九龙江流域河水溶解态碳的时空变化
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摘要
为了研究九龙江流域河流中溶解碳变化规律,分别于2017年7月与2018年1月对九龙江河水溶解无机碳(DIC)与溶解有机碳(DOC)进行了分析。丰水季河水DIC浓度为7. 50~49. 04 mg/L,平均值为22. 12 mg/L,枯水季DIC浓度为8. 84~84. 91 mg/L,平均浓度41. 17 mg/L,丰水季河水中的DOC浓度为0. 54~2. 89 mg/L,平均值为1. 04 mg/L,枯水季河水中DOC浓度变化在1. 34~3. 56 mg/L之间,平均值为2. 34 mg/L,据此计算了九龙江河水DOC、DIC的入海通量。研究结果表明九龙江河水中溶解碳具有显著的时空变化特征,通过与中国其他河流溶解碳数据对比,解释了碳酸盐岩的风化、气候变化、河流中浮游植物以及人类活动对九龙江河流溶解碳浓度的影响。
In order to study the variations of dissolved carbon in Jiulongjiang River,the water samples were collected in July 2017 and January 2018,respectively,and dissolved inorganic carbon( DIC) and dissolved organic carbon( DOC) in rivers waters were also analyzed. The concentrations of DIC in river water are between7. 50 and 49. 04 mg/L in the wet season,and the average value is 22. 12 mg/L. The DIC concentrations in the dry season are between 8. 84 and 84. 912 mg/L and the average value is 41. 17 mg/L. The DOC concentrations in the river water during the wet season are between 0. 54 and 2. 89 mg/L,average concentration is 1. 04 mg/L,dry season water DOC concentrations are and 1. 34-3. 56 mg/L,average concentration is 2. 34 mg/L. The results show that the dissolved carbon in Jiulongjiang River has significant temporal and spatial characteristics. On the base of the discharge of Jiulongjiang River,we also calculated budget of dissolved carbon to the sea. This paper analyzes the dissolved carbon data from different tributaries in the Jiulongjiang River,combines with previous dissolved carbon data from other rivers in China,we disclose the controlling factors of dissolved carbon in river waters. And we also understand the effects of weathering of carbonate rocks, climate change,phytoplankton in rivers,and human activities on dissolved carbon concentrations in rivers.
In order to study the variations of dissolved carbon in Jiulongjiang River,the water samples were collected in July 2017 and January 2018,respectively,and dissolved inorganic carbon( DIC) and dissolved organic carbon( DOC) in rivers waters were also analyzed. The concentrations of DIC in river water are between7. 50 and 49. 04 mg/L in the wet season,and the average value is 22. 12 mg/L. The DIC concentrations in the dry season are between 8. 84 and 84. 912 mg/L and the average value is 41. 17 mg/L. The DOC concentrations in the river water during the wet season are between 0. 54 and 2. 89 mg/L,average concentration is 1. 04 mg/L,dry season water DOC concentrations are and 1. 34-3. 56 mg/L,average concentration is 2. 34 mg/L. The results show that the dissolved carbon in Jiulongjiang River has significant temporal and spatial characteristics. On the base of the discharge of Jiulongjiang River,we also calculated budget of dissolved carbon to the sea. This paper analyzes the dissolved carbon data from different tributaries in the Jiulongjiang River,combines with previous dissolved carbon data from other rivers in China,we disclose the controlling factors of dissolved carbon in river waters. And we also understand the effects of weathering of carbonate rocks, climate change,phytoplankton in rivers,and human activities on dissolved carbon concentrations in rivers.
引文
[1]耿元波,董云社,孟维奇.陆地碳循环研究进展[J].地理科学进展,2000,19(4):297-306.GENG Y B,DONG Y S,MENG W Q.Progress of terrestrial carbon cycle sdudies[J].Progress in Geography,2003,200(3):203-216.
[2]BARTH J A C,CRONIN A A,DUNLOP J,et al.Influence of carbonates on the riverine carbon cycle in an anthropogenically dominated catchment basin:evidence from major elements and stable carbon isotopes in the Lagan River(N.Ireland)[J].Chemical Geology,2003,200(3):203-216.
[3]张永领.河流有机碳循环研究综述[J].河南理工大学学报(自然科学版),2012,31(3):344-351.ZHANG Y L.The review of the research of the riverine organic carbon cycle[J].Journal of Henan Polytechnic University(Natural Science),2012,31(3):344-351.
