Palladium supported on triphenylphosphine-functionalized porous organic polymer: an efficient heterogeneous catalyst for aminocarbonylation

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• 作者：Yizhu Lei ; Xuefeng Zhang ; Yanlong Gu ; Jianglin Hu…
• 刊名：Transition Metal Chemistry
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：41
• 期：1
• 页码：1-7
• 全文大小：1,153 KB
• 参考文献：1.Pattabiraman VR, Bode JW (2011) Nature 480:471CrossRef
  2.Zhang DW, Zhao X, Hou JL, Li ZT (2012) Chem Rev 112:5271CrossRef
  3.Gadge ST, Bhanage BM (2014) RSC Adv 4:10367CrossRef
  4.Sumino S, Fusano A, Fukuyama T, Ryu I (2014) Acc Chem Res 47:1563CrossRef
  5.Wu X-F, Neumann H, Beller M (2013) Chem Rev 113:1CrossRef
  6.Omae I (2011) Coord Chem Rev 255:139CrossRef
  7.Wu X-F, Neumann H, Beller M (2011) Chem Soc Rev 40:4986CrossRef
  8.Xu T, Alper H (2014) J Am Chem Soc 136:16970CrossRef
  9.Quesnel JS, Arndtsen BA (2013) J Am Chem Soc 135:16841CrossRef
  10.Fang T, Gao X-H, Tang R-Y, Zhang X-G, Deng C-L (2014) Chem Commun 50:14775CrossRef
  11.Gadge ST, Bhanage BM (2014) Org Biomol Chem 12:5727CrossRef
  12.Xu T, Alper H (2013) Tetrahedron Lett 54:5496CrossRef
  13.Tinnis F, Verho O, Gustafson KPJ, Tai C-W, Bäckvall J-E, Adolfsson H (2014) Chem Eur J 20:5885CrossRef
  14.Cai M, Zhao H, Huang Y (2005) J Mol Catal A Chem 238:41CrossRef
  15.Hao WY, Sha JC, Sheng SR, Cai MZ (2008) Catal Commun 10:257CrossRef
  16.Dang TT, Zhu Y, Ghosh SC, Chen A, Chai CLL, Seayad AM (2012) Chem Commun 48:1805CrossRef
  17.Dang TT, Zhu Y, Ngiam JSY, Ghosh SC, Chen A, Seayad AM (2013) ACS Catal 3:1406CrossRef
  18.Qureshi ZS, Revankar SA, Khedkar MV, Bhanage BM (2012) Catal Today 198:148CrossRef
  19.Islam SM, Ghosh K, Roy AS, Molla RA (2014) RSC Adv 4:38986CrossRef
  20.Molla RA, Iqubal MA, Ghosh K, Roy AS, Islam SM (2014) RSC Adv 4:48177CrossRef
  21.Li B, Guan Z, Wang W, Yang X, Hu J, Tan B, Li T (2012) Adv Mater 24:3390CrossRef
  22.Sun Q, Jiang M, Shen Z, Jin Y, Pan S, Wang L, Meng X, Chen W, Ding Y, Li J, Xiao F-S (2014) Chem Commun 50:11844CrossRef
  23.Rose M (2014) ChemCatChem 6:1166
  24.Zhang Q, Yang Y, Zhang S (2013) Chem Eur J 19:10024CrossRef
  25.Jiang M, Yan L, Ding Y, Sun Q, Liu J, Zhu H, Lin R, Xiao F, Jiang Z, Liu J (2015) J Mol Catal A Chem 404–405:211CrossRef
  26.Sun Q, Dai Z, Liu X, Sheng N, Deng F, Meng X, Xiao F-S (2015) J Am Chem Soc 137:5204CrossRef
  27.Lei Y, Wu L, Zhang X, Mei H, Gu Y, Li G (2015) J Mol Catal A Chem 398:164CrossRef
  28.Mei H, Hu J, Xiao S, Lei Y, Li G (2014) Appl Catal A Gen 475:40CrossRef
  29.Mei H, Xiao S, Zhu T, Lei Y, Li G (2014) Transit Met Chem 39:443CrossRef
  30.Barnard CFJ (2008) Org Process Res Dev 12:566CrossRef
  31.Genelot M, Villandier N, Bendjeriou A, Jaithong P, Djakovitch L, Dufaud V (2012) Catal Sci Technol 2:1886CrossRef
  32.Balogh J, Kuik Á, Ürge L, Darvas F, Bakos J, Skoda-Földes R (2009) J Mol Catal A Chem 302:76CrossRef
  33.Takács E, Varga C, Skoda-Földes R, Kollár L (2007) Tetrahedron Lett 48:2453CrossRef
  34.Papp M, Skoda-Földes R (2013) J Mol Catal A Chem 378:193CrossRef
  
• 作者单位：Yizhu Lei (1)
  Xuefeng Zhang (2)
  Yanlong Gu (2)
  Jianglin Hu (2)
  Guangxing Li (2)
  Kaiyi Shi (1)
  
  1. Department of Chemistry and Chemical Engineering, Liupanshui Normal University, Liupanshui, 553004, Guizhou, People’s Republic of China
  2. School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road 1037, Wuhan, 430074, Hubei, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-901X

文摘

An efficient route for the catalytic synthesis of aryl amides via the aminocarbonylation of aryl iodides with amines is described using palladium supported on triphenylphosphine-functionalized porous organic polymer (Pd@KAPs(Ph-PPh₃)) as the catalyst. Under low carbon monoxide pressure, the catalyst exhibited remarkable activity, and only 0.5 mol% palladium loading was required to achieve moderate to excellent yields (70–97 %) of aryl amides. The catalyst can be easily separated by a simple filtration process and recycled up to seven times with only minor loss of activity. The salient features of this protocol are the simplicity in handling of catalyst, low CO pressure, good functional group tolerance, high catalytic activity, negligible palladium leaching and effective catalyst recyclability.