高强耐热稀土镁合金研究进展
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摘要
梳理了高强耐热镁合金的研究历程及现状。Mg-Gd(Y)-Ag和Mg-Gd(Y)-Zn系合金是目前强度最高的镁合金体系,铸造Mg-9.8Gd-2.7Y-2.0Ag-0.4Zr合金最优常温力学性能如下:抗拉强度(UTS),410 MPa;屈服强度(YS),300 MPa;延伸率(EL),2.3%。高强耐热稀土镁合金的大尺寸构件铸造工艺性亟需重点研究。总结了"固溶强化增塑"的合金设计、"高、低稀土镁合金"强韧性的设计与开发、"低稀土总量、多元合金"耦合强化设计、集成计算材料工程(ICME)等理念,对新型高强耐热铸造镁稀土合金的开发具有指导意义。
The research history and current status of high-strength heat-resistant magnesium alloys are introduced. Mg-Gd(Y)-Ag and Mg-Gd(Y)-Zn alloys are the most promising magnesium alloy systems at present. The optimum ultimate tensile strength(UTS), yield strength(YS)and elongation(EL)of Mg-9.8 Gd-2.7 Y-2.0 Ag-0.4 Zr alloy are 410 MPa, 300 MPa and 2.3% respectively. The casting process of large-sized components of high-strength heat-resistant rare earth magnesium alloys needs to be urgently studied. Finally, new ideas for the alloy design of "solid solution strengthening plasticization", the strength and toughness design and development of "high and low rare earth magnesium alloy", the coupling strengthening design of "low rare earth total amount, multi-alloy" and the integrated computational materials engineering(ICME) have been proposed, which will guide the development of new high-strength heat-resistant cast rare earth magnesium alloys.
The research history and current status of high-strength heat-resistant magnesium alloys are introduced. Mg-Gd(Y)-Ag and Mg-Gd(Y)-Zn alloys are the most promising magnesium alloy systems at present. The optimum ultimate tensile strength(UTS), yield strength(YS)and elongation(EL)of Mg-9.8 Gd-2.7 Y-2.0 Ag-0.4 Zr alloy are 410 MPa, 300 MPa and 2.3% respectively. The casting process of large-sized components of high-strength heat-resistant rare earth magnesium alloys needs to be urgently studied. Finally, new ideas for the alloy design of "solid solution strengthening plasticization", the strength and toughness design and development of "high and low rare earth magnesium alloy", the coupling strengthening design of "low rare earth total amount, multi-alloy" and the integrated computational materials engineering(ICME) have been proposed, which will guide the development of new high-strength heat-resistant cast rare earth magnesium alloys.
引文
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[4] 吴国华,陈玉狮,丁文江.镁合金在航空航天领域研究应用现状与展望[J].载人航天,2016,22(3):281-292.
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[8] LUO A A.Magnesium casting technology for structural applications[J].Journal of Magnesium and Alloys,2013,1(1):2-22.
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[11] ROKHLIN L L.Magnesium alloys containing rare earth metals:structure and properties[M].London:Taylor & Francis,2003:1-15.
[12] ALI Y,QIU D,JIANG B,et al.Current research progress in grain refinement of cast magnesium alloys:a review article[J].Journal of Alloys and Compounds,2015,619:639-651.
[13] KANG Y B,JIN L L,CHARTRAND P,et al.Thermodynamic evaluations and optimizations of binary Mg-light rare earth (La,Ce,Pr,Nd,Sm) systems[J].Calphad,2012,38:100-116.
[14] NIE J F.Precipitation and hardening in magnesium alloys[J].Metallurgical and Materials Transactions A,2012,43(11):3891-3939.
[15] NIE J F,WILSON N C,ZHU Y M,et al.Solute clusters and GP zones in binary Mg-RE alloys[J].Acta Materialia,2016,106:260-271.
[16] NIE J F.Applications of atomic-resolution HAADF-STEM and EDS-STEM characterization of light alloys[J].IOP Conference Series:Materials Science and Engineering,2017,219:12005.
