Nanoscale Inhomogeneities Mapping in Ga-Modified Arsenic Selenide Glasses

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• 作者：Ya. Shpotyuk ; S. Adamiak ; A. Dziedzic ; J. Szlezak…
• 关键词：Arsenic selenide glass ; Nanoindentation ; Crystallization ; Phase separation
• 刊名：Nanoscale Research Letters
• 出版年：2017
• 出版时间：December 2017
• 年：2017
• 卷：12
• 期：1
• 全文大小：2780KB
• 刊物主题：Nanotechnology; Nanotechnology and Microengineering; Nanoscale Science and Technology; Nanochemistry; Molecular Medicine;
• 出版者：Springer US
• ISSN：1556-276X
• 卷排序：12

文摘

Nanoscale inhomogeneities mapping in Ga-modified As₂Se₃ glass was utilized exploring possibilities of nanoindentation technique using a Berkovitch-type diamond tip. Structural inhomogeneities were detected in Ga_x(As_0.40Se_0.60)_100−x alloys with more than 3 at.% of Ga. The appeared Ga₂Se₃ nanocrystallites were visualized in Ga-modified arsenic selenide glasses using scanning and transmission electron microscopy. The Ga additions are shown to increase nanohardness and Young’s modulus, this effect attaining an obvious bifurcation trend in crystallization-decomposed Ga₅(As_0.40Se_0.60)₉₅ alloy.