[4]WOLFGANG L,JEANLUC P,STEFAN K.Predicting the oceanic input of organic carbon by continental erosion[J].Global Biogeochemical Cycles,1996,10(1):23-41.
[5]LEE D,VEIZER J.Water and carbon cycles in the Mississippi River basin:Potential implications for the Northern Hemisphere residual terrestrial sink[J].Global Biogeochemical Cycles,2003,17(2).
[6]CAUWET G,MACKENZIE F T.Carbon inputs and distribution in estuaries of turbid rivers:the Yang Tze and Yellow rivers(China)[J].Marine Chemistry,1993,43(1-4):235-246.
[7]CLAIR T A,POLLOCK T L,EHRMAN J M.Exports of carbon and nitrogen from river basins in Canada's Atlantic Provinces[J].Global Biogeochemical Cycles,1994,8(4):441-450.
[8]孙平安,于奭,莫付珍,等.不同地质背景下河流水化学特征及影响因素研究:以广西大溶江、灵渠流域为例[J].环境科学,2016,37(1):123-131.SUN P A,YU S,MO F Z,et al.Hydrochemical characteristics and influencing factors in different geological background:a case study in darongjiang and Lingqu Basin,Guangxi,China[j].Environmental Science,2016,37(1):123-131.
[9]LI S L,LIU C Q,LI J,et al.Geochemistry of dissolved inorganic carbon and carbonate weathering in a small typical karstic catchment of Southwest China:Isotopic and chemical constraints[J].Chemical Geology,2010,277(3):301-309.
[10]SUCHET P A,PROBST J L.A global model for present-day atmospheric/soil CO2consumption by chemical erosion of continental rocks(GEM-CO2)[J].Tellus,1995,47(1-2):273-280.
[11]CHAO Y,KEVIN T,JN V.Chemical dynamics of the“St.Lawrence”riverine system:δDH2O,δ18OH2O,δ13CDIC,δ34Ssulfate,and dissolved87Sr/86Sr[J].Geochimica et Cosmochimica Acta,1996,60(5):851-866.
[12]ECKHARDT B W,MOORE T R.Controls on dissolved organic carbon concentrations in streams,Southern Québec[J].Canadian Journal of Fisheries&Aquatic Sciences,1990,47(8):1537-1544.
[13]DALVA M,MOORE T R.Sources and sinks of dissolved organic carbon in a forested swamp catchment[J].Biogeochemistry,1991,15(1):1-19.
[14]GUYOT J L,WASSON J G.Regional pattern of riverine dissolved organic carbon in the Amazon Drainage Basin of Bolivia[J].Limnology&Oceanography,1994,39(2):452-458.
[15]KALBITZ K,SOLINGER S,PARK J H,et al.Controls on the dynamics of dissolved organic matter in soils:a review.[J].Soil Science,2000,165(4):277-304.
[16]刘岩,侯广利,孙继昌,等.水质总有机碳(TOC)分析方法的研究[J].山东科学,2005(5):1-5.LIU Y,HOU G L,SUN J CH,et al.Study on analysis approach of Total Organic Carbon(TOC)in water[J].Shandong Science,2005(5):1-5.
[17]ROBARDS K,MCKELVIE I D,BENSON R L,et al.Determination of carbon,phosphorus,nitrogen and silicon species in waters[J].Analytica Chimica Acta,1994,287(3):147-190.
[18]JANSSON M,PERSSON L,DE ROOS A M,et al.Terrestrial carbon and intraspecific size-variation shape lake ecosystems[J].Trends in Ecology&Evolution,2007,22(6):316-322.
[19]潘文俊,曹文志,王飞飞,等.基于水足迹理论的九龙江流域水资源评价[J].资源科学,2012,34(10):1905-1912.PAN W J,CAO W Z,WANG F F,et al.Evaluation of water resource utilization in the Jiulong River Basin Based on water footprint theory[J].Resources Science,2012,34(10):1905-1912.
[20]陈能汪,张珞平,洪华生,等.九龙江流域农村生活污水污染定量研究[J].厦门大学学报(自然版),2004,43(s1):249-253.CHEN N W,ZHANG L P,HONG H S,et al.Estimates of household wastewater loads from Jiulong River Watershed[J].Journal of Xiamen University(Natural Science),2004,43(s1):249-253.
