浓香型烟叶浸膏微波裂解行为及裂解产物成分分析
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摘要
为研究浓香型烟叶浸膏在裂解过程中的变化规律,以河南B011烟叶为原料,乙醇-水溶液为溶剂制备烟叶浸膏,经冷冻干燥处理后进行微波裂解,对裂解产物进行成分分析;并将裂解产物加入电子烟中进行感官评价。结果表明:微波裂解功率为900 W,微波裂解时间为120 s时,①裂解产物中香味成分总数量较多,总质量分数较大;②裂解产物中各类挥发性香味成分数量较多,质量分数较大;③5次重复实验组分峰面积的RSD平均值为2.52%;④感官评价结果显示,裂解产物应用于电子烟后的感官评价效果较好。
In order to study the variation of robust flavor style tobacco extract during pyrolysis process, B011 tobacco from Henan was used as the raw material and tobacco extract was prepared by using ethanol-water solution as the extraction solvent. After freeze drying, the extract was subjected to microwave pyrolysis, the pyrolysis products were analyzed and added into an electronic cigarette for sensory evaluation. The results were obtained using a microwave power at 900 W and pyrolysis time at 120 s. The results showed that: 1) the total amount and total mass of aroma components in the pyrolysis products were larger; 2) the amount and mass of each volatile aroma component in the pyrolysis products were larger; 3) the average RSD of peak areas of five replicate tests was 2.52%; 4) the results of sensory evaluation indicated that the sensory quality of electronic cigarette containing pyrolysis products was better.
In order to study the variation of robust flavor style tobacco extract during pyrolysis process, B011 tobacco from Henan was used as the raw material and tobacco extract was prepared by using ethanol-water solution as the extraction solvent. After freeze drying, the extract was subjected to microwave pyrolysis, the pyrolysis products were analyzed and added into an electronic cigarette for sensory evaluation. The results were obtained using a microwave power at 900 W and pyrolysis time at 120 s. The results showed that: 1) the total amount and total mass of aroma components in the pyrolysis products were larger; 2) the amount and mass of each volatile aroma component in the pyrolysis products were larger; 3) the average RSD of peak areas of five replicate tests was 2.52%; 4) the results of sensory evaluation indicated that the sensory quality of electronic cigarette containing pyrolysis products was better.
引文
[1]丁冬.国外电子烟管制概况及其对我国的启示[J].中国烟草学报,2017,23(4):128-135.DING Dong.Overview of e-cigarette regulation situation and some suggestions[J].Acta Tabacaria Sinica,2017,23(4):128-135.
[2]王耀.电子烟发展现状及未来研究思路[J].中国科技信息,2017(9):49-50.WANG Yao.Development status and future research ideas of electronic cigarettes[J].China Science and Technology Information,2017(9):49-50.
[3]王福山,陈丽媛,张蒙蒙.电子烟从中国制造走向中国创造[J].消费电子,2017(4):38-43.WANG Fushan,CHEN Liyuan,ZHANG Mengmeng.Electronic cigarettes from Chinese manufacturing to Chinese creation[J].Consumer Electronics Magazine,2017(4):38-43.
[4]巩效伟,韩熠,李寿波,等.电子烟雾化温度测定及影响研究[J].中国烟草学报,2017,23(3):49-55.GONG Xiaowei,HAN Yi,LI Shoubo,et al.Investigation into factors influencing atomization temperature in vaping[J].Acta Tabacaria Sinica,2017,23(3):49-55.
[5]洪群业,郑路,刘亚丽,等.国内电子烟专利技术分析[J].烟草科技,2019,52(3):74-85.HONG Qunye,ZHENG Lu,LIU Yali,et al.Technological analysis of patents related to e-cigarettes in China[J].Tobacco Science&Technology,2019,52(3):74-85.
[6]肖卫强,袁凯龙,史春云,等.烟末提取物热裂解行为研究[J].湖北农业科学,2016,55(13):3405-3410,3419.XIAO Weiqiang,YUAN Kailong,SHI Chunyun,et al.Study on pyrolysis behavior of the extraction from tobacco powder[J].Hubei Agricultural Sciences,2016,55(13):3405-3410,3419.
[7]姬小明,于建军,刘国顺,等.金莲花浸膏的热裂解行为及单料烟加香应用研究[J].中国烟草科学,2011,32(6):72-76.JI Xiaoming,YU Jianjun,LIU Guoshun,et al.Study on the pyrolytic behavior of the extract of Trollius chinensis bunge and application of unblended cigarette flavoring[J].Chinese Tobacco Science,2011,32(6):72-76.
