摘要
本世纪前十年(2001年-2010年),国内流体包裹体的研究和应用都有了很大的进展。本文就流体包裹体研究的几个主要方面——包裹体流体体系PVTX性质的模拟、人工合成流体包裹体、成矿流体和成矿机制研究以及油气包裹体和成藏过程研究等——进行了总结。国内包裹体流体体系PVTX性质的模拟研究已经达到国际水平,各种天然流体体系的状态方程被应用于包裹体研究中。结合国际上流行的流体包裹体合成技术,国内学者利用人工流体包裹体,已经开展了流体包裹体形成机理、包裹体中流体体系相平衡和流体包裹体分析设备标定的研究工作。成矿流体和成矿机制研究仍然是流体包裹体的主要应用领域,一些国际前沿的新技术和新方法,如金属矿物中流体包裹体的红外显微测温技术,单个流体包裹体成矿元素的LA-ICP-MS测定方法,以及流体包裹体组合(FIA)研究方法等,被国内学者在研究中采用。油气包裹体研究越来越受到石油地质学家的重视,其在油气成藏机理尤其是油气充注以及成分演化史研究中发挥着日益重要的作用。除了上述主要研究领域,利用熔体包裹体研究地幔流体,通过超高压变质岩中流体包裹体研究变质流体,应用表生环境下蒸发岩(石盐)中的流体包裹体研究古气候,这些方面也都取得了很好的研究成果。本世纪的前十年,国内流体包裹体研究与国际研究紧密结合,中国学者创立的ACROFI系列会议目前也已经成为国际流体包裹体界的重要系列会议之一。
Fluid inclusion research and application had made great progress in the first ten years of this century(from 2001to 2010)in China.This paper provides an overview of fluid inclusion studies including PVTX study,synthetic fluid inclusions,study of ore-forming fluids and mineralization mechanisms and study of petroleum inclusions and oil and gas accumulation.In PVTX study,the use of various equations of state(EOS)on geo-fluid systems has greatly contributed to the fluid inclusion studies.Synthetic fluid inclusions have been applied to the investigation of mechanism of natural fluid inclusions formation,phase equilibrium of inclusion fluids and calibration of analytical techniques on fluid inclusion.Property of ore-forming fluids and mineralization mechanisms is always the main application of fluid inclusion study.Meanwhile,some new techniques and approaches were introduced to the research of this field,which are infrared microthermometry of fluid inclusion in ore minerals,LA-ICP-MS analysesof single fluid inclusion and fluid inclusion assemblage(FIA)method etc.The study of petroleum inclusions has played a more and more important role in the evaluation of oil and gas accumulation process and exploration.Also,some progresses have been achieved in property of mantle fluids by melt and fluid inclusion in mantle xenoliths,understanding of ultrahigh-pressure(UHP)metamorphism process by fluid inclusion and reconstruction of palaeo-environmental conditions by fluid inclusions trapped in halite from earth surface environments.In the first ten years of this century(from 2001to 2010),studies of fluid inclusion in China advanced with international studies.Especially,the Asian Current Research on Fluid Inclusions(ACROFI)established by Chinese scholar has become one of the key international forums in the world.
引文
[1]Sorby H C.On the microscopic structures of crystals,indicating the origin of minerals and rocks[J].Geol.Soc.London Q.J.,1858,14:453-500.
[2]卢焕章,范宏瑞,倪培,等.流体包裹体[M].北京:科学出版社,2004:1-487.
[3]刘斌.烃类包裹体热动力学[M].北京:科学出版社,2005:1-383.
[4]倪培.流体包裹体研究进展[J].南京大学学报(自然科学),2012,48(3):237-239.
[5]Ni P,Li Z L.Asian current research on fluid inclusions:An introduction[J].Acta Petrologica,2007,23(1):1-2.
[6]Zhang Z G,Duan Z H.Phase equilibria of the system methane-ethane from temperature scaling Gibbs Ensemble Monte Carlo simulation[J].Geochim.Cosmochim.Acta,2002,66:3431-3439.
[7]Duan Z H,Sun R.An improved model calculating CO2solubility in pure water and aqueous NaCl solutions from 273to533Kand from 0to 2000bar[J].Chem.Geol.,2003,193:257-271.