[21]张莉,祁士华,瞿程凯,等.福建九龙江流域重金属分布来源及健康风险评价[J].中国环境科学,2014,34(8):2133-2139.ZHANG L,QI S L,QU C K,et al.Distribution,source and health risk assessment of heavy metals in the water of Jiulong River,Fujian[J].China Environmental Science,2014,34(8):2133-2139.
[22]李晓强,韩贵琳,董爱国,等.九龙江丰水期水化学组成特征及其控制因素[J].生态学杂志,2018,37(3):697-706.LI X Q,HAN G L,DONG A G,et al.Hydrogeochemical characteristics and controlling factors in Jiulong River(Fujian Province)during the flood season[J].Chinese Journal of Ecology,2018,37(3):697-706.
[23]花育明,郑生.福建九龙江流域环境审计研究[J].审计研究,2013(02)46-51.HUA Y M,ZHENG S.Research on Jiulong River Basin environmental audit[J].Auditing Research,2013(02)46-51.
[24]HUANG J,ZHANG Z,FENG Y,C2013.Hydrologic response to climate change and human activities in a subtropical coastal watershed of southeast China[J].Regional Environmental Change,13:1195-1210.
[25]卢清地,朱根灵,秦正永.福建中-新生代玄武岩的地球化学特征及其成因[J].中国区域地质,2000,19(1):85-91.LU Q D,ZHU G L,QING Z Y.Geochemical feature and genesis of the Mesozoic and Cenozoic basalt in Fujian Province[J].Regional Geology of China,2000,19(1):85-91.
[26]张振杰,左仁广.闽西南地区大地构造演化和矿床时空分布规律[J].岩石学报,2015,31(01):217-229.ZHANG Z J,ZUO R G.Tectonic evolution of southwestern Fujian Province and spatial-temporal distribution regularity of mineral deposits[J].Acta Petrologica Sinica,2015,31(01):217-229.
[27]JIN Z,YOU C F,YU J,et al.Seasonal contributions of catchment weathering and eolian dust to river water chemistry,northeastern Tibetan Plateau:Chemical and Sr isotopic constraints[J].Journal of Geophysical Research Earth Surface,2011,116(F4).
[28]WHITE A F,BLUM A E.Effects of climate on chemical weathering in watersheds[J].Geochimica et Cosmochimica Acta,1995,59(9):1729-1747.
[29]梁翠翠.九龙江干流-河口水体溶解无机碳含量及其碳稳定同位素地球化学特征[D].厦门大学,2015.LIANG C C.Geochemical characteristics of dissolved inorganic carbon and its carbon stable isotopes in estuaries[D].Xiamen University,2015.
[30]黄秀琴.九龙江流域水文特性[J].水利科技,2008(1):20-21,24.HUANG X Q.Hydrological characteristics of Jiulongjiang Basin[J].Water Conservancy Technology,2008(1):20-21,24.
[31]SINGH S K,FRANCE-LANORD C,SARIN M M.Chemical erosion in the eastern Himalaya:Major ion composition of the Brahmaputra andδ13C of dissolved inorganic carbon[J].Geochimica et Cosmochimica Acta,2005,69(14):3573-3588.
[32]GAILLARDET J,CALMELS D.Sulfuric acid as a weathering agent of carbonate weathering constrained byδ13C:Examples from Southwest China[J].Acta Geochimica,2006,25(s1):270-271.
[33]王骏博.溶解有机碳同位素测定方法研究及其在九龙江的应用[D].国家海洋局第三海洋研究所,2015.WANG J B.Determination of dissolved organic carbon isotope and its application in Jiulongjiang[D].Third Institute of Oceanography,State Oceanic Administration.
[34]TELMER K,VEIZER J.Carbon fluxes,pCO2,and substrate weathering in a large northern river basin,Canada:carbon isotope perspectives[J].Chemical Geology,1999,159(1-4):61-86.
[35]AUCOUR A M,SHEPPARD S M F,GUYOMAR O,et al.Use of,ja:math,to trace origin and cycling of inorganic carbon in the Rh8ne river system[J].Chemical Geology,1999,159(1-4):87-105.
