调湿材料的化学物理结构与性能研究进展
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摘要
首先介绍了硅胶、海泡石等无机矿物调湿材料的结构对其调湿性能的影响,指出比表面积、孔容和孔径对其调湿性能起决定作用。然后介绍了有机调湿材料中亲水基团的极性、聚合度等化学结构,表面状态、比表面积、孔容和孔径等物理结构对其调湿性能的影响。最后阐述了有机高分子调湿材料今后的研究重点。
The effect of physical structure on properties of inorganic humidity controlling materials is introduced.It is confirmed that the humidity-controlling property is determined by the factors of pore volume,pore size and surface area.And then the effects of the chemical structure including the polarity of hydrophilic group,the polymerization degree,as well as the physical structure including surface state,pore volume,pore size,surface area,on properties of organic humidity controlling materials are summarized.At last,the future research emphasis of the orga-nic/polymeric humidity controlling material is discussed.
The effect of physical structure on properties of inorganic humidity controlling materials is introduced.It is confirmed that the humidity-controlling property is determined by the factors of pore volume,pore size and surface area.And then the effects of the chemical structure including the polarity of hydrophilic group,the polymerization degree,as well as the physical structure including surface state,pore volume,pore size,surface area,on properties of organic humidity controlling materials are summarized.At last,the future research emphasis of the orga-nic/polymeric humidity controlling material is discussed.
引文
1姜洪义,栾聪梅.改性海泡石粉体的孔结构与调湿性能[J].武汉理工大学学报,2010,32(5):9
2李国胜,梁金生,丁燕,等.海泡石矿物材料的显微结构对其吸湿性能的影响[J].硅酸盐学报,2005,33(5):604
3姜洪义,王一萍,万维新.沸石、硅藻土孔结构及调湿性能的研究[J].硅酸盐通报,2006,25(6):30
4王一萍.无机调湿材料的制备与性能研究[D].武汉:武汉理工大学,2007
5 Li Haibin,Ai Minghuan,Liu Baizhan,et al.Water vaporsorption on surfactant-templated porous silica xerogels[J].Microp Mesop Mater,2011,143(1):1
6吕荣超.海泡石、硅藻土、沸石作为调湿建筑材料的基础研究[D].北京:中国建筑材料科学研究总院,2005
7#12
8姜洪义,王一萍,吴海亮.有机调湿材料的探索研究[J].武汉理工大学学报,2007,29(3):6
9张春晓,白福臣,潘振远,等.聚丙烯酸-甲基丙烯酸-丙烯酰胺P(AA-MA-AM)三元共聚物的合成及其吸湿性能研究[J].功能材料,2011,42(S2):282
10 Kim Seon Jeong,Lee Ki Jung,Kim Sun I,et al.Sorptioncharacterization of poly(vinyl alcohol)/chitosan interpene-trating polymer network hydrogels[J].J Appl Polym Sci,2003,90(1):86
11李万芬,汪超,陈国锋,等.魔芋葡甘聚糖接枝丙烯酸共聚物超强吸湿剂的扩散吸湿特性研究[J].材料科学与工程学报,2007,25(2):276
12罗曦芸,金鑫荣.文物保护用复合型调湿剂的机理研究[J].化工新型材料,2000,28(12):15
13李鑫,李慧玲,冯伟洪,等.不同吸湿官能团对高分子调湿材料吸湿和放湿性能的影响[J].中南大学学报:自然科学版,2011,42(1):28
14 Teng Jing,Bates Simon,Engers David A,et al.Effect ofwater vapor sorption on local structure of poly(vinylpyrroli-done)[J].J Pharm Sci,2010,99(9):3815
15施小宁,王文波,王爱勤.瓜尔胶-g-聚(丙烯酸钠-co-苯乙烯)/海泡石复合高吸水性树脂的制备及溶胀行为[J].化工学报,2011,62(3):864
16 Yin L,Fei L,Cui F,et al.Superporous hydrogels containingpoly(acrylic acid-co-acrylamide)/O-carboxymethyl chitosa-ninterpenetrating polymer networks[J].Biomaterials,2007,28(6):1258
17陈煜,刘云飞,唐焕林,等.致孔法制备新型CMCTS-g-PAA大孔高吸水树脂[J].化工学报,2008,59(3):785
18 Bajpai S K,Bajpai M,Sharma Leena.Investigation of wateruptake behavior and mechanical properties of superporoushydrogels[J].J Macromol Sci Part A:Pure Appl Chem,2006,43(3):507
19 Ao Haiyong,Huang Miaoliang,Wu Jihuai.Synthesis andproperties of poly(acrylamide-co-acrylic acid)/polyacryla-mide superporous IPN hydrogels[J].Polym Adv Techn,2009,20(12):1044