[8]Sun R,Duan Z H.Prediction of CH4and CO2hydrate phase equilibrium and cage occupancy from ab initio intermolecular potentials[J].Geochimi.Cosmochim.Acta,2005,69:4411-4424.
[9]Zhang Z G,Duan Z H.Prediction of the PVT properties of water over wide range of temperatures and pressures from molecular dynamics simulation[J].Phys.Earth Planet.Inter.2005,149:335-354.
[10]Duan Z H,Zhang Z G.Equation of state of the H2O-CO2system up to 10GPa and 2573K:Molecular dynamics simulations with abinition potential surface[J].Geochim.Cosmochim.Acta,2006,70:2311-2324.
[11]Zhang C,Duan Z H,Zhang Z G.Molecular dynamics simulation of the CH4and CH4-H2O systems up to 10GPa and 2573K[J].Geochim.Cosmochim.Acta,2007,71:2036-2055.
[12]Duan Z H,Li D D.Coupled phase and aqueous species equilibrium of the H2O-CO2-NaCl-CaCO3 system from 0 to250℃,1to 1000bar with NaCl concentrations up to saturation of halite[J].Mol.Phys.,2008,106:2685-2697.
[13]Zhang C,Duan Z H.A model for C-O-H fluid in the Earth’s mantle[J].Geochim.Cosmochim.Acta,2009,73:2089
[14]段振豪.地质流体状态方程[J].中国科学(地球科学),2010,40(4):393-413.
[15]倪培,饶冰,丁俊英,张林松.人工合成包裹体的实验研究极其在激光拉曼探针测定方面的应用[J].岩石学报,2003,19(2):319-326.
[16]丁俊英,倪培,饶冰.CaCl2-H2O体系人工合成流体包裹体研究[J].岩石学报,2005,21(5):1425-1428.
[17]Ni P,Ding J Y,Rao B.In situ cryogenic Raman spectroscopic studies on the synthetic fluid inclusions in the systems H2O and NaCl-H2O[J].Chinese Science Bulletin,2006,51(1):108-114.
[18]丁俊英,倪培.NaCl-CaCl2-H2O体系人工合成流体包裹体及其冷冻后的熔融行为研究[J].岩石学报,2007,23(9):2039-2044.
[19]丁俊英,倪培,Dubessy J,张婷.原位低温拉曼光谱技术在人工合成CaCl2-H2O和MgCl2-H2O体系流体包裹体分析中的应用I:低温拉曼光谱研究[J].岩石学报,2008,24(9):1961-1967.
[20]倪培,丁俊英,Dubessy J,张婷.原位低温拉曼光谱技术在人工合成CaCl2-H2O和MgCl2-H2O体系流体包裹体分析中的应用II:低温下流体包裹体相变行为的研究[J].岩石学报,2008,24(9):1968-1974.
[21]倪培,Dubessy J,丁俊英,王天刚,张婷.低温原位拉曼光谱技术在流体包裹体研究中的应用[J].地学前缘,2009,16(1):173-180.
[22]倪培,王一刚.人工合成烃类包裹体的实验研究[J].岩石学报,2007,23(9):2033-2038.
[23]孟凡巍,倪培,丁俊英,王天刚,张婷.人工合成烃类流体包裹体测温数据对石油地质的指示[J].岩石学报,2008,24(9):1975-1980.
[24]倪培,孟凡巍.碳酸盐岩中烃类包裹体的人工合成实验研究[J].岩石学报,2008,24(1):161-165.
[25]李兆麟,翟伟,黄栋林,赵文霞,杨荣勇,全亚荣,李文.新疆乔尕山和粤西河台韧性剪切带金矿床中熔融包裹体的发现及矿床成因[J].矿床地质,2001,20(3):208-215.
[26]范宏瑞,谢奕汉,翟明国,金成伟.豫陕小秦岭脉状金矿床三期流体运移成矿作用[J].岩石学报,2003,19(2):260-265.
[27]Fan H R,Zhai M G,Xie Y H,Yang J H.Ore-forming fluids associated with granite-hosted gold mineralization at the Sanshandao deposit,Jiaodong gold province,China[J].Mineralium Deposita,2003,38:739-750.
[28]张文淮,张德会,刘敏.江西银山铜铅锌金银矿床成矿流体及成矿机制研究[J].岩石学报,2003,19(2):242-250.