[36]TIPPER E T,BICKLE M J,GALY A,et al.The short term climatic sensitivity of carbonate and silicate weathering fluxes:Insight from seasonal variations in river chemistry[J].Geochimica et Cosmochimica Acta,2006,70(11):2737-2754.
[37]XING J W,XIAN W W,SHENG X Z.Distribution and source of particulate organic carbon and particulate nitrogen in the Yangtze River Estuary in summer 2012[J].Environmental Science,2014,35(7):2520.
[38]俞超超.九龙江河流-库区系统浮游植物群落组成及其磷胁迫研究[D].厦门大学,2014.YU C C.Phytoplankton community composition and phosphorus stress in Jiulongjiang River and reservoir system[D].Xiamen University,2014.
[39]唐文魁,陶贞,高全洲,等.桂江主要离子及溶解无机碳的生物地球化学过程[J].环境科学,2014,35(6):2099-2107.TANG W K,TAO Z,GAO Q ZH,et al.Biogeochemical processes of the major ions and dissolved inorganic carbon in the Guijiang River[J].Environmental Science,2014,35(6):2099-2107.
[40]黄奇波,覃小群,唐萍萍,等.桂江流域河流有机碳特征[J].地质科技情报,2014(2):148-153.HUANG Q B,TAN X Q,TANG P P,et al.Characteristics of organic carbon in rivers of Guangxi River Basin[J].Geological Science and Technology Information,2014(2):148-153.
[41]焦树林,高全洲,刘昆.珠江流域西江、北江河流溶解无机碳及其稳定同位素组成特征[J].中山大学学报(自然科学版),2009,48(2):99-105.JIAO S L,GAO Q Z,LIU K.Riverine DIC and itsδ13C DIC of the Xijiang and the Beijiang tributaries in the Pearl River Basin,South China[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2009,48(2):99-105.
[42]张连凯,覃小群,杨慧,等.珠江流域河流碳输出通量及变化特征[J].环境科学,2013,34(8):3025-3034.ZHANG L K,TAN X Q,YANG H,et al.Transported fluxes of the riverine carbon and seasonal variation in Pearl River Basin[J].Environmental Science,2013,34(8):3025-3034.
[43]王敏.长江主流碳的时空输运特征及三峡工程对其影响[D].中国海洋大学,2010.WANG M.Temporal and spatial transport characteristics of mainstream carbon in the Yangtze River and its impact on the Three Gorges Project[D].Chinese Marine University,2010.
[44]李军,刘丛强,李龙波,等.硫酸侵蚀碳酸盐岩对长江河水DIC循环的影响[J].地球化学,2010,39(4):305-313.LI J,LIU C Q,LI L B,et al.The impacts of chemical weathering of carbonate rock by sulfuric acid on the cycling of dissolved inorganic carbon in Changjiang River water[J].Geochimica,2010,39(4):305-313.
[45]李军,刘丛强,李思亮.长江水系河水化学侵蚀的水化学和碳同位素证据[J].矿物岩石地球化学通报,2007,26.LI J,LIU C Q,LI S L.Hydrochemical and carbon isotope evidence for chemical erosion of river water in the Yangtze River System[J].Bulletin of Mineralogy,Petrology and Geochemistry2007,26.
[46]苏征.黄河主流碳的时空分布及通量研究[D].中国海洋大学,2005.SUN Z.Temporal and spatial distribution and flux of mainstream carbon in the Yellow River[D].Chinese Marine University,2005.
[47]温志超.夏季黄河流域化学风化及无机碳输运研究[D].中国海洋大学,2009.WEN Z C.Chemical weathering and inorganic carbon transport in the Yellow River basin in summer[D].Chinese Marine University,2005.
[48]WEI J,GUO Z,XIANG H,et al.A comparative overview of weathering intensity and HCO-3flux in the world's major rivers with emphasis on the Changjiang,Huanghe,Zhujiang(Pearl)and Mississippi Rivers[J].Continental Shelf Research,2008,28(12):1538-1549.
[49]MEYBECK M.Carbon,nitrogen,and phosphorus transport by world rivers[J].American Journal of Science,1982,282(4):401-450.
[2]BARTH J A C,CRONIN A A,DUNLOP J,et al.Influence of carbonates on the riverine carbon cycle in an anthropogenically dominated catchment basin:evidence from major elements and stable carbon isotopes in the Lagan River(N.Ireland)[J].Chemical Geology,2003,200(3):203-216.