[8]陈翠玲,马青,孔浩辉,等.应用裂解色谱模拟技术分析烟气组分的研究进展[J].现代食品科技,2010,26(8):871-875.CHEN Cuiling,MA Qing,KONG Haohui,et al.Recent progress of pyrolysis-chromatography technique in simulating cigarette smoke component[J].Modern Food Science and Technology,2010,26(8):871-875.
[9]Baker R R,Bishop L J.The pyrolysis of tobacco ingredients[J].Journal of Analytical and Applied Pyrolysis,2004,71(1):223-311.
[10]陈峰,杨伟祖,陈永宽.烟草中多羟基吡嗪的提取及其热裂解行为研究[J].天然产物研究与开发,2005,17(3):349-350.CHEN Feng,YANG Weizu,CHEN Yongkuan.Study on extraction and thermolysis of polyhydroxypyrazine in flue-cured tobacco[J].Natural Product Research and Development,2005,17(3):349-350.
[11]钟洪祥,王素方,蔡继宝,等.香兰素的热解研究[J].烟草科技,2004(7):22-26.ZHONG Hongxiang,WANG Sufang,CAI Jibao,et al.Study on pyrolysis of vanillin[J].Tobacco Science&Technology,2004(7):22-26.
[12]张敦铁,殷发强,何佳文.三种Amadori化合物的热解研究[J].中国烟草学报,2006,12(2):13-15.ZHANG Duntie,YIN Faqiang,HE Jiawen.Comparison of the pyrolysis of selected Amadori compounds[J].Acta Tabacaria Sinica,2006,12(2):13-15.
[13]董宁宁.不同温度条件下卷烟的热裂解-GC/MS研究[J].质谱学报,2003,24(1):283-286.DONG Ningning.Pyrolysis research on cigarette at different temperatures by GC/MS[J].Journal of Chinese Mass Spectrometry Society,2003,24(1):283-286.
[14]杨伯伦,贺拥军.微波加热在化学反应中的应用进展[J].现代化工,2001,21(4):8-12.YANG Bolun,HE Yongjun.New progress of microwave heating applied in chemical reaction[J].Contemporary Chemical Industry,2001,21(4):8-12.
[15]韩天竹,李欣,齐慧敏,等.仿真模拟技术在微波裂解技术上的应用研究[J].当代化工,2018,47(9):1911-1915.HAN Tianzhu,LI Xin,QI Huimin,et al.Application of simulation technology in microwave pyrolysis[J].Contemporary Chemical Industry,2018,47(9):1911-1915.
[16]Parvez A M,WU T,Afzal M T,et al.Conventional and microwave-assisted pyrolysis of gumwood:Acomparison study using thermodynamic evaluation and hydrogen production[J].Fuel Processing Technology,2019,184:1-11.
[17]Wang Y P,Zeng Z H,Tian X J,et al.Production of biooil from agricultural waste by using a continuous fast microwave pyrolysis system[J].Bioresource Technology,2018,269:162-168.
[18]郭维图.微波技术的安全性与推广应用探讨[J].机电信息,2017(5):1-6,33.GUO Weitu.Discussion on the safety and popularization of microwave technology[J].Mechanical and Electrical Information,2017(5):1-6,33.
[19]王荣发.微波技术在食品工程中的应用[J].民营科技,2016(2):37.WANG Rongfa.Application of microwave technology in food engineering[J].Private Technology,2016(2):37.
[20]张光葳,赵云,沈英,等.微波裂解技术在生物质中的应用[J].机电技术,2015(1):133-136.ZHANG Guangwei,ZHAO Yun,SHEN Ying,et al.Application of microwave cracking technology in biomass[J].Mechanical&Electrical Technology,2015(1):133-136.
[21]张秀芹,张宇,张中强,等.生物柴油微波裂解脱羧制备烃类燃料的研究[J].粮食与油脂,2015,28(2):45-48.ZHANG Xiuqin,ZHANG Yu,ZHANG Zhongqiang,et al.Pyrolysis decarboxylation of biodiesel for hydrocarbon fuel via microwave[J].Cereals&Oils,2015,28(2):45-48.
[22]曾庆倬,于凤文,盛佳峰,等.微波对生物质原料预处理及热解的作用研究进展[J].过程工程学报,2013,13(6):1061-1067.ZENG Qingzhuo,YU Fengwen,SHENG Jiafeng,et al.Research progress in microwave drying pretreatment and microwave-assisted pyrolysis of biomass[J].The Chinese Journal of Process Engineering,2013,13(6):1061-1067.
