相变材料的研究进展
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摘要
综述了相变材料的种类,并主要从相变机理、自身缺陷、改进方案等方面对无机、有机两大类相变材料进行了总结。概括了4种制备复合相变材料的工艺路线,简单介绍了相变材料在建筑节能、工业余热回收、调温纤维等领域的应用,最后对相变材料今后的研究方向进行了展望。
The types of phase change materials are reviewed,and the inorganic and organic phase change materials are summarized mainly from the aspects of phase transition mechanism,self-defects and improvement schemes.The process routes of four kinds of composite phase change materials were summarized.The application of phase change materials in building energy conservation,industrial waste heat recovery and temperature regulation fiber was briefly introduced.Finally,the future research directions of phase change materials were prospected.
The types of phase change materials are reviewed,and the inorganic and organic phase change materials are summarized mainly from the aspects of phase transition mechanism,self-defects and improvement schemes.The process routes of four kinds of composite phase change materials were summarized.The application of phase change materials in building energy conservation,industrial waste heat recovery and temperature regulation fiber was briefly introduced.Finally,the future research directions of phase change materials were prospected.
引文
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[23] Liu Xianzhi,Liu Lingzhi,Men Yongfeng.Synthesis and characterization of chitosan/paraffin phase change microcapsules[J].Applied Chemistry,2012,29(1):9-13(in Chinese).刘先之,刘凌志,门永锋.石蜡相变微胶囊的制备与表征[J].应用化学,2012,29(1):9-13.
[24] Zhong Y J,Guo Q G,Li S Z,et al.Heat transfer enhancement of paraffin wax using graphite foam for thermal energy storage[J].Solar Energy Materials&Solar Cells,2010,94(6):1011-1014.
[25] Tang X H,Zhu B,Xu M H,et al.Shape-stablilized phase change materials based on fatty acid eutectics/expanded graphite composites for thermal storage[J].Energy and Buildings,2015,109:353-360.
[26] Zhang J J,Zhang J L,He S M,et al.Thermal studies on the solid-liquid phase transition in binary system of fatty acids[J].Thermochim Acta,2011,369:157-160.
[27] Wu Shuying,Zhu Dongsheng, Wang Nan.Organic phase change materials:application and advances in improving their heat transfer performance[J].Mod Chem Ind,2009,29(10):19-23(in Chinese).吴淑英,朱冬生,汪南.改善有机储热材料传热性能的研究进展及应用[J].现代化工,2009,29(10):19-23.
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[29] Wang Lijiu,Tan Xiaoqian.Preparation and properties of clay-phase transition building materials[J].J Shenyang Univ Technol,2012,34(4):455-460(in Chinese).王立久,谭晓倩.粘土相变建筑材料制备及性能[J].沈阳工业大学学报,2012,34(4):455-460.
[30] Efimova A,Pinnau S,Mischke M,et al.Development of salt hydrate eutectics as latent heat storage for air conditioning and cooling[J].Thermochim Acta,2014(575):276-278.
[31] Xu Xiaolong,Niu Runping,Feng Guohui,et al.Study on the application of solar house and phase change energy storage technology[J].Cryogenic Construction Technology,2013,35(4):123-125(in Chinese).徐小龙,牛润萍,冯国会,等.太阳房与相变蓄能结合技术应用研究[J].低温建筑技术,2013,35(4):123-125.
[32] Wei Yuntang,Cui Haiting,Lyu Shuiyan,et al.Numerical and experimental analysis on heat storage and discharge characteristics of globular heat[J].Renewable Energy,2010,28(4):134-136(in Chinese).韦玉堂,崔海亭,吕水燕,等.球状蓄热体蓄放热性能的数值分析与实验[J].可再生能源,2010,28(4):134-136.
[33] Lafdi K,Mesalhy O,Elgafy A.Graphite foams infiltrated with phase change materials as alternative materials for space and terrestrial thermal energy storage application[J].Carbon,2008,46:159-168.
[34] Zhang X X,Li Y,Tao X M,et al.Interactive textiles regulate body temperature[J].Intern Textile Bulletin,1999,45(1):58-59.
[35] Li Zhao,Ye Guangdou,Xu Jianjun,et al.Preparation and charaterization of polyethylene glycol-polyvinly alcohol thermal regulating fiber[J].Synthetic Fiber in China,2015,44(7):14-18(in Chinese).李昭,叶光斗,徐建军,等.聚乙二醇-聚乙烯醇相变储能纤维的制备及其性能[J].合成纤维,2015,44(7):14-18.
[36] Wen Guoqing,Xie Rui,Ju Xiaojie,et al.Preparation and properties of MWNT/polyvinyl butyral composite phase change fibers[J].Chem Ind Eng Prog,2015,34(10):3688-3692(in Chinese).温国清,谢锐,巨晓洁,等.多壁碳纳米管/聚乙烯醇缩丁醛复合相变纤维的制备与性能[J].化工进展.,2015,34(10):3688-3692.
