低温SCR脱硝催化剂的研究
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摘要
综述了低温SCR脱硝催化剂的国内外研究现状,介绍了低温SCR脱硝催化剂的种类、反应机理及存在的问题,为制备性能更好的低温SCR脱硝催化剂提供依据。
In this paper,the research and development advances of low-temperature SCR denitrification catalyst in China and in the globe are reviewed. The types,reaction mechanism and existing problems of low-temperature SCR denitrification catalysts are introduced,which aims to provide information and reference for the preparation of lowtemperature SCR denitrification catalysts with better performance.
In this paper,the research and development advances of low-temperature SCR denitrification catalyst in China and in the globe are reviewed. The types,reaction mechanism and existing problems of low-temperature SCR denitrification catalysts are introduced,which aims to provide information and reference for the preparation of lowtemperature SCR denitrification catalysts with better performance.
引文
[1]李春雨.SCR脱硝催化剂研究及产业现状分析[J].能源工程,2014,(1):60-64.
[2]陈艳平,程党国,陈丰秋,等.Cu-ZSM-5分子筛催化分解及选择性催化还原NO[J].化学进展,2014,26(S1):248-258.
[3]高翔,卢徐节,胡明华.低温SCR脱硝催化剂综述[J].江汉大学学报:自然科学版,2014,42(2):12-18.
[4]闫瑞宁.SCR反应催化剂的要求及影响因素研究[J].科技创新导报,2017,(22):102-103.
[5]肖翠微,李婷.低温SCR锰系脱硝催化剂的研究进展[J].洁净煤技术,2016,22(1):95-100.
[6]Kapteijn F,Singoredjo L,Andreini A,et al.ChemInform abstract:Activity and selectivity of pure manganese oxides in the selective catalytic reduction of nitric oxide with ammonia[J].Cheminform,1994,3(2/3):173-189.
[7]陈志航,李雪辉,高翔,等.新型铬锰复合氧化物低温选择性催化氨还原NOx[J].催化学报,2009,30(1):4-6.
[8]陈焕章,李宏,李花.Mn-Co-Fe/Ti O2催化剂的制备及其低温脱硝性能的研究[J].化学工程,2016,44(8):6-10.
[9]Zhang G,Han W,Zhao H,et al.Solvothermal synthesis of well-designed ceria-tin-titanium catalysts with enhanced catalytic performance for wide temperature NH3-SCR reaction[J].Applied Catalysis B Environmental,2018,226:117-126.
[10]郭静,李彩亭,路培,等.CeO2改性Mn Ox/Al2O3的低温SCR法脱硝性能及机制研究[J].环境科学,2011,32(8):2240-2246.
[11]王晓波,伍士国,邹伟欣,等.Fe-Mn/Al2O3催化剂低温NH3选择性催化还原NO的性能[J].催化学报,2016,37(8):1314-1323.
[12]甘玲,刘琪琪,李建军,等.Fe掺杂Mn-Ce/AC催化剂的制备及其低温脱硝[J].环境工程学报,2017,11(1):445-449.
[13]陈九玉,朱宝忠,堵同宽,等.Co改性Fe2O3/AC催化剂低温SCR脱硝性能[J].有色金属工程,2017,7(2):99-102.
[14]唐剑骁,马丽萍,王冬东,等.微波对Cu-ZSM-5催化剂结构及低温NH3-SCR脱硝活性的影响[J].人工晶体学报,2017,46(8):1569-1574.
[15]黄增斌,李翠清,王振,等.不同分子筛负载锰铈催化剂的低温NH3-SCR脱硝性能[J].燃料化学学报,2016,44(11):1388-1393.
[16]Zhao S,Huang L,Jiang B,et al.Stability of Cu-Mn bimetal catalysts based on different zeolites for NOxremoval from diesel engine exhaust[J].Chinese Journal of Catalysis,2018,39(4):800-809.
[17]邢帅,姜宏,熊春荣,等.椰壳活性炭氧化后负载硅基复合氧化物低温脱硝催化剂的研究[J].分子催化,2016,30(2):140-150.
[18]Li X,Shi H,Zhu W,et al.Nanocomposite La Fe1-xNixO3/Palygorskite catalyst for photo-assisted reduction of NOx:Effect of Ni doping[J].Applied Catalysis B Environmental,2018,S092633731830198X.
[19]李金虎.凹凸棒石负载锰氧化物低温选择性催化还原NO[D].合肥:合肥工业大学,2010.
[20]Liu F,Shan W,Lian Z,et al.The smart surface modification of Fe2O3by WOxfor significantly promoting the selective catalytic reduction of NOxwith NH3[J].Applied Catalysis B Environmental,2018,230.
[21]Chen T,Guan B,Lin H,et al.In situ DRIFTS study of the mechanism of low temperature selective catalytic reduction over manganese-iron oxides[J].Chinese Journal of Catalysis,2014,35(3):294-301.
[22]Jiang Y,Gao X,Wu W H.Effects of H2O and SO2on the performance of V2O5/Ti O2catalysts for selective catalytic reduction of NOin flue gas[J].Proceedings of the Csee,2013,33(20):28-33.
[23]Zhu Z,Liu Z,Niu H,et al.Mechanism of SO2promotion for NO reduction with NH3over activated carbon-supported vanadium oxide catalyst[J].Journal of Catalysis,2001,197(1):6-16.
[24]Huang Z,Zhu Z,Liu Z.Combined effect of H2O and SO2on V2O5/AC catalysts for NO reduction with ammonia at lower temperatures[J].Applied Catalysis B Environmental,2002,39(4):361-368.