[23]阮榕生,程方园,王允圃,等.生物质高效炼制绿色化学品的最新研究进展[J].现代化工,2013,33(9):27-31.RUAN Rongsheng,CHENG Fangyuan,WANG Yunpu,et al.Advance in biorefinery technology for green chemicals[J].Modern Chemical Industry,2013,33(9):27-31.
[24]GB 5606.4-2005卷烟第4部分:感官技术要求[S].GB 5606.4-2005 Cigarettes-Part 4:Technical requirements for sense evaluation[S].
[25]谢剑平.烟草香原料[M].北京:化学工业出版社,2009.XIE Jianping.Tobacco flavor raw material[M].Beijing:Chemical Industry Press,2009.
[26]Davis D L,Nielsen M T.烟草--生产,化学和技术[M].北京:化学工业出版社,2002.Davis D L,Nielsen M T.Tobacco-production,chemistry and technology[M].Beijing:Chemical Industry Press,2002.
[27]谢国勇,胡建,杜文,等.电子烟雾化剂雾化过程的温度变化特性[J].烟草科技,2018,51(7):40-45.XIE Guoyong,HU Jian,DU Wen,et al.Temperature characteristics of e-cigarette liquid during vaporization process[J].Tobacco Science&Technology,2018,51(7):40-45.
[2]王耀.电子烟发展现状及未来研究思路[J].中国科技信息,2017(9):49-50.WANG Yao.Development status and future research ideas of electronic cigarettes[J].China Science and Technology Information,2017(9):49-50.
[3]王福山,陈丽媛,张蒙蒙.电子烟从中国制造走向中国创造[J].消费电子,2017(4):38-43.WANG Fushan,CHEN Liyuan,ZHANG Mengmeng.Electronic cigarettes from Chinese manufacturing to Chinese creation[J].Consumer Electronics Magazine,2017(4):38-43.
[4]巩效伟,韩熠,李寿波,等.电子烟雾化温度测定及影响研究[J].中国烟草学报,2017,23(3):49-55.GONG Xiaowei,HAN Yi,LI Shoubo,et al.Investigation into factors influencing atomization temperature in vaping[J].Acta Tabacaria Sinica,2017,23(3):49-55.
[5]洪群业,郑路,刘亚丽,等.国内电子烟专利技术分析[J].烟草科技,2019,52(3):74-85.HONG Qunye,ZHENG Lu,LIU Yali,et al.Technological analysis of patents related to e-cigarettes in China[J].Tobacco Science&Technology,2019,52(3):74-85.
[6]肖卫强,袁凯龙,史春云,等.烟末提取物热裂解行为研究[J].湖北农业科学,2016,55(13):3405-3410,3419.XIAO Weiqiang,YUAN Kailong,SHI Chunyun,et al.Study on pyrolysis behavior of the extraction from tobacco powder[J].Hubei Agricultural Sciences,2016,55(13):3405-3410,3419.
[7]姬小明,于建军,刘国顺,等.金莲花浸膏的热裂解行为及单料烟加香应用研究[J].中国烟草科学,2011,32(6):72-76.JI Xiaoming,YU Jianjun,LIU Guoshun,et al.Study on the pyrolytic behavior of the extract of Trollius chinensis bunge and application of unblended cigarette flavoring[J].Chinese Tobacco Science,2011,32(6):72-76.
[8]陈翠玲,马青,孔浩辉,等.应用裂解色谱模拟技术分析烟气组分的研究进展[J].现代食品科技,2010,26(8):871-875.CHEN Cuiling,MA Qing,KONG Haohui,et al.Recent progress of pyrolysis-chromatography technique in simulating cigarette smoke component[J].Modern Food Science and Technology,2010,26(8):871-875.
[9]Baker R R,Bishop L J.The pyrolysis of tobacco ingredients[J].Journal of Analytical and Applied Pyrolysis,2004,71(1):223-311.
[10]陈峰,杨伟祖,陈永宽.烟草中多羟基吡嗪的提取及其热裂解行为研究[J].天然产物研究与开发,2005,17(3):349-350.CHEN Feng,YANG Weizu,CHEN Yongkuan.Study on extraction and thermolysis of polyhydroxypyrazine in flue-cured tobacco[J].Natural Product Research and Development,2005,17(3):349-350.
[11]钟洪祥,王素方,蔡继宝,等.香兰素的热解研究[J].烟草科技,2004(7):22-26.ZHONG Hongxiang,WANG Sufang,CAI Jibao,et al.Study on pyrolysis of vanillin[J].Tobacco Science&Technology,2004(7):22-26.