[3]张永领.河流有机碳循环研究综述[J].河南理工大学学报(自然科学版),2012,31(3):344-351.ZHANG Y L.The review of the research of the riverine organic carbon cycle[J].Journal of Henan Polytechnic University(Natural Science),2012,31(3):344-351.
[4]WOLFGANG L,JEANLUC P,STEFAN K.Predicting the oceanic input of organic carbon by continental erosion[J].Global Biogeochemical Cycles,1996,10(1):23-41.
[5]LEE D,VEIZER J.Water and carbon cycles in the Mississippi River basin:Potential implications for the Northern Hemisphere residual terrestrial sink[J].Global Biogeochemical Cycles,2003,17(2).
[6]CAUWET G,MACKENZIE F T.Carbon inputs and distribution in estuaries of turbid rivers:the Yang Tze and Yellow rivers(China)[J].Marine Chemistry,1993,43(1-4):235-246.
[7]CLAIR T A,POLLOCK T L,EHRMAN J M.Exports of carbon and nitrogen from river basins in Canada's Atlantic Provinces[J].Global Biogeochemical Cycles,1994,8(4):441-450.
[8]孙平安,于奭,莫付珍,等.不同地质背景下河流水化学特征及影响因素研究:以广西大溶江、灵渠流域为例[J].环境科学,2016,37(1):123-131.SUN P A,YU S,MO F Z,et al.Hydrochemical characteristics and influencing factors in different geological background:a case study in darongjiang and Lingqu Basin,Guangxi,China[j].Environmental Science,2016,37(1):123-131.
[9]LI S L,LIU C Q,LI J,et al.Geochemistry of dissolved inorganic carbon and carbonate weathering in a small typical karstic catchment of Southwest China:Isotopic and chemical constraints[J].Chemical Geology,2010,277(3):301-309.
[10]SUCHET P A,PROBST J L.A global model for present-day atmospheric/soil CO2consumption by chemical erosion of continental rocks(GEM-CO2)[J].Tellus,1995,47(1-2):273-280.
[11]CHAO Y,KEVIN T,JN V.Chemical dynamics of the“St.Lawrence”riverine system:δDH2O,δ18OH2O,δ13CDIC,δ34Ssulfate,and dissolved87Sr/86Sr[J].Geochimica et Cosmochimica Acta,1996,60(5):851-866.
[12]ECKHARDT B W,MOORE T R.Controls on dissolved organic carbon concentrations in streams,Southern Québec[J].Canadian Journal of Fisheries&Aquatic Sciences,1990,47(8):1537-1544.
[13]DALVA M,MOORE T R.Sources and sinks of dissolved organic carbon in a forested swamp catchment[J].Biogeochemistry,1991,15(1):1-19.
[14]GUYOT J L,WASSON J G.Regional pattern of riverine dissolved organic carbon in the Amazon Drainage Basin of Bolivia[J].Limnology&Oceanography,1994,39(2):452-458.
[15]KALBITZ K,SOLINGER S,PARK J H,et al.Controls on the dynamics of dissolved organic matter in soils:a review.[J].Soil Science,2000,165(4):277-304.
[16]刘岩,侯广利,孙继昌,等.水质总有机碳(TOC)分析方法的研究[J].山东科学,2005(5):1-5.LIU Y,HOU G L,SUN J CH,et al.Study on analysis approach of Total Organic Carbon(TOC)in water[J].Shandong Science,2005(5):1-5.
[17]ROBARDS K,MCKELVIE I D,BENSON R L,et al.Determination of carbon,phosphorus,nitrogen and silicon species in waters[J].Analytica Chimica Acta,1994,287(3):147-190.
[18]JANSSON M,PERSSON L,DE ROOS A M,et al.Terrestrial carbon and intraspecific size-variation shape lake ecosystems[J].Trends in Ecology&Evolution,2007,22(6):316-322.
[19]潘文俊,曹文志,王飞飞,等.基于水足迹理论的九龙江流域水资源评价[J].资源科学,2012,34(10):1905-1912.PAN W J,CAO W Z,WANG F F,et al.Evaluation of water resource utilization in the Jiulong River Basin Based on water footprint theory[J].Resources Science,2012,34(10):1905-1912.