[29]范宏瑞,胡芳芳,杨进辉,沈昆,翟明国.胶东中生代构造体制转折过程中流体演化和金的大规模成矿[J].岩石学报,2005,21(5):1317-1328.
[30]胡芳芳,范宏瑞,沈昆,翟明国,金成伟,陈绪松.胶东乳山脉状金矿床成矿流体性质与演化[J].岩石学报,2005,21(5):1329-1338.
[31]倪培,田京辉,朱筱婷,凌洪飞,蒋少涌,顾连兴.江西永平铜矿下盘网脉状矿化的流体包裹体研究[J].岩石学报,2005,21(5):1339-1346.
[32]谢玉玲,侯增谦,徐九华,杨志明,徐文艺,何建平.藏东玉龙斑岩铜矿床多期流体演化与成矿的流体包裹体证据[J].岩石学报,2005,21(5):1409-1415.
[33]徐九华,丁汝福,谢玉玲,钟长华,原旭.阿尔泰山南缘萨热阔布金矿床的纯CO2流体[J].科学通报,2005,50(4):380-386.
[34]徐文艺,曲晓明,侯增谦,杨丹,杨竹森,崔艳合,陈伟十.西藏冈底斯中段雄村铜金矿床成矿流体特征与成因探讨[J].矿床地质,2006,25(3):243-251.
[35]卢焕章.CO2流体与金矿化:流体包裹体的证据[J].地球化学,2008,37(4):321-328.
[36]王天刚,倪培,王国光,张婷.甘肃厂坝铅锌矿富甲烷流体包裹体的发现及其意义[J].岩石学报,2008,24(9):2105-2112.
[37]Xu J H,Ding R F,Xie Y L,Zhong C H,Shan L H.The source of hydrothermal fluids for the Sarekoubu gold deposit in the southern Altai,Xinjiang,China:Evidence from fluid inclusions and geochemistry[J].Journal of Asian Earth Sciences,2008,32:247-258.
[38]杨奎峰,刘爽,胡芳芳,范宏瑞.内蒙古赛乌素金矿成矿流体特征[J].岩石学报,2008,24(9):2079-2084.
[39]Chen Y J,Pirajno F,Li N,Guo D S,Lai Y.Isotope systematics and fluid inclusion studies of the Qiyugou breccia pipehosted gold deposit,Qinling Orogen,Henan province,China:Implications for ore genesis[J].Ore Geology Reviews,2009,35:245-261.
[40]李诺,陈衍景,倪智勇,胡海珠.河南省嵩县鱼池岭斑岩钼矿床成矿流体特征及其地质意义[J].岩石学报,2009,25(10):2509-2522.
[41]陈衍景.初论浅成作用和热液矿床成因分类[J].地学前缘,2010,17(2):27-34.
[42]刘玄,范宏瑞,胡芳芳,郑小礼,蓝廷广,杨奎锋.胶东大庄子金矿床流体包裹体及稳定同位素研究[J].矿床地质,2010,S1:593-594.
[43]Ni P,Zhu X,Wang R C,Shen Kun,Zhang Z M,Qiu J S,Huang J P.Constraining ultrahigh-pressure(UHP)metamorphism and titanium ore formation from an infrared microthermometric study of fluid inclusions in rutile from Donghai UHP eclogites,eastern China[J].Geological Society of America Bulletin,2008,120(9/10):1296-1304.
[44]Su W C,Heinrich C A,Pettke T,Zhang X C,Hu R Z,Xia B.Sediment-hosted gold deposits in Guizhou,China:Products of wall-rock sulfidation by deep crustal fluids[J].Economic Geology,2009,104:73-93.
[45]Chi G X,Lu H Z.Validation and representation of fluid inclusion microthermometric data using the fluid inclusion assemblage(FIA)concept[J].Acta Petrologica Sinica,2008,24(9):1945-1953.
[46]王旭东,倪培,蒋少涌,黄建宝,孙立强.赣南漂塘钨矿流体包裹体研究[J].岩石学报,2008,24(9):2163-2170.
[47]孙玉梅,席小应,黄正吉.流体包裹体分析技术在渤中25-1油田油气充注史研究中的应用[J].中国海上油气地质,2002,16(4):238-244.
