环氧树脂增韧研究进展
|
摘要
介绍了弹性体、刚性粒子、无机纳米粒子、柔性链段固化剂、核壳结构聚合物及热致性液晶聚合物增韧改性环氧树脂的研究进展,阐述了各增韧剂的增韧机理及其改性环氧树脂的优缺点,最后对环氧树脂增韧改性的研究进行展望。
The research progress in toughening modification of epoxy resin with elastomer,rigid particle,inorganic nanoparticle,flexible chain curing agent,core-shell structure polymer and thermotropic liquid crystal polymer was introduced. The toughening mechanism of various toughening agents and the advantages and disadvantages of modified epoxy resin were described. Finally,the research prospect of toughening modification of epoxy resin was prospected.
The research progress in toughening modification of epoxy resin with elastomer,rigid particle,inorganic nanoparticle,flexible chain curing agent,core-shell structure polymer and thermotropic liquid crystal polymer was introduced. The toughening mechanism of various toughening agents and the advantages and disadvantages of modified epoxy resin were described. Finally,the research prospect of toughening modification of epoxy resin was prospected.
引文
[1]胡传群,万式青.环氧树脂增韧技术进展[J].化工新型材料,2017,45(1):4-6.
[2]常鹏善,左瑞霖,王汝敏,等.环氧树脂增韧改性新技术[J].中国胶粘剂,2001,11(2):37-39.
[3]李文凯.热致性液晶聚合物增韧改性环氧树脂的研究[D].大连:大连理工大学,2016.
[4]邓双辉,李志强,李山剑,等.一种新型增韧剂的合成及其对环氧树脂的改性[J].材料科学与工程学报,2018,36(6):868-873;882.
[5]尹术帮,杨杰,刘新东,等.环氧树脂增韧改性方法及机理研究进展[J].热固性树脂,2013,28(4):46-52.
[6]KOSTRZEWA M,HAUSNEROVA B,BAKAR M,et al.Property evaluation and structure analysis of polyurethane/epoxy graft interpenetrating polymer networks[J].Journal of Applied Polymer Science,2011,122(3):1722-1730.
[7]HSIEH K H,HAN J L,YU C T,et al.Graft interpenetrating polymer networks of urethane-modified bismaleimide and epoxy(I):mechanical behavior and morphology[J].Polymer,2001,42(6):2491-2500.
[8]马收,郭建春.有机粘土/聚醚砜/环氧树脂杂化纳米复合材料的制备和性能[J].材料研究学报,2014,28(10):794-800.
[9]张凌.雷达吸波涂料粘结剂增韧研究[D].武汉:中国地质大学,2003.
[10]ZHAO Y J,HUANG X M,DAI R R,et al.Study on properties of epoxy resin/Al2O3composites[J].Advanced Materials Research,2013(652-654):116-120.
[11]代娟娟.纳米碳酸钙的合成及增韧环氧树脂的研究[D].青岛:中国海洋大学,2012.
[12]LIN Y,CHEN H,CHAN C M,et al.Effects of coating amount and particle concentration on the impact toughness of polypropylene/CaCO3nanocomposites[J].European Polymer Journal,2011,47(3):294-304.
[13]张瑞珠,贾新杰,李林杰,等.环氧树脂的增韧研究进展[J].化工新型材料,2018,46(9):21-24.
[14]曹万荣,符开斌,狄宁宇,等.无机纳米粒子增韧改性环氧树脂的研究进展[J].绝缘材料,2009,42(6):31-35.
[15]黄雷,陈立亚,付继芳.纳米二氧化钛改性环氧树脂的应用研究[J].粘接,2015,24(9):34-38.
[16]GHOSH P K,PATHAK A,GOYAT M S.Influence of nanoparticle weight fraction on morphology and thermal properties of epoxy/TiO2nanocomposite[J].Journal of Reinforced Plastics and Composites,2012,31(17):1180-1188.
[17]强磊,詹航,吴广,等.碳纳米管/环氧树脂原位复合薄膜的制备与性能[J].材料科学与工程学报,2018,36(6):904-910;926.
[18]孔志祥,邹路丝,张洋,等.含柔性链段环氧树脂的合成与性能[J].粘接,2015,24(11):44-47;43.
[19]王熙.新型柔性固化剂的合成与性能表征[J].合成材料老化与应用,2015,44(1):27-33.
[20]孙兰兰.柔性脂肪侧链环氧树脂的合成、结构与性能研究[D].武汉:武汉理工大学,2008.
[21]张凯,郝晓东,黄渝鸿,等.用核壳型聚合物粒子增韧改性环氧树脂[J].化工新型材料,2003,31(12):14-17.
[22]任小明.壳层厚度可控的SiO2-PBA核壳粒子增韧环氧树脂体系临界壳层厚度的研究[D].武汉:湖北大学,2017.
[23]汪源,王源升.不同结构聚合物核壳粒子对环氧树脂的增韧改性[J].高分子材料科学与工程,2012,28(2):23-27.
[24]孙洪秀,吴越,庄伟,等.核壳丙烯酸酯聚合物改性E-51环氧树脂[C].全国第十七届有机和精细化工中间体学术交流会论文集,2011:320-327.
[25]徐晨,武向南,张庆新,等.增韧导热环氧树脂/氮化硼复合材料的制备与表征[J].化工进展,2018,37(12):4752-4757.