[20]陈能汪,张珞平,洪华生,等.九龙江流域农村生活污水污染定量研究[J].厦门大学学报(自然版),2004,43(s1):249-253.CHEN N W,ZHANG L P,HONG H S,et al.Estimates of household wastewater loads from Jiulong River Watershed[J].Journal of Xiamen University(Natural Science),2004,43(s1):249-253.
[21]张莉,祁士华,瞿程凯,等.福建九龙江流域重金属分布来源及健康风险评价[J].中国环境科学,2014,34(8):2133-2139.ZHANG L,QI S L,QU C K,et al.Distribution,source and health risk assessment of heavy metals in the water of Jiulong River,Fujian[J].China Environmental Science,2014,34(8):2133-2139.
[22]李晓强,韩贵琳,董爱国,等.九龙江丰水期水化学组成特征及其控制因素[J].生态学杂志,2018,37(3):697-706.LI X Q,HAN G L,DONG A G,et al.Hydrogeochemical characteristics and controlling factors in Jiulong River(Fujian Province)during the flood season[J].Chinese Journal of Ecology,2018,37(3):697-706.
[23]花育明,郑生.福建九龙江流域环境审计研究[J].审计研究,2013(02)46-51.HUA Y M,ZHENG S.Research on Jiulong River Basin environmental audit[J].Auditing Research,2013(02)46-51.
[24]HUANG J,ZHANG Z,FENG Y,C2013.Hydrologic response to climate change and human activities in a subtropical coastal watershed of southeast China[J].Regional Environmental Change,13:1195-1210.
[25]卢清地,朱根灵,秦正永.福建中-新生代玄武岩的地球化学特征及其成因[J].中国区域地质,2000,19(1):85-91.LU Q D,ZHU G L,QING Z Y.Geochemical feature and genesis of the Mesozoic and Cenozoic basalt in Fujian Province[J].Regional Geology of China,2000,19(1):85-91.
[26]张振杰,左仁广.闽西南地区大地构造演化和矿床时空分布规律[J].岩石学报,2015,31(01):217-229.ZHANG Z J,ZUO R G.Tectonic evolution of southwestern Fujian Province and spatial-temporal distribution regularity of mineral deposits[J].Acta Petrologica Sinica,2015,31(01):217-229.
[27]JIN Z,YOU C F,YU J,et al.Seasonal contributions of catchment weathering and eolian dust to river water chemistry,northeastern Tibetan Plateau:Chemical and Sr isotopic constraints[J].Journal of Geophysical Research Earth Surface,2011,116(F4).
[28]WHITE A F,BLUM A E.Effects of climate on chemical weathering in watersheds[J].Geochimica et Cosmochimica Acta,1995,59(9):1729-1747.
[29]梁翠翠.九龙江干流-河口水体溶解无机碳含量及其碳稳定同位素地球化学特征[D].厦门大学,2015.LIANG C C.Geochemical characteristics of dissolved inorganic carbon and its carbon stable isotopes in estuaries[D].Xiamen University,2015.
[30]黄秀琴.九龙江流域水文特性[J].水利科技,2008(1):20-21,24.HUANG X Q.Hydrological characteristics of Jiulongjiang Basin[J].Water Conservancy Technology,2008(1):20-21,24.
[31]SINGH S K,FRANCE-LANORD C,SARIN M M.Chemical erosion in the eastern Himalaya:Major ion composition of the Brahmaputra andδ13C of dissolved inorganic carbon[J].Geochimica et Cosmochimica Acta,2005,69(14):3573-3588.
[32]GAILLARDET J,CALMELS D.Sulfuric acid as a weathering agent of carbonate weathering constrained byδ13C:Examples from Southwest China[J].Acta Geochimica,2006,25(s1):270-271.
[33]王骏博.溶解有机碳同位素测定方法研究及其在九龙江的应用[D].国家海洋局第三海洋研究所,2015.WANG J B.Determination of dissolved organic carbon isotope and its application in Jiulongjiang[D].Third Institute of Oceanography,State Oceanic Administration.
[34]TELMER K,VEIZER J.Carbon fluxes,pCO2,and substrate weathering in a large northern river basin,Canada:carbon isotope perspectives[J].Chemical Geology,1999,159(1-4):61-86.
