色质联用技术的进步与农药多残留分析方法的发展(之一)
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摘要
气相色谱-质谱联用技术是农药多类多残留检测分析方法发展的起点,液相色谱-质谱联用技术的发展给极性农药、热不稳定性农药及其代谢物的检测创造了条件,高选择性、高灵敏度、高通量的色谱-串联质谱技术创建了农药的多残留检测方法。本文回顾了色质联用技术的进步及其在农药多残留分析方法发展过程中的重要作用。
This paper reviewes the progress of gas chromatography-mass spectrometry(GC-MS)and its important role in the development of multi-residue analysis of pesticides.GC-MS technology is the starting point for the development of multi-residue analysis of pesticides.The development of liquid chromatography-mass spectrometry(LCMS)technology created conditions for the detection of polar or thermounstable pesticides and their metabolites.High selectivity,high sensitivity and high throughput chromatography-mass spectrometry technology creates the condition for the realization of multi-residue detection of pesticides.
This paper reviewes the progress of gas chromatography-mass spectrometry(GC-MS)and its important role in the development of multi-residue analysis of pesticides.GC-MS technology is the starting point for the development of multi-residue analysis of pesticides.The development of liquid chromatography-mass spectrometry(LCMS)technology created conditions for the detection of polar or thermounstable pesticides and their metabolites.High selectivity,high sensitivity and high throughput chromatography-mass spectrometry technology creates the condition for the realization of multi-residue detection of pesticides.
引文
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[13]傅若农.近年国内外毛细管气相色谱柱的进展和趋向[J].分析试验室,2009,28(3):103-122.FU Ruonong.Advances and trend of capillary GC chromatographic columns in recent two years[J].Chinese Journal of Analysis Laboratory,2009,28(3):103-122(in Chinese).
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[15]FILLION J,HINDLE R,LACROIX M,SELWYNJ.Multiresidue determination of pesticides in fruit and vegetables by gas chromatography mass-selective detection and liquid chromatography with fluorescence detection[J].Journal of AOAC International,1995,78(5):1 252-1 265.
[16]FILLION J,SAUVE F,SELWYN J.Multiresidue method for the determination of residues of251pesticides in fruits and vegetables by gas chromatography/mass spectrometry and liquid chromatography with Xuorescence detection[J].Journal of AOAC International,2000,83(3):698-713.
[17]PANG G F,CAO Y Z,FAN C L.Analysis method study on 839pesticide and chemical contaminant multiresidues in animal muscles by gel permeation chromatography cleanup,GC/MS,and LC/MS/MS[J].Journal of Aoac International,2009,92(3):933-940.
[18]中华人民共和国国家卫生和计划生育委员会,中华人民共和国农业部,国家食品药品监督管理总局.GB 23200.10-2016桑枝、金银花、枸杞子和荷叶中488种农药及相关化学品残留量的测定气相色谱-质谱法[S].北京:中国标准出版社,2016.
[19]中华人民共和国国家卫生和计划生育委员会,中华人民共和国农业部,国家食品药品监督管理总局.GB/T GB 23200.9-2016粮谷中475种农药及相关化学品残留量的测定气相色谱-质谱法[S].北京:中国标准出版社,2016.
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