[37] Jiang Mengjin,Song Xiaoqing,Wang Bin,et al.Preparation of phase change energy storage as-spun PEG/PVA fiber by composite spinning[J].Chin Synth Fib Ind,2008,31(6):17-22(in Chinese).姜猛进,宋晓庆,王斌,等.复合纺丝法制备PEG/PVA相变储能初生纤维[J].合成纤维工业,2008,31(6):17-22.
[38] Aleksandrov V D,Sobolev A Y.Phasediagram of the Na2CO3·10H2O-Na2S2O3·5H2O system[J].Inorganic Materials,2014,50(7):686-690.
[2]张仁元,朱泽培,朱焕良,等.相变(复合)储能技术应用与开发可行性研究报告[R].广州:中国科学院广州能源研究所报,1988.
[3] Yu A P,Ramesh P,Itkis M E,et al.Graphite nanoplatelet-epoxy composite thermal interface materials[J].J Phys Chem C,2007,111(21):7565-7569.
[4]崔海亭,杨峰.储热技术及其应用[M].北京:化学工业出版社,2004:27.
[5] Sharma A,Shukla A,Chen C R,et al.Development of phase change materials(PCMs)for low temperature energy storage applications[J].Energy Technol,2014(7):17-21.
[6] Zhang Lizhi,Zhang Qing.Phase change heat storage materials[J].New Chemical Materials,1999,27(2):19-21(in Chinese).张丽芝,张庆.相变贮热材料[J].化工新型材料,1999,27(2):19-21.
[7] Guo Chaxiu,Liu Shulan.Review on intensifying heat transfer of phase change[J].Guangzhou Chemical Industry,2011,3(12):32-33(in Chinese).郭茶秀,刘树兰.固-液相变传热强化过程研究进展[J].广州化工,2011,3(12):32-33.
[8]张寅平,胡汉平,孔祥冬.相变贮能-理论和应用[M].合肥:中国科学技术大学出版社,1996.
[9] Hadjieva M,Stoykov R,Filipova T.Composite salt-hydrate concrete system for building energy storage[J].Renew Energy,2000,19(1):111-115.
[10] Ye Feng,Qu Jianglan,Zhong Junyu,et al.Research and development of phase change material(PCM)used as heat storing material[J].Chin J Proc Eng,2010,10(6):1231-1241(in Chinese).叶锋,曲江兰,仲俊喻,等.相变储热材料研究进展[J].过程工程学报,2010,10(6):1231-1241.
[11] Li Yunhong,Jiao Qingying,Xia Dingguo,et al.The study and applications of normal and low temperature phase change and heat storage materials[J].Chin J Chem Edu,2004,25(10):9-13(in Chinese).李玉红,焦庆影,夏定国,等.常低温先变储热材料的研究和应用[J].化学教育,2004,25(10):9-13.
[12] Ruan Deshui,Zhang Taiping,Zhang Daosheng,et al.Study on long-term heat storage using molten salt hydrates[J].Acta Energiae Solaris Sinica,1993,14(1):16-22(in Chinese).阮德水,张太平,张道圣,等.水合盐相变热长期贮存的研究[J].太阳能学报,1993,14(1):16-22.
[13] Wang Xin,Fang Jianhua,Jiang Zeqi,et al.Research progress of phase change energy storage fibers[J].Synthetic Fiber in China,2018,47(8):31-35(in Chinese).王鑫,方建华,江泽琦,等.相变储能纤维的研究进展[J].合成纤维,2018,47(8):31-35.
[14] Zhang Renyuan,Ke Xiufang.Preparation and performance of salt/ceramic composite energy storage material[J].Chinese Journal Of Materials Research,2000,14(6):652-656(in Chinese).张仁元,柯秀芳.无机盐/陶瓷基复合储能材料的制备和性能[J].材料研究学报,2000,14(6):652-656.
[15] Du Xiaodong,Zhang Xuelai,Ding Jinghong,et al.Effects of nanoparticles nucleating agents on the performance of sodium acetate trihydrate[J].Building Energy Efficiency,2017,45(9):25-28(in Chinese).杜晓东,章学来,丁锦宏,等.纳米成核剂对三水醋酸钠蓄热性能的影响[J].建筑节能,2017,45(9):25-28.
[16] Liu Y S,Yang Y Z.Use of nano-α-Al2O3to improve binary eutectic hydrated salt as phase change material[J].Solar Energy Materials&Solar Cells,2017(160):18-25.
[17]孙欣炎.结晶水合盐相变材料的研究[D].上海:华东理工大学,2014.
[18] Dutil Y,Rousse D R,Salah N B,et al.A review on phase-change materials:mathematical modeling and simulations[J].Renewable and Sustainable Energy Reviews,2011,15(1):112-130.
[19] Sharma A,Tyagi V V,Chen C R,et al.Review on thermal energy storage with phase change materials and applications[J].Renewable and Sustainable Energy Reviews,2009,13(2):318-345.
[20]胡小东.五水硫代硫酸钠相变蓄热材料的制备及其性能研究[D].广州:湖南理工大学,2014.
[21] Xu Weiliang.Phase-change heat storage of sodium acetate hydrate[J].Science and Technology Bulletin,1999,15(4):287-291(in Chinese).徐伟亮.水合乙酸钠相变蓄热研究[J].科技通报,1999,15(4):287-291.