[35]AUCOUR A M,SHEPPARD S M F,GUYOMAR O,et al.Use of,ja:math,to trace origin and cycling of inorganic carbon in the Rh8ne river system[J].Chemical Geology,1999,159(1-4):87-105.
[36]TIPPER E T,BICKLE M J,GALY A,et al.The short term climatic sensitivity of carbonate and silicate weathering fluxes:Insight from seasonal variations in river chemistry[J].Geochimica et Cosmochimica Acta,2006,70(11):2737-2754.
[37]XING J W,XIAN W W,SHENG X Z.Distribution and source of particulate organic carbon and particulate nitrogen in the Yangtze River Estuary in summer 2012[J].Environmental Science,2014,35(7):2520.
[38]俞超超.九龙江河流-库区系统浮游植物群落组成及其磷胁迫研究[D].厦门大学,2014.YU C C.Phytoplankton community composition and phosphorus stress in Jiulongjiang River and reservoir system[D].Xiamen University,2014.
[39]唐文魁,陶贞,高全洲,等.桂江主要离子及溶解无机碳的生物地球化学过程[J].环境科学,2014,35(6):2099-2107.TANG W K,TAO Z,GAO Q ZH,et al.Biogeochemical processes of the major ions and dissolved inorganic carbon in the Guijiang River[J].Environmental Science,2014,35(6):2099-2107.
[40]黄奇波,覃小群,唐萍萍,等.桂江流域河流有机碳特征[J].地质科技情报,2014(2):148-153.HUANG Q B,TAN X Q,TANG P P,et al.Characteristics of organic carbon in rivers of Guangxi River Basin[J].Geological Science and Technology Information,2014(2):148-153.
[41]焦树林,高全洲,刘昆.珠江流域西江、北江河流溶解无机碳及其稳定同位素组成特征[J].中山大学学报(自然科学版),2009,48(2):99-105.JIAO S L,GAO Q Z,LIU K.Riverine DIC and itsδ13C DIC of the Xijiang and the Beijiang tributaries in the Pearl River Basin,South China[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2009,48(2):99-105.
[42]张连凯,覃小群,杨慧,等.珠江流域河流碳输出通量及变化特征[J].环境科学,2013,34(8):3025-3034.ZHANG L K,TAN X Q,YANG H,et al.Transported fluxes of the riverine carbon and seasonal variation in Pearl River Basin[J].Environmental Science,2013,34(8):3025-3034.
[43]王敏.长江主流碳的时空输运特征及三峡工程对其影响[D].中国海洋大学,2010.WANG M.Temporal and spatial transport characteristics of mainstream carbon in the Yangtze River and its impact on the Three Gorges Project[D].Chinese Marine University,2010.
[44]李军,刘丛强,李龙波,等.硫酸侵蚀碳酸盐岩对长江河水DIC循环的影响[J].地球化学,2010,39(4):305-313.LI J,LIU C Q,LI L B,et al.The impacts of chemical weathering of carbonate rock by sulfuric acid on the cycling of dissolved inorganic carbon in Changjiang River water[J].Geochimica,2010,39(4):305-313.
[45]李军,刘丛强,李思亮.长江水系河水化学侵蚀的水化学和碳同位素证据[J].矿物岩石地球化学通报,2007,26.LI J,LIU C Q,LI S L.Hydrochemical and carbon isotope evidence for chemical erosion of river water in the Yangtze River System[J].Bulletin of Mineralogy,Petrology and Geochemistry2007,26.
[46]苏征.黄河主流碳的时空分布及通量研究[D].中国海洋大学,2005.SUN Z.Temporal and spatial distribution and flux of mainstream carbon in the Yellow River[D].Chinese Marine University,2005.
[47]温志超.夏季黄河流域化学风化及无机碳输运研究[D].中国海洋大学,2009.WEN Z C.Chemical weathering and inorganic carbon transport in the Yellow River basin in summer[D].Chinese Marine University,2005.
[48]WEI J,GUO Z,XIANG H,et al.A comparative overview of weathering intensity and HCO-3flux in the world's major rivers with emphasis on the Changjiang,Huanghe,Zhujiang(Pearl)and Mississippi Rivers[J].Continental Shelf Research,2008,28(12):1538-1549.
[49]MEYBECK M.Carbon,nitrogen,and phosphorus transport by world rivers[J].American Journal of Science,1982,282(4):401-450.