[17] STANFORD N.The effect of rare earth elements on the behaviour of magnesium-based alloys(Part 2):recrystallisation and texture development[J].Materials Science and Engineering:A,2013,565:469-475.
[18] LI L.TMS 2016 145th annual meeting & exhibition[J].Powder Diffraction,2016,31(3):253-254.
[19] ABBOTT T B.Magnesium:industrial and research developments over the last 15 years[J].Corrosion,2015,71(2):120-127.
[20] 巫瑞智,张景怀,尹冬松.先进镁合金制备与加工技术[M].北京:科学出版社,2012:1-30.
[21] 陈振华.耐热镁合金[M].北京:化工工业出版社,2007:1-40.
[22] BRANDT E N.We called it magnificent:Dow chemical and magnesium,1916-1998[J].Journal for the History of Astronomy,2013,40(3):474-475.
[23] HAUGHTON J L.Magnesium and its alloys recent developments in great Britain[J].Industrial & Engineering Chemistry,1939,31(8):969-971.
[24] LEONTIS T E.The properties of sand cast magnesium-rare earth alloys[J].JOM,1949,1(12):968-983.
[25] LEONTIS T E.Effect of rare-earth metals on the properties of extruded magnesium[J].JOM,1951,3(11):987-993.
[26] LEONTIS T E.Properties of magnesium-thorium and magnesium-thorium-cerium alloys[J].JOM,1952,3(4):287-294.
[27] YAMAMOTO A S,ROSTOKER W.Partial phase diagram of the systems Mg-Th and Mg-Th-Zn[J].Transactions of American Society for Metals,1958,50:1-24.
[28] SAUERWALD F.Der stand der entwicklung der zweistofflegierungen und vielstofflegierungen auf der basis magnesium-zirkon und magnesium-thorium-zirkon[J].Zeitschrift fur Metallkunde,1954,45:257-269.
[29] GIBSON E D,CARLSON O N.The yttrium-magnesium alloy system[J].Transactions of the American Society for Metals,1960(52):1084-1096.
[30] SMITH J F,BAILEY D M,NOVOTNY D B,et al.Thermodynamics of formation of yttrium-magnesium intermediate phases[J].Acta Metallurgica,1965,13(8):889-895.
[31] VOSTRYP,SMOLAB,STULíKOVáI,et al.Microstructure evolution in isochronally heat treated Mg-Gd alloys[J].Physica Status Solidi:A,1999,175(2):491-500.
[32] 师昌绪,李恒德,王淀佐,等.加速我国金属镁工业发展的建议[J].材料导报,2001,15(4):5-6.
[33] 翟春泉,曾小勤.镁合金的开发与应用[J].铸造工程·造型材料,2000,24(1):6-9.
[34] 曾小勤,王渠东,吕宜振,等.镁合金应用新进展[J].铸造,1998(11):39-43.
[35] 潘复生,韩恩厚.高性能变形镁合金及加工技术[M].北京:科学出版社,2007:1-10.
[36] JIANG H S,ZHENG M Y,QIAO X G,et al.Microstructure and mechanical properties of WE43 magnesium alloy fabricated by direct-chill casting[J].Materials Science and Engineering:A,2017,684:158-164.
[37] 吴国华,张亮,丁文江.镁合金液态精密成型研究进展[J].上海电力学院学报,2015,31(4):299-316.
[38] NING Z L,YI J Y,QIAN M,et al.Microstructure and elevated temperature mechanical and creep properties of Mg-4Y-3Nd-0.5Zr alloy in the product form of a large structural casting[J].Materials & Design,2014,60:218-225.
[39] 丁文江,彭立明,付彭怀,等.高性能镁合金及其成形加工技术与应用研究进展[J].新材料产业,2008(2):58-63.
[40] 丁文江,吴玉娟,彭立明,等.高性能镁合金研究及应用的新进展[J].中国材料进展,2010,29(8):37-45.
[41] 潘复生.镁合金新材料及先进加工技术研究进展[R].北京:中国有色金属学会,2018.