[25]Gao F,Tang X,Yi H,et al.Promotional mechanisms of activity and SO2tolerance of Co-or Ni-doped Mn Ox-CeO2catalysts for SCR of NOxwith NH3at low temperature[J].Chemical Engineering Journal,2017,317:20-31.
[26]Sun P,Guo R T,Liu S M,et al.The enhanced performance of MnOx catalyst for NH3-SCR reaction by the modification with Eu[J].Applied Catalysis A General,2016,531:129-138.
[2]陈艳平,程党国,陈丰秋,等.Cu-ZSM-5分子筛催化分解及选择性催化还原NO[J].化学进展,2014,26(S1):248-258.
[3]高翔,卢徐节,胡明华.低温SCR脱硝催化剂综述[J].江汉大学学报:自然科学版,2014,42(2):12-18.
[4]闫瑞宁.SCR反应催化剂的要求及影响因素研究[J].科技创新导报,2017,(22):102-103.
[5]肖翠微,李婷.低温SCR锰系脱硝催化剂的研究进展[J].洁净煤技术,2016,22(1):95-100.
[6]Kapteijn F,Singoredjo L,Andreini A,et al.ChemInform abstract:Activity and selectivity of pure manganese oxides in the selective catalytic reduction of nitric oxide with ammonia[J].Cheminform,1994,3(2/3):173-189.
[7]陈志航,李雪辉,高翔,等.新型铬锰复合氧化物低温选择性催化氨还原NOx[J].催化学报,2009,30(1):4-6.
[8]陈焕章,李宏,李花.Mn-Co-Fe/Ti O2催化剂的制备及其低温脱硝性能的研究[J].化学工程,2016,44(8):6-10.
[9]Zhang G,Han W,Zhao H,et al.Solvothermal synthesis of well-designed ceria-tin-titanium catalysts with enhanced catalytic performance for wide temperature NH3-SCR reaction[J].Applied Catalysis B Environmental,2018,226:117-126.
[10]郭静,李彩亭,路培,等.CeO2改性Mn Ox/Al2O3的低温SCR法脱硝性能及机制研究[J].环境科学,2011,32(8):2240-2246.
[11]王晓波,伍士国,邹伟欣,等.Fe-Mn/Al2O3催化剂低温NH3选择性催化还原NO的性能[J].催化学报,2016,37(8):1314-1323.
[12]甘玲,刘琪琪,李建军,等.Fe掺杂Mn-Ce/AC催化剂的制备及其低温脱硝[J].环境工程学报,2017,11(1):445-449.
[13]陈九玉,朱宝忠,堵同宽,等.Co改性Fe2O3/AC催化剂低温SCR脱硝性能[J].有色金属工程,2017,7(2):99-102.
[14]唐剑骁,马丽萍,王冬东,等.微波对Cu-ZSM-5催化剂结构及低温NH3-SCR脱硝活性的影响[J].人工晶体学报,2017,46(8):1569-1574.
[15]黄增斌,李翠清,王振,等.不同分子筛负载锰铈催化剂的低温NH3-SCR脱硝性能[J].燃料化学学报,2016,44(11):1388-1393.
[16]Zhao S,Huang L,Jiang B,et al.Stability of Cu-Mn bimetal catalysts based on different zeolites for NOxremoval from diesel engine exhaust[J].Chinese Journal of Catalysis,2018,39(4):800-809.
[17]邢帅,姜宏,熊春荣,等.椰壳活性炭氧化后负载硅基复合氧化物低温脱硝催化剂的研究[J].分子催化,2016,30(2):140-150.
[18]Li X,Shi H,Zhu W,et al.Nanocomposite La Fe1-xNixO3/Palygorskite catalyst for photo-assisted reduction of NOx:Effect of Ni doping[J].Applied Catalysis B Environmental,2018,S092633731830198X.
[19]李金虎.凹凸棒石负载锰氧化物低温选择性催化还原NO[D].合肥:合肥工业大学,2010.
[20]Liu F,Shan W,Lian Z,et al.The smart surface modification of Fe2O3by WOxfor significantly promoting the selective catalytic reduction of NOxwith NH3[J].Applied Catalysis B Environmental,2018,230.
[21]Chen T,Guan B,Lin H,et al.In situ DRIFTS study of the mechanism of low temperature selective catalytic reduction over manganese-iron oxides[J].Chinese Journal of Catalysis,2014,35(3):294-301.
[22]Jiang Y,Gao X,Wu W H.Effects of H2O and SO2on the performance of V2O5/Ti O2catalysts for selective catalytic reduction of NOin flue gas[J].Proceedings of the Csee,2013,33(20):28-33.
[23]Zhu Z,Liu Z,Niu H,et al.Mechanism of SO2promotion for NO reduction with NH3over activated carbon-supported vanadium oxide catalyst[J].Journal of Catalysis,2001,197(1):6-16.
[24]Huang Z,Zhu Z,Liu Z.Combined effect of H2O and SO2on V2O5/AC catalysts for NO reduction with ammonia at lower temperatures[J].Applied Catalysis B Environmental,2002,39(4):361-368.
[25]Gao F,Tang X,Yi H,et al.Promotional mechanisms of activity and SO2tolerance of Co-or Ni-doped Mn Ox-CeO2catalysts for SCR of NOxwith NH3at low temperature[J].Chemical Engineering Journal,2017,317:20-31.
[26]Sun P,Guo R T,Liu S M,et al.The enhanced performance of MnOx catalyst for NH3-SCR reaction by the modification with Eu[J].Applied Catalysis A General,2016,531:129-138.