Propanal synthesis from aqueous propylene glycol/hydrogen peroxide on a Ru/alumina catalyst

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• 作者：R.S. Disselkamp ; B.D. Harris ; J.N. Patel ; T.R. Hart ; C.H.F. Peden
• 关键词：Propylene glycol ; Hydrogen peroxide ; Dehydration ; Ruthenium/alumina catalyst ; Magnesium promoter
• 刊名：Inorganic Chemistry Communications
• 出版年：2008
• 期刊代码：39_13877003
• 类别：ch
• 出版时间：May 2008
• 卷：11
• 期：5
• 页码：561-563
• 文件大小：87 K

摘要

The conversion of polyol materials, including 1,2-diols, into higher commodity chemicals is actively being pursued by many researchers. Here we report the production of propanal from aqueous propylene glycol and hydrogen peroxide using a Ru/alumina catalyst. Experiments were conducted by adding up to four peroxide equivalents under steady-state reflux conditions at 371 K. The product propanal and its subsequent reaction product with substrate, 1,3-dioxolane-2-ethyl-4-methyl, was observed to be an intermediate achieving a maximum concentration of 3%of substrate. Buffering using Mg(OH)₂ at pH f" alt="not, vert, similar" title="not, vert, similar" border="0"> 10 resulted in propanal formation, whereas buffering at similar pH using Na₂HPO₄ did not, from which we propose that magnesium acts as a promoter in the reaction. The mechanism appears to be a dehydration to enol, followed by rearrangement to product. Experiments utilizing Ru/carbon did not yield any propanol suggesting that the acidic sites of alumina aid the dehydration reaction. To our knowledge, this represents the first time hydrogen peroxide has been used in an alcohol dehydration reaction.