[42] FU P H,PENG L M,JIANG H Y,et al.Tensile properties of high strength cast Mg alloys at room temperature:a review[J].China Foundry,2014,11(4):277-286.
[43] WANG Q D,CHEN J,ZHAO Z,et al.Microstructure and super high strength of cast Mg-8.5Gd-2.3Y-1.8Ag-0.4Zr alloy[J].Materials Science and Engineering:A,2010,528(1):323-328.
[44] 曾小勤,史枭颖.稀土镁合金强韧性设计与开发[J].航空材料学报,2017,37(1):18-25.
[45] MO N,TAN Q Y,BERMINGHAM M,et al.Current development of creep-resistant magnesium cast alloys:a review[J].Materials & Design,2018,155:422-442.
[46] LUO A A.Magnesium alloy development and advanced processing:the role of computational thermodynamics and kinetics[R].Shanghai:The Ohio State University,2018.
[2] 丁文江,付彭怀,彭立明,等.先进镁合金材料及其在航空航天领域中的应用[J].航天器环境工程,2011,28(2):103-109.
[3] 曾小勤.稀土镁合金研究与应用进展[J].稀土信息,2016(2):26-29.
[4] 吴国华,陈玉狮,丁文江.镁合金在航空航天领域研究应用现状与展望[J].载人航天,2016,22(3):281-292.
[5] 吴玉娟,丁文江,彭立明,等.高性能稀土镁合金的研究进展[J].中国材料进展,2011,30(2):1-9.
[6] 张丁非,谌夏,潘复生,等.稀土元素对镁合金力学性能影响的研究进展[J].功能材料,2014,45(5):05001-05007.
[7] 丁文江.镁合金科学与技术[M].北京:科学出版社,2007:1-7.
[8] LUO A A.Magnesium casting technology for structural applications[J].Journal of Magnesium and Alloys,2013,1(1):2-22.
[9] MORDIKE B L,EBERT T.Magnesium:properties-applications-potential[J].Materials Science and Engineering:A,2001,302(1):37-45.
[10] PEKGULERYUZ M O,KAINER K,KAYA A A.Fundamentals of magnesium alloy metallurgy[M].Singapore:Elsevier,2013:1-20.
[11] ROKHLIN L L.Magnesium alloys containing rare earth metals:structure and properties[M].London:Taylor & Francis,2003:1-15.
[12] ALI Y,QIU D,JIANG B,et al.Current research progress in grain refinement of cast magnesium alloys:a review article[J].Journal of Alloys and Compounds,2015,619:639-651.
[13] KANG Y B,JIN L L,CHARTRAND P,et al.Thermodynamic evaluations and optimizations of binary Mg-light rare earth (La,Ce,Pr,Nd,Sm) systems[J].Calphad,2012,38:100-116.
[14] NIE J F.Precipitation and hardening in magnesium alloys[J].Metallurgical and Materials Transactions A,2012,43(11):3891-3939.
[15] NIE J F,WILSON N C,ZHU Y M,et al.Solute clusters and GP zones in binary Mg-RE alloys[J].Acta Materialia,2016,106:260-271.
[16] NIE J F.Applications of atomic-resolution HAADF-STEM and EDS-STEM characterization of light alloys[J].IOP Conference Series:Materials Science and Engineering,2017,219:12005.
[17] STANFORD N.The effect of rare earth elements on the behaviour of magnesium-based alloys(Part 2):recrystallisation and texture development[J].Materials Science and Engineering:A,2013,565:469-475.
[18] LI L.TMS 2016 145th annual meeting & exhibition[J].Powder Diffraction,2016,31(3):253-254.
[19] ABBOTT T B.Magnesium:industrial and research developments over the last 15 years[J].Corrosion,2015,71(2):120-127.
[20] 巫瑞智,张景怀,尹冬松.先进镁合金制备与加工技术[M].北京:科学出版社,2012:1-30.
[21] 陈振华.耐热镁合金[M].北京:化工工业出版社,2007:1-40.
[22] BRANDT E N.We called it magnificent:Dow chemical and magnesium,1916-1998[J].Journal for the History of Astronomy,2013,40(3):474-475.
