二维石墨烯和准二维类石墨烯在全固态柔性超级电容器中的应用
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摘要
近年来,二维石墨烯和准二维无机类石墨烯材料作为电极材料广泛应用于超级电容器,随着便携式电子器件的快速发展,超薄、柔性储能器件的研发必不可少.其中,具有柔性乃至平面构型的超薄超级电容器正在迅速兴起,成为一种极具潜力及发展优势的能量存储器件,而二维材料在该类器件的构建中至关重要.本文概述了全固态柔性超级电容的构建原理,特别是二维/准二维材料在构建柔性超级电容器中的材料选择与复合提高性能,综述了平面超级电容器的发展,展望了下一代平面超级电容器在柔性能源存储器件中可能的应用前景.
Two-dimensional(2D) graphene/quasi-two-dimensional inorganic materials have been widely explored for construction of energyrelated applications. Catering for rapid development of portable electronic devices, energy storage devices with ultra-thin and high flexibility are urgently needed. Very recently, planar supercapacitor with novel configurations has been rapidly developed as important energy storage devices. In this regard, the assembled thin film of 2D graphene and quasi-2D graphene analogues acted as the vital role for the planar configurations as well as the enhanced performances in the construction of planar energy storage device. This review summarized the construction concept of flexible supercapacitors in all-solid-state based on 2D graphene and quasi-2D graphene analogues. We also surveyed how to select quasi-2D graphene analogues with high electrochemical properties, and even how to use the synergic advantages of hybrid structure for further performance enhancement of planar supercapacitors. Recent progresses and possible future applications on planar supercapacitors were also reviewed and outlooked.
Two-dimensional(2D) graphene/quasi-two-dimensional inorganic materials have been widely explored for construction of energyrelated applications. Catering for rapid development of portable electronic devices, energy storage devices with ultra-thin and high flexibility are urgently needed. Very recently, planar supercapacitor with novel configurations has been rapidly developed as important energy storage devices. In this regard, the assembled thin film of 2D graphene and quasi-2D graphene analogues acted as the vital role for the planar configurations as well as the enhanced performances in the construction of planar energy storage device. This review summarized the construction concept of flexible supercapacitors in all-solid-state based on 2D graphene and quasi-2D graphene analogues. We also surveyed how to select quasi-2D graphene analogues with high electrochemical properties, and even how to use the synergic advantages of hybrid structure for further performance enhancement of planar supercapacitors. Recent progresses and possible future applications on planar supercapacitors were also reviewed and outlooked.
引文
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2 Tarascon J M,Armand M.Issues and challenges facing rechargeable lithium batteries.Nature,2001,414:359–367
3 杨勇,龚正良,吴晓彪,等.锂离子电池若干正极材料体系的研究进展.科学通报,2012,57:2570–2586
4 Miller J R,Simon P.Electrochemical capacitors for energy management.Science,2008,321:651–652
5 Meng C Z,Liu C H,Chen L Z,et al.Highly flexible and all-solid-state paperlike polymer supercapacitors.Nano Lett,2010,10:4025–4031
6 Bae J,Song M K,Park Y J,et al.Fiber supercapacitors made of nanowire-fiber hybrid structures for wearable/flexible energy storage.Angew Chem Int Ed,2011,50:1683–1687
7 Choi B G,Hong J,Hong W H,et al.Facilitated ion transport in all-solid-state flexible supercapacitors.ACS Nano,2011,5:7205–7213
8 Wu Q,Xu Y X,Yao Z Y,et al.Supercapacitors based on flexible graphene/polyaniline nanofiber composite films.ACS Nano,2010,4:1963–1970
9 Wang K,Zou W J,Quan B G,et al.An all-solid-state flexible micro-supercapacitor on a chip.Adv Energy Mater,2011,1:1068–1072
10 Dong X Y,Wang L,Wang D,et al.Layer-by-layer engineered Co-Al hydroxide nanosheets/graphene multilayer films as flexible electrode for supercapacitor.Langmuir,2011,28:293–298
11 Liu Q,Nayfeh M H,Yau S T.Brushed-on flexible supercapacitor sheets using a nanocomposite of polyaniline and carbon nanotubes.J Power Sources,2010,195:7480–7483
12 Chou S L,Wang J Z,Chew S Y,et al.Electrodeposition of MnO2nanowires on carbon nanotube paper as free-standing,flexible electrode for supercapacitors.Electrochem Commun,2008,10:1724–1727
13 张永起,夏新辉,康婧,等.多孔氢氧化钴薄膜的制备及其超级电容器性能.科学通报,2012,57:2644–2648
14 Eda G,Fanchini G,Chhowalla M.Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material.Nat Nanotechnol,2008,3:270–274
