二硫化钼纳米微球的制备及其在摩擦领域中的应用
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摘要
二硫化钼作为一种典型的过渡金属硫化物,具有非常优异的各向异性、化学惰性、润滑性以及催化性能等等。其中,二硫化钼纳米微球由于可滚动、弹性变形、球壳剥落等特点,表现出了出色的耐磨润滑性能。本文在综述不同结构二硫化钼纳米微球制备方法的基础上,对其在润滑领域中的应用进行了总结,并展望了其未来的发展。
Molybdenum disulfide is a typical transition metal sulfide which possesses excellent anisotropy,chemical inertness,lubricating properties,catalytic properties,and etc. Especially,the molybdenum disulfide nanosphere exhibits outstanding tribological properties,due to its speciall properties,such as scrollable,elastic,deformation and spherical shell peeling. In this article,on the basis of reviewing several preparation methods of molybdenum disulfide nanosphere,its applications in tribological field were summerized,and its further development was also suggested.
Molybdenum disulfide is a typical transition metal sulfide which possesses excellent anisotropy,chemical inertness,lubricating properties,catalytic properties,and etc. Especially,the molybdenum disulfide nanosphere exhibits outstanding tribological properties,due to its speciall properties,such as scrollable,elastic,deformation and spherical shell peeling. In this article,on the basis of reviewing several preparation methods of molybdenum disulfide nanosphere,its applications in tribological field were summerized,and its further development was also suggested.
引文
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[22]石华强,傅洵,周晓东,等.自制二硫化钼微球在500SN中的摩擦磨损性能研究[J].润滑与密封,2007,32(2):75-77.
[23] Kawasato Shinpei. Powder spray lubricant of molybdenum disulfide[P]. US2006030496. 2006-02-09.
[24]缐芳,李巧玲,陈贝,等.纳米花球MoS2的制备及其对环氧树脂摩擦性能的影响[J].应用化工,2018,47(3):443-447.
[25]胡坤宏,S Schraube,徐玉福,等.二硫化钼改性聚甲醛自润滑复合材料的微观摩擦学性能研究[J].摩擦学学报,2010,30(1):38-45.
[26] Perekrestova Verev. Solid lubricant for pairs of friction wheel Crest-Rail[P]. SU1752188,1992-07-30.
[27]吕桂森,邱明,李迎春,等.二硫化钼基自润滑涂层制备及性能测试[J].润滑与密封,38(6):28-30.
[2] J Deng,H Li,J Xiao,et al. Triggering the electrocatalytic hydrogen evolution activity of the inert two-dimensional MoS2surface via single-atom metal doping[J].Energy Environ. Sci.,2015,8(5):1594-1601.
[3] W S Zhang,P P Zhang,Z Q Su,et al. Synthesis and sensor applications of MoS2-based nanocomposites[J].Nanoscale,2015,7(44):18364-18378.
[4] Z Z Wu,D Z Wang,Y Wang,et al. Preparation and Tribological Properties of MoS2Nanosheets[J]. Preparation and Tribological,2010,12(6):534-538.
[5]曾一,赵鹏,王跃峰,等.气相反应条件对合成高纯度富勒烯结构二硫化钼的影响[J].中国钨业,2008,23(1):42-44.
[6] K H Hua,J Wang,S Schraubed,et al. Tribological properties of MoS2nano-balls as filler in polyoxymethylene-based composite layer of three-layer self-lubrication bearing materials[J]. Wear,2009,266(11):1198-1207.
[7]陈九菊,修可白,孟庆刚.二硫化钼纳米颗粒的制备与润滑性能研究[J].黑龙江工程学院学报,2010,24(3):72-75.
[8] Q Jiang,X Chen,L Li,et al. Synthesis and Electrochemical Properties of Molybdenum Disulfide/Carbon Microsphere Composite[J]. J. Electron. Mater.,2017,46(2):1079-1087.
[9] J Theerthagiri,R A Senthil,P Arunachalam,et al. Synthesis of various carbon incorporated flower-like MoS2microspheres as counter electrode for dye-sensitized solar cells[J]. J. Solid. State. Electr,2017(21):589-590.
[10]缑卫军.富勒烯纳米二硫化钼的制备[J].中国钼业,2016,40(2):1-6.
[11]李汉,李飞,蒋波,等.球中球结构二硫化钼的制备及其光催化性能研[J].淮北师范大学学报(自然科学版),2016,37(4):52-55.
[12] Wu D,Zhou X,Fu X,et al. Synthesis and characterization of molybdenum disulfide micro-sized solid spheres[J]. J. Mater. Sci.,2006,41(17):5682-5686.
[13]马少华,杨鹏.油溶性二硫化钼纳米微粒的制备及抗磨性能[J].合成材料老化与应用,2015(1):52-54.
[14]白鸽玲,吴壮志.二硫化钼纳米球的制备及其摩擦性能研究[J].润滑与密封,2013,38(4):93-96.
[15] Tang G,Zhang J,Liu C,et al. Synthesis and tribological properties of flower-like MoS2microspheres[J].Ceram. Int.,2014,40(8):11575-11580.
[16] Tang G G,Sun J R,Wei C,et a1. Synthesis and characterization of flowerlike MoS2nanostructures through CTAB-assisted hydmtherma process[J]. Mater.Lett.,2012,86(11):9-12.
[17]周军,兰新哲,张秋利,等.微乳液法制备纳米二硫化钼酸沉过程研究[J].有色金属(冶炼部分),2011,13(8):47-51.
[18] Xu Z Y,Xu Y,Hu K H,et al. Formation and tribological properties of hollow sphere-like nano-MoS2precipitated in Ti O2particles[J]. Tribol. Int.,2015,81:139-148.
[19] Liu Y R,Hua K H,Hua E Z,et al. Double hollow MoS2nano-spheres:Synthesis,tribological properties,and functional conversion from lubrication to photocatalysis[J]. Appl. Surf. Sci.,2017,392:1144-1152.
[20] Lin D,Li Y,Zhang P,et al. Fast preparation of MoS2nanoflowers decorated with platinum nanoparticles for electrochemical detection of hydrogen peroxide[J]. RSC Advances,2016,58(6):52739-52745.
[21]刘敏,徐勇,胡坤宏.不同形态二硫化钼润滑剂在玉米油中的摩擦学性能[J].安徽化工,2016,42(3):15-18.
[22]石华强,傅洵,周晓东,等.自制二硫化钼微球在500SN中的摩擦磨损性能研究[J].润滑与密封,2007,32(2):75-77.
[23] Kawasato Shinpei. Powder spray lubricant of molybdenum disulfide[P]. US2006030496. 2006-02-09.
[24]缐芳,李巧玲,陈贝,等.纳米花球MoS2的制备及其对环氧树脂摩擦性能的影响[J].应用化工,2018,47(3):443-447.
[25]胡坤宏,S Schraube,徐玉福,等.二硫化钼改性聚甲醛自润滑复合材料的微观摩擦学性能研究[J].摩擦学学报,2010,30(1):38-45.
[26] Perekrestova Verev. Solid lubricant for pairs of friction wheel Crest-Rail[P]. SU1752188,1992-07-30.
[27]吕桂森,邱明,李迎春,等.二硫化钼基自润滑涂层制备及性能测试[J].润滑与密封,38(6):28-30.