[22] Chen Aiying,Wang Xueying,Cao Xuezeng.Research and application of phase change material(PCM)used as energy storing material[J].Materials Review,2003,17(5):42-44(in Chinese).陈爱英,汪学英,曹学增.相变储能材料的研究进展与应用[J].材料导报,2003,17(5):42-44.
[23] Liu Xianzhi,Liu Lingzhi,Men Yongfeng.Synthesis and characterization of chitosan/paraffin phase change microcapsules[J].Applied Chemistry,2012,29(1):9-13(in Chinese).刘先之,刘凌志,门永锋.石蜡相变微胶囊的制备与表征[J].应用化学,2012,29(1):9-13.
[24] Zhong Y J,Guo Q G,Li S Z,et al.Heat transfer enhancement of paraffin wax using graphite foam for thermal energy storage[J].Solar Energy Materials&Solar Cells,2010,94(6):1011-1014.
[25] Tang X H,Zhu B,Xu M H,et al.Shape-stablilized phase change materials based on fatty acid eutectics/expanded graphite composites for thermal storage[J].Energy and Buildings,2015,109:353-360.
[26] Zhang J J,Zhang J L,He S M,et al.Thermal studies on the solid-liquid phase transition in binary system of fatty acids[J].Thermochim Acta,2011,369:157-160.
[27] Wu Shuying,Zhu Dongsheng, Wang Nan.Organic phase change materials:application and advances in improving their heat transfer performance[J].Mod Chem Ind,2009,29(10):19-23(in Chinese).吴淑英,朱冬生,汪南.改善有机储热材料传热性能的研究进展及应用[J].现代化工,2009,29(10):19-23.
[28] Xu Weiliang.Development and application of solid-liquid phase change materials at constant low temperatures[J].Modern Chemical Engineering,1998,(4):14-16(in Chinese).徐伟亮.常低温固-液相变材料的研制和应用[J].现代化工,1998,(4):14-16.
[29] Wang Lijiu,Tan Xiaoqian.Preparation and properties of clay-phase transition building materials[J].J Shenyang Univ Technol,2012,34(4):455-460(in Chinese).王立久,谭晓倩.粘土相变建筑材料制备及性能[J].沈阳工业大学学报,2012,34(4):455-460.
[30] Efimova A,Pinnau S,Mischke M,et al.Development of salt hydrate eutectics as latent heat storage for air conditioning and cooling[J].Thermochim Acta,2014(575):276-278.
[31] Xu Xiaolong,Niu Runping,Feng Guohui,et al.Study on the application of solar house and phase change energy storage technology[J].Cryogenic Construction Technology,2013,35(4):123-125(in Chinese).徐小龙,牛润萍,冯国会,等.太阳房与相变蓄能结合技术应用研究[J].低温建筑技术,2013,35(4):123-125.
[32] Wei Yuntang,Cui Haiting,Lyu Shuiyan,et al.Numerical and experimental analysis on heat storage and discharge characteristics of globular heat[J].Renewable Energy,2010,28(4):134-136(in Chinese).韦玉堂,崔海亭,吕水燕,等.球状蓄热体蓄放热性能的数值分析与实验[J].可再生能源,2010,28(4):134-136.
[33] Lafdi K,Mesalhy O,Elgafy A.Graphite foams infiltrated with phase change materials as alternative materials for space and terrestrial thermal energy storage application[J].Carbon,2008,46:159-168.
[34] Zhang X X,Li Y,Tao X M,et al.Interactive textiles regulate body temperature[J].Intern Textile Bulletin,1999,45(1):58-59.
[35] Li Zhao,Ye Guangdou,Xu Jianjun,et al.Preparation and charaterization of polyethylene glycol-polyvinly alcohol thermal regulating fiber[J].Synthetic Fiber in China,2015,44(7):14-18(in Chinese).李昭,叶光斗,徐建军,等.聚乙二醇-聚乙烯醇相变储能纤维的制备及其性能[J].合成纤维,2015,44(7):14-18.
[36] Wen Guoqing,Xie Rui,Ju Xiaojie,et al.Preparation and properties of MWNT/polyvinyl butyral composite phase change fibers[J].Chem Ind Eng Prog,2015,34(10):3688-3692(in Chinese).温国清,谢锐,巨晓洁,等.多壁碳纳米管/聚乙烯醇缩丁醛复合相变纤维的制备与性能[J].化工进展.,2015,34(10):3688-3692.
[37] Jiang Mengjin,Song Xiaoqing,Wang Bin,et al.Preparation of phase change energy storage as-spun PEG/PVA fiber by composite spinning[J].Chin Synth Fib Ind,2008,31(6):17-22(in Chinese).姜猛进,宋晓庆,王斌,等.复合纺丝法制备PEG/PVA相变储能初生纤维[J].合成纤维工业,2008,31(6):17-22.
[38] Aleksandrov V D,Sobolev A Y.Phasediagram of the Na2CO3·10H2O-Na2S2O3·5H2O system[J].Inorganic Materials,2014,50(7):686-690.