[23] HAUGHTON J L.Magnesium and its alloys recent developments in great Britain[J].Industrial & Engineering Chemistry,1939,31(8):969-971.
[24] LEONTIS T E.The properties of sand cast magnesium-rare earth alloys[J].JOM,1949,1(12):968-983.
[25] LEONTIS T E.Effect of rare-earth metals on the properties of extruded magnesium[J].JOM,1951,3(11):987-993.
[26] LEONTIS T E.Properties of magnesium-thorium and magnesium-thorium-cerium alloys[J].JOM,1952,3(4):287-294.
[27] YAMAMOTO A S,ROSTOKER W.Partial phase diagram of the systems Mg-Th and Mg-Th-Zn[J].Transactions of American Society for Metals,1958,50:1-24.
[28] SAUERWALD F.Der stand der entwicklung der zweistofflegierungen und vielstofflegierungen auf der basis magnesium-zirkon und magnesium-thorium-zirkon[J].Zeitschrift fur Metallkunde,1954,45:257-269.
[29] GIBSON E D,CARLSON O N.The yttrium-magnesium alloy system[J].Transactions of the American Society for Metals,1960(52):1084-1096.
[30] SMITH J F,BAILEY D M,NOVOTNY D B,et al.Thermodynamics of formation of yttrium-magnesium intermediate phases[J].Acta Metallurgica,1965,13(8):889-895.
[31] VOSTRYP,SMOLAB,STULíKOVáI,et al.Microstructure evolution in isochronally heat treated Mg-Gd alloys[J].Physica Status Solidi:A,1999,175(2):491-500.
[32] 师昌绪,李恒德,王淀佐,等.加速我国金属镁工业发展的建议[J].材料导报,2001,15(4):5-6.
[33] 翟春泉,曾小勤.镁合金的开发与应用[J].铸造工程·造型材料,2000,24(1):6-9.
[34] 曾小勤,王渠东,吕宜振,等.镁合金应用新进展[J].铸造,1998(11):39-43.
[35] 潘复生,韩恩厚.高性能变形镁合金及加工技术[M].北京:科学出版社,2007:1-10.
[36] JIANG H S,ZHENG M Y,QIAO X G,et al.Microstructure and mechanical properties of WE43 magnesium alloy fabricated by direct-chill casting[J].Materials Science and Engineering:A,2017,684:158-164.
[37] 吴国华,张亮,丁文江.镁合金液态精密成型研究进展[J].上海电力学院学报,2015,31(4):299-316.
[38] NING Z L,YI J Y,QIAN M,et al.Microstructure and elevated temperature mechanical and creep properties of Mg-4Y-3Nd-0.5Zr alloy in the product form of a large structural casting[J].Materials & Design,2014,60:218-225.
[39] 丁文江,彭立明,付彭怀,等.高性能镁合金及其成形加工技术与应用研究进展[J].新材料产业,2008(2):58-63.
[40] 丁文江,吴玉娟,彭立明,等.高性能镁合金研究及应用的新进展[J].中国材料进展,2010,29(8):37-45.
[41] 潘复生.镁合金新材料及先进加工技术研究进展[R].北京:中国有色金属学会,2018.
[42] FU P H,PENG L M,JIANG H Y,et al.Tensile properties of high strength cast Mg alloys at room temperature:a review[J].China Foundry,2014,11(4):277-286.
[43] WANG Q D,CHEN J,ZHAO Z,et al.Microstructure and super high strength of cast Mg-8.5Gd-2.3Y-1.8Ag-0.4Zr alloy[J].Materials Science and Engineering:A,2010,528(1):323-328.
[44] 曾小勤,史枭颖.稀土镁合金强韧性设计与开发[J].航空材料学报,2017,37(1):18-25.
[45] MO N,TAN Q Y,BERMINGHAM M,et al.Current development of creep-resistant magnesium cast alloys:a review[J].Materials & Design,2018,155:422-442.
[46] LUO A A.Magnesium alloy development and advanced processing:the role of computational thermodynamics and kinetics[R].Shanghai:The Ohio State University,2018.