Science
• 出版年：2016
• 出版时间：2016
• 年：2016
• 卷：270
• 期：1
• 页码：29-76
• 全文大小：1,984 KB
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• 作者单位：Amir Khabibullin (19)
  Erlita Mastan (20)
  Krzysztof Matyjaszewski (19)
  Shiping Zhu (20)
  
  19. Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA, 15213, USA
  20. Department of Chemical Engineering, McMaster University, 1280 Main Street West, Hamilton, ON, Canada, L8S 4L7
  
• 丛书名：Controlled Radical Polymerization at and from Solid Surfaces
• ISBN：978-3-319-22138-0
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1436-5030

文摘

This review covers the basic principles of surface-initiated atom transfer radical polymerization (SI-ATRP). SI-ATRP is a robust and versatile method for preparation of various hybrid materials with controlled molecular characteristics of the tethered polymer chains, such as polymer composition and architecture. Various aspects of SI-ATRP, such as polymer brush grafting density, surface geometry, and reaction conditions, including structure of initiator, ligand, and catalyst, are important for engineering the structure and properties of the hybrid polymer materials. Elementary reactions, such as initiation, propagation, termination, transfer, and activation/deactivation equilibria as well as factors affecting these processes are discussed. The properties of materials prepared by SI-ATRP are illustrated through several selected examples.