Nitrogen is a requirement for the photochemical induced 3-azabicyclo[3.3.1]nonane skeletal rearrangement!

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• 作者：Williams ; Craig M. ; Heim ; Ralf ; Bernhardt ; Paul V.
• 关键词：Photochemistry ; 3-Azabicyclo[3.3.1]nonane
• 刊名：Tetrahedron
• 出版年：2005
• 期刊代码：107_00404020
• 类别：ch
• 出版时间：April 11, 2005
• 卷：61
• 期：15
• 页码：3771-3779
• 文件大小：520 K

摘要

Specific 3-azabicyclo[3.3.1]nonane derivatives undergo skeletal cleavage when subjected to light or Lewis acidic conditions affording novel heterotricycles, which is in stark contrast to 3-oxabicyclo[3.3.1]nonanes.