[12]张敦铁,殷发强,何佳文.三种Amadori化合物的热解研究[J].中国烟草学报,2006,12(2):13-15.ZHANG Duntie,YIN Faqiang,HE Jiawen.Comparison of the pyrolysis of selected Amadori compounds[J].Acta Tabacaria Sinica,2006,12(2):13-15.
[13]董宁宁.不同温度条件下卷烟的热裂解-GC/MS研究[J].质谱学报,2003,24(1):283-286.DONG Ningning.Pyrolysis research on cigarette at different temperatures by GC/MS[J].Journal of Chinese Mass Spectrometry Society,2003,24(1):283-286.
[14]杨伯伦,贺拥军.微波加热在化学反应中的应用进展[J].现代化工,2001,21(4):8-12.YANG Bolun,HE Yongjun.New progress of microwave heating applied in chemical reaction[J].Contemporary Chemical Industry,2001,21(4):8-12.
[15]韩天竹,李欣,齐慧敏,等.仿真模拟技术在微波裂解技术上的应用研究[J].当代化工,2018,47(9):1911-1915.HAN Tianzhu,LI Xin,QI Huimin,et al.Application of simulation technology in microwave pyrolysis[J].Contemporary Chemical Industry,2018,47(9):1911-1915.
[16]Parvez A M,WU T,Afzal M T,et al.Conventional and microwave-assisted pyrolysis of gumwood:Acomparison study using thermodynamic evaluation and hydrogen production[J].Fuel Processing Technology,2019,184:1-11.
[17]Wang Y P,Zeng Z H,Tian X J,et al.Production of biooil from agricultural waste by using a continuous fast microwave pyrolysis system[J].Bioresource Technology,2018,269:162-168.
[18]郭维图.微波技术的安全性与推广应用探讨[J].机电信息,2017(5):1-6,33.GUO Weitu.Discussion on the safety and popularization of microwave technology[J].Mechanical and Electrical Information,2017(5):1-6,33.
[19]王荣发.微波技术在食品工程中的应用[J].民营科技,2016(2):37.WANG Rongfa.Application of microwave technology in food engineering[J].Private Technology,2016(2):37.
[20]张光葳,赵云,沈英,等.微波裂解技术在生物质中的应用[J].机电技术,2015(1):133-136.ZHANG Guangwei,ZHAO Yun,SHEN Ying,et al.Application of microwave cracking technology in biomass[J].Mechanical&Electrical Technology,2015(1):133-136.
[21]张秀芹,张宇,张中强,等.生物柴油微波裂解脱羧制备烃类燃料的研究[J].粮食与油脂,2015,28(2):45-48.ZHANG Xiuqin,ZHANG Yu,ZHANG Zhongqiang,et al.Pyrolysis decarboxylation of biodiesel for hydrocarbon fuel via microwave[J].Cereals&Oils,2015,28(2):45-48.
[22]曾庆倬,于凤文,盛佳峰,等.微波对生物质原料预处理及热解的作用研究进展[J].过程工程学报,2013,13(6):1061-1067.ZENG Qingzhuo,YU Fengwen,SHENG Jiafeng,et al.Research progress in microwave drying pretreatment and microwave-assisted pyrolysis of biomass[J].The Chinese Journal of Process Engineering,2013,13(6):1061-1067.
[23]阮榕生,程方园,王允圃,等.生物质高效炼制绿色化学品的最新研究进展[J].现代化工,2013,33(9):27-31.RUAN Rongsheng,CHENG Fangyuan,WANG Yunpu,et al.Advance in biorefinery technology for green chemicals[J].Modern Chemical Industry,2013,33(9):27-31.
[24]GB 5606.4-2005卷烟第4部分:感官技术要求[S].GB 5606.4-2005 Cigarettes-Part 4:Technical requirements for sense evaluation[S].
[25]谢剑平.烟草香原料[M].北京:化学工业出版社,2009.XIE Jianping.Tobacco flavor raw material[M].Beijing:Chemical Industry Press,2009.
[26]Davis D L,Nielsen M T.烟草--生产,化学和技术[M].北京:化学工业出版社,2002.Davis D L,Nielsen M T.Tobacco-production,chemistry and technology[M].Beijing:Chemical Industry Press,2002.
[27]谢国勇,胡建,杜文,等.电子烟雾化剂雾化过程的温度变化特性[J].烟草科技,2018,51(7):40-45.XIE Guoyong,HU Jian,DU Wen,et al.Temperature characteristics of e-cigarette liquid during vaporization process[J].Tobacco Science&Technology,2018,51(7):40-45.