20欧阳娜,林松柏,李云龙.泡沫体系分散聚合法合成多孔CMC-g-PAA高吸水性材料[J].黎明职业大学学报,2008(2):32
21颜荣华,陈煜,刘云飞,等.冷冻诱导相分离法制备大孔羧甲基壳聚糖基高吸水树脂[J].高分子材料科学与工程,2008,24(7):144
22孟昊业,郑裕东,奚廷斐,等.复合多孔水凝胶的微观结构与数字散斑相关分析[J].复合材料学报,2011,28(1):50
23何谷,陈煜,张明明,等.聚乙烯醇/壳聚糖互穿聚合物海绵的制备及应用探索[J].高分子材料科学与工程,2011,27(1):150
24张春晓,张万喜,潘振远,等.聚丙烯酸钠/尿素多孔材料的制备与吸湿性能[J].高分子材料科学与工程,2009,25(7):144
25杨海亮,彭志勤,周旸,等.二次制孔法制备CMC-g-PAM/PAAS多孔树脂及其调湿性能[J].化工学报,2010,61(12):3302
26 Yang Hailiang,Peng Zhiqin,Zhou Yang,et al.Preparationand performances of a novel intelligent humidity controlcomposite material[J].Energy Buildings,2011,43(2):386
27杨海亮,彭志勤,张敬,等.γ-Al2O3法制备复合多孔树脂及其调湿与甲醛吸附性能[J].高等学校化学学报,2011,32(4):978
28万明球,金鑫荣,罗曦芸.反相悬浮聚合制备高分子调湿剂[J].功能高分子学报,1995,8(3):271
29王吉会,李燕,张子洋.凹凸棒粘土/聚丙烯酸复合材料的制备与调湿性能[J].材料研究学报,2010,24(2):113
2李国胜,梁金生,丁燕,等.海泡石矿物材料的显微结构对其吸湿性能的影响[J].硅酸盐学报,2005,33(5):604
3姜洪义,王一萍,万维新.沸石、硅藻土孔结构及调湿性能的研究[J].硅酸盐通报,2006,25(6):30
4王一萍.无机调湿材料的制备与性能研究[D].武汉:武汉理工大学,2007
5 Li Haibin,Ai Minghuan,Liu Baizhan,et al.Water vaporsorption on surfactant-templated porous silica xerogels[J].Microp Mesop Mater,2011,143(1):1
6吕荣超.海泡石、硅藻土、沸石作为调湿建筑材料的基础研究[D].北京:中国建筑材料科学研究总院,2005
7#12
8姜洪义,王一萍,吴海亮.有机调湿材料的探索研究[J].武汉理工大学学报,2007,29(3):6
9张春晓,白福臣,潘振远,等.聚丙烯酸-甲基丙烯酸-丙烯酰胺P(AA-MA-AM)三元共聚物的合成及其吸湿性能研究[J].功能材料,2011,42(S2):282
10 Kim Seon Jeong,Lee Ki Jung,Kim Sun I,et al.Sorptioncharacterization of poly(vinyl alcohol)/chitosan interpene-trating polymer network hydrogels[J].J Appl Polym Sci,2003,90(1):86
11李万芬,汪超,陈国锋,等.魔芋葡甘聚糖接枝丙烯酸共聚物超强吸湿剂的扩散吸湿特性研究[J].材料科学与工程学报,2007,25(2):276
12罗曦芸,金鑫荣.文物保护用复合型调湿剂的机理研究[J].化工新型材料,2000,28(12):15
13李鑫,李慧玲,冯伟洪,等.不同吸湿官能团对高分子调湿材料吸湿和放湿性能的影响[J].中南大学学报:自然科学版,2011,42(1):28
14 Teng Jing,Bates Simon,Engers David A,et al.Effect ofwater vapor sorption on local structure of poly(vinylpyrroli-done)[J].J Pharm Sci,2010,99(9):3815
15施小宁,王文波,王爱勤.瓜尔胶-g-聚(丙烯酸钠-co-苯乙烯)/海泡石复合高吸水性树脂的制备及溶胀行为[J].化工学报,2011,62(3):864
16 Yin L,Fei L,Cui F,et al.Superporous hydrogels containingpoly(acrylic acid-co-acrylamide)/O-carboxymethyl chitosa-ninterpenetrating polymer networks[J].Biomaterials,2007,28(6):1258
17陈煜,刘云飞,唐焕林,等.致孔法制备新型CMCTS-g-PAA大孔高吸水树脂[J].化工学报,2008,59(3):785
18 Bajpai S K,Bajpai M,Sharma Leena.Investigation of wateruptake behavior and mechanical properties of superporoushydrogels[J].J Macromol Sci Part A:Pure Appl Chem,2006,43(3):507
19 Ao Haiyong,Huang Miaoliang,Wu Jihuai.Synthesis andproperties of poly(acrylamide-co-acrylic acid)/polyacryla-mide superporous IPN hydrogels[J].Polym Adv Techn,2009,20(12):1044
20欧阳娜,林松柏,李云龙.泡沫体系分散聚合法合成多孔CMC-g-PAA高吸水性材料[J].黎明职业大学学报,2008(2):32
21颜荣华,陈煜,刘云飞,等.冷冻诱导相分离法制备大孔羧甲基壳聚糖基高吸水树脂[J].高分子材料科学与工程,2008,24(7):144
22孟昊业,郑裕东,奚廷斐,等.复合多孔水凝胶的微观结构与数字散斑相关分析[J].复合材料学报,2011,28(1):50
23何谷,陈煜,张明明,等.聚乙烯醇/壳聚糖互穿聚合物海绵的制备及应用探索[J].高分子材料科学与工程,2011,27(1):150
24张春晓,张万喜,潘振远,等.聚丙烯酸钠/尿素多孔材料的制备与吸湿性能[J].高分子材料科学与工程,2009,25(7):144
25杨海亮,彭志勤,周旸,等.二次制孔法制备CMC-g-PAM/PAAS多孔树脂及其调湿性能[J].化工学报,2010,61(12):3302
26 Yang Hailiang,Peng Zhiqin,Zhou Yang,et al.Preparationand performances of a novel intelligent humidity controlcomposite material[J].Energy Buildings,2011,43(2):386
27杨海亮,彭志勤,张敬,等.γ-Al2O3法制备复合多孔树脂及其调湿与甲醛吸附性能[J].高等学校化学学报,2011,32(4):978
28万明球,金鑫荣,罗曦芸.反相悬浮聚合制备高分子调湿剂[J].功能高分子学报,1995,8(3):271
29王吉会,李燕,张子洋.凹凸棒粘土/聚丙烯酸复合材料的制备与调湿性能[J].材料研究学报,2010,24(2):113