Gas chromatography–pyrolysis–isotope ratio mass spectrometry: a new method for investigating intramolecular isotopic variation in low molecular weight organic acids

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• 作者：Dias ; Robert F. ; Freeman ; Katherine H. ; Franks ; Stephen G.
• 刊名：Organic Geochemistry
• 出版年：2002
• 期刊代码：40_01466380
• 类别：pw
• 出版时间：February, 2002
• 卷：33
• 期：2
• 页码：161-168
• 文件大小：192 K

摘要

A new GC–Pyrolysis–IRMS method was developed for the δ¹³C determination of carboxyl carbon in low-molecular weight organic acids. By utilizing a palladium-wire reactor at 600 °C with a helium/hydrogen reactant gas, the carboxyl carbon of low-molecular weight organic acids is pyrolytically cleaved and introduced into an IRMS for stable carbon-isotope analysis. The precision of the GC–Py–IRMS method is similar to that of more conventional, combustion-based continuous-flow IRMS techniques and interpretation of isotope-dilution experiments with acetic and octanoic acid shows that the technique is sufficiently accurate for the determination of δ¹³C values at natural abundance levels. As a demonstration of this new capability, the carboxyl carbon of low-molecular weight (LMW, C₂–C₆) organic acids generated via hydrous pyrolysis of an oil-prone source rock (the Ghareb Shale) shows δ¹³C values consistent with the hypothesis that organic acids readily undergo exchange of their carboxyl carbon with aqueous inorganic carbon.