[26]肖中鹏,麦堪成,曹民,等.热致液晶聚合物的研究进展[J].广州化工,2013,41(3):9-12.
[27]周桦林,赵利亚,李又兵,等.液晶增韧环氧树脂/聚酯纤维复合材料的制备及性能[J].重庆理工大学学报(自然科学),2017,31(11):74-79.
[28]徐淑权,蔡建,秦旭峰.液晶环氧树脂增韧改性E-51树脂体系性能研究[J].包装工程,2016,37(5):99-102.
[29]赵利亚,周桦林,李又兵,等.LCP增韧EP/GF/PET复合材料的制备及性能[J].工程塑料应用,2017,45(12):29-33.
[2]常鹏善,左瑞霖,王汝敏,等.环氧树脂增韧改性新技术[J].中国胶粘剂,2001,11(2):37-39.
[3]李文凯.热致性液晶聚合物增韧改性环氧树脂的研究[D].大连:大连理工大学,2016.
[4]邓双辉,李志强,李山剑,等.一种新型增韧剂的合成及其对环氧树脂的改性[J].材料科学与工程学报,2018,36(6):868-873;882.
[5]尹术帮,杨杰,刘新东,等.环氧树脂增韧改性方法及机理研究进展[J].热固性树脂,2013,28(4):46-52.
[6]KOSTRZEWA M,HAUSNEROVA B,BAKAR M,et al.Property evaluation and structure analysis of polyurethane/epoxy graft interpenetrating polymer networks[J].Journal of Applied Polymer Science,2011,122(3):1722-1730.
[7]HSIEH K H,HAN J L,YU C T,et al.Graft interpenetrating polymer networks of urethane-modified bismaleimide and epoxy(I):mechanical behavior and morphology[J].Polymer,2001,42(6):2491-2500.
[8]马收,郭建春.有机粘土/聚醚砜/环氧树脂杂化纳米复合材料的制备和性能[J].材料研究学报,2014,28(10):794-800.
[9]张凌.雷达吸波涂料粘结剂增韧研究[D].武汉:中国地质大学,2003.
[10]ZHAO Y J,HUANG X M,DAI R R,et al.Study on properties of epoxy resin/Al2O3composites[J].Advanced Materials Research,2013(652-654):116-120.
[11]代娟娟.纳米碳酸钙的合成及增韧环氧树脂的研究[D].青岛:中国海洋大学,2012.
[12]LIN Y,CHEN H,CHAN C M,et al.Effects of coating amount and particle concentration on the impact toughness of polypropylene/CaCO3nanocomposites[J].European Polymer Journal,2011,47(3):294-304.
[13]张瑞珠,贾新杰,李林杰,等.环氧树脂的增韧研究进展[J].化工新型材料,2018,46(9):21-24.
[14]曹万荣,符开斌,狄宁宇,等.无机纳米粒子增韧改性环氧树脂的研究进展[J].绝缘材料,2009,42(6):31-35.
[15]黄雷,陈立亚,付继芳.纳米二氧化钛改性环氧树脂的应用研究[J].粘接,2015,24(9):34-38.
[16]GHOSH P K,PATHAK A,GOYAT M S.Influence of nanoparticle weight fraction on morphology and thermal properties of epoxy/TiO2nanocomposite[J].Journal of Reinforced Plastics and Composites,2012,31(17):1180-1188.
[17]强磊,詹航,吴广,等.碳纳米管/环氧树脂原位复合薄膜的制备与性能[J].材料科学与工程学报,2018,36(6):904-910;926.
[18]孔志祥,邹路丝,张洋,等.含柔性链段环氧树脂的合成与性能[J].粘接,2015,24(11):44-47;43.
[19]王熙.新型柔性固化剂的合成与性能表征[J].合成材料老化与应用,2015,44(1):27-33.
[20]孙兰兰.柔性脂肪侧链环氧树脂的合成、结构与性能研究[D].武汉:武汉理工大学,2008.
[21]张凯,郝晓东,黄渝鸿,等.用核壳型聚合物粒子增韧改性环氧树脂[J].化工新型材料,2003,31(12):14-17.
[22]任小明.壳层厚度可控的SiO2-PBA核壳粒子增韧环氧树脂体系临界壳层厚度的研究[D].武汉:湖北大学,2017.
[23]汪源,王源升.不同结构聚合物核壳粒子对环氧树脂的增韧改性[J].高分子材料科学与工程,2012,28(2):23-27.
[24]孙洪秀,吴越,庄伟,等.核壳丙烯酸酯聚合物改性E-51环氧树脂[C].全国第十七届有机和精细化工中间体学术交流会论文集,2011:320-327.
[25]徐晨,武向南,张庆新,等.增韧导热环氧树脂/氮化硼复合材料的制备与表征[J].化工进展,2018,37(12):4752-4757.
[26]肖中鹏,麦堪成,曹民,等.热致液晶聚合物的研究进展[J].广州化工,2013,41(3):9-12.
[27]周桦林,赵利亚,李又兵,等.液晶增韧环氧树脂/聚酯纤维复合材料的制备及性能[J].重庆理工大学学报(自然科学),2017,31(11):74-79.
[28]徐淑权,蔡建,秦旭峰.液晶环氧树脂增韧改性E-51树脂体系性能研究[J].包装工程,2016,37(5):99-102.
[29]赵利亚,周桦林,李又兵,等.LCP增韧EP/GF/PET复合材料的制备及性能[J].工程塑料应用,2017,45(12):29-33.