[48]Liu D H,Xiao X M,Mi J K,Li X Q,Shen J K,Song Z G,Peng P A.Determination of trapping pressure and temperature of petroleum inclusions using PVT simulation softwareA case study of Lower Ordovician carbonates from the Lunnan Low Uplift,Tarim Basin[J].Marine and Petroleum Geology,2003,20:29-43.
[49]Pan C C,Yang J Q,Fu J M.Molecular correlation of free oil and inclusion oil of reservoir rocks in the Junggar Basin,China[J].Organic Geochemistry,2003,34:357-374.
[50]刘德汉,宫色,刘东鹰,曾庆辉,肖贤明,田辉,申家贵,李贤庆.江苏句容-黄桥地区有机包裹体形成期次和捕获温度、压力的PVTsim模拟计算[J].岩石学报,2005,21(5):1435-1448.
[51]王飞宇,庞雄奇,曾花森,师玉雷,胡剑峰,刘可禹.古油层识别技术及其在石油勘探中的应用[J].新疆石油地质,2005,26(5):107-111.
[52]张鼐,张水昌,李新景,涂建淇.塔中117井储层烃包裹体研究及油气成藏史[J].岩石学报,2005,21(5):1473-1478.
[53]李荣西,席胜利,邸领军.用储层油气包裹体岩相学确定油气成藏期次——以鄂尔多斯盆地陇东油田为例[J].石油与天然气地质,2006,27(2):194-199.
[54]欧光习,李林强,孙玉梅,沉积盆地流体包裹体研究的理论与实践[J].矿物岩石地球化学通报,2006,25(1):1-11,
[55]陶士振,邹才能,袁选俊.流体包裹体在油气勘探中的应用——以吉林油田扶新隆起扶余油层为例[J].中国石油勘探,2006,11(4):46-51.
[56]潘立银,倪培,欧光习,李林强.中国塔里木盆地塔中北坡志留系多期石油充注:流体包裹体和有机地球化学证据[J].岩石学报,2007,23(1):131-136.
[57]Pan C C,Liu D Y.Molecular correlation of free oil,adsorbed oil and inclusion oil of reservoir rocks in the Tazhong Uplift of the Tarim Basin,China[J].Organic Geochemistry,2009,40:387-399.
[58]徐九华,谢玉玲.中国吉林长白山地区地幔捕虏体中硫化物熔体包裹体[J].岩石学报,2007,23(1):117-124.
[59]樊祺诚,隋建立,孙谦,李霓,赵勇伟,杜星星.北部湾涠洲岛橄榄岩中熔体包裹体——大陆岩石圈地幔交代作用的新证据[J].岩石学报,2008,24(11):2495-2500.
[60]刘吉强,陈立辉,倪培.山东临朐新生代地幔捕虏体中的流体/熔体包裹体:软流圈-岩石圈相互作用的信息[J].科学通报,2010,55(7):583-592.
[61]范宏瑞,刘景波,郭敬辉,叶凯,从柏林.大别山超高压变质带白片岩中的流体包裹体[J].科学通报,2002,47(8):623-627.
[62]范宏瑞,郭敬辉,胡芳芳,储雪蕾,陈福坤,金成伟.苏鲁造山带超高压变质岩的差异性折返:流体包裹体证据[J].科学通报,2005,50(10):1007-1015.
[63]沈昆,张泽明,孙晓明,徐莉.超高压变质流体的组成与演化:中国大陆科学钻探工程主孔岩心的流体包裹体研究[J].岩石学报,2005,21(2):489-504.
[64]沈昆,张泽明,黄太岭,赵旭东.中国大陆科学钻探(CCSD)主孔超高压变质岩副矿物锆石中的流体包裹体研究[J].岩石学报,2006,22(7):1975-1984.
[65]张泽明,沈昆,赵旭东,石超.超高压变质作用过程中的流体——来自苏鲁超高压变质岩岩石学、氧同位素和流体包裹体研究的限定[J].岩石学报,2006,7:1985-1998.
[66]刘兴起,倪培.表生环境条件形成的石盐流体包裹体研究进展[J].地球科学进展,2005,20(8):856-862.
[67]葛晨东,王天刚,刘兴起,孟凡巍,刘吉强.青海茶卡盐湖石盐中流体包裹体记录的古气候信息[J].岩石学报,2007,23(9):2063-2068.