15 Brezesinski T,Wang J,Tolbert S H,et al.Ordered mesoporous-MoO3with iso-oriented nanocrystalline walls for thin-film pseudocapacitors.Nat Mater,2010,9:146–151
16 Mai L Q,Yang F,Zhao Y L,et al.Hierarchical MnMoO4/CoMoO4heterostructured nanowires with enhanced supercapacitor performance.Nat Commun,2011,2:381
17 Zhang K,Zhang L L,Zhao X S,et al.Graphene/polyaniline nanofiber composites as supercapacitor electrodes.Chem Mater,2010,22:1392–1401
18 Zhao Y,Liu J,Hu Y,et al.Highly compression-tolerant supercapacitor based on polypyrrole-mediated graphene foam electrodes.Adv Mater,2013,25:591–595
19 Laforgue A,Simon P,Sarrazin C,et al.Polythiophene-based supercapacitors.J Power Sources,1999,80:142–148
20 Butler S Z,Hollen S M,Cao L,et al.Progress,challenges,and opportunities in two-dimensional materials beyond graphene.ACS Nano,2013,7:2898–2926
21 Kim J,Cote L J,Huang J X.Two dimensional soft material:New faces of graphene oxide.Acc Chem Res,2012,45:1356–1364
22 Xu M S,Liang T,Shi M M,et al.Graphene-like two-dimensional materials.Chem Rev,2013,113:3766–3798
23 Komaba S,Kumagai N,Chiba S.Synthesis of layered MnO2by calcination of KMnO4for rechargeable lithium battery cathode.Electrochim Acta,2000,46:31–37
24 Chhowalla M,Shin H S,Eda G,et al.The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets.Nat Chem,2013:263–275
25 Yoo J J,Balakrishnan K,Huang J,et al.Ultrathin planar graphene supercapacitors.Nano Lett,2011,11:1423–1427
26 Yu G H,Hu L B,Vosgueritchian M,et al.Solution-processed graphene/MnO2nanostructured textiles for high-performance electrochemical capacitors.Nano Lett,2011,11:2905–2911
27 Conway B E.Transition from supercapacitor to battery behavior in electrochemical energy storage.J Electrochem Soc,1991,138:1539–1548
28 Naoi K,Simon P.New materials and new configurations for advanced electrochemical capacitors.Electrochem Soc Interface,2008,17:34 –37
29 Simon P,Gogotsi Y.Materials for electrochemical capacitors.Nat Mater,2008,7:845 854
30 Lu X H,Wang G M,Zhai T,et al.Hydrogenated TiO2nanotube arrays for supercapacitors.Nano Lett,2012,12:1690 1696
31 Lang X,Hirata A,Fujita T,et al.Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors.Nat Nanotechnol,2011,6:232 –236
32 Wang X F,Liu B,Wang Q F,et al.Three-dimensional hierarchical GeSe2nanostructures for high performance flexible all-solid-state supercapacitors.Adv Mater,2012,25:1479–1486
33 He Y M,Chen W J,Li X D,et al.Freestanding three-dimensional graphene/MnO2composite networks as ultralight and flexible supercapacitor electrodes.ACS Nano,2013,7:174–182
34 Novoselov K S,Geim A K,Morozov S V,et al.Electric field effect in atomically thin carbon films.Science,2004,306:666–669
35 Guo S J,Dong S J.Graphene nanosheet:Synthesis,molecular engineering,thin film,hybrids,and energy and analytical applications.Chem Soc Rev,2011,40:2644–2672
36 Xie J F,Sun X,Zhang N,et al.Layer-by-layer-Ni(OH)2/graphene nanohybrids for ultraflexible all-solid-state thin film supercapacitors with high electrochemical performance.Nano Energy,2013,2:65–74
37 Jiang Y Q,Zhou Q,Lin L.Planar MEMS supercapacitor using carbon nanotube forests.In:IEEE,ed.Proceedings of 22th IEEE Micro Electro Mechanical Systems Conference,2009.Piscataway,NJ,USA:IEEE,2009.587–590
38 Chmiola J,Largeot C,Taberna P L,et al.Monolithic carbide-derived carbon films for micro-supercapacitors.Science,2010,328:480–483
39 Marzan L M L.(Non-carbon)anisotropic nanomaterials.J Mater Chem,2006,16:3891–3892
40 Yang H,Hyeokjin L H,Holloway P H.Anisotropic growth of luminescent Eu3+or Er3+doped Gd2O3nanocrystals.Nanotechnology,2005,16 :2794–2798
41 Feng J,Sun X,Wu C Z,et al.Metallic few-layered VS2ultrathin nanosheets:High two-dimensional conductivity for in-plane supercapacitors.J Am Chem Soc,2011,133:17832–17838
42 Xiao X,Li T,Yang P,et al.Fiber-based all-solid-state flexible supercapacitors for self-powered systems.ACS Nano,2012,6:9200–9206
43 Liu B,Tan D S,Wang X F,et al.Flexible,planar-integrated,all-solid-state fiber supercapacitors with an enhanced distributed-capacitance effect.Small,2013,9:1998–2004
44 Peng L L,Peng X,Liu B R,et al.Ultrathin two-dimensional MnO2/graphene hybrid nanostructures for high-performance,flexible planar supercapacitors.Nano Lett,2013,13:2151–2157