高温钛合金制造技术研究进展
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摘要
高温钛合金制造技术已成为先进航空发动机技术的核心与关键,近年来受到高度重视。在简要回顾新型高温钛合金、阻燃钛合金和Ti-Al系金属间化合物合金发展的基础上,从大规格铸锭熔炼、挤压开坯、整体叶盘模锻、环件轧制及零件机加工等方面介绍这些高温钛合金制造技术研究所取得的重要进展。最后,提出我国高温钛合金应用研究中需要重点关注的问题以及进一步发展的建议。
The manufacturing technology of high temperature titanium alloys,as the core and key of advanced aeroengine technology,is paid great attention recently. The development of new high temperature titanium alloys,fireproof titanium alloys and Ti-Al system intermetallics alloys are briefly reviewed. A comprehensive introduction to the basic situation of the manufacturing technologies,such as,large scale ingot preparing,ingot extrusion breakdown,blisk die forging,ring rolling of these new alloys and research advances therein is given in this work. Key issues need to pay more attention and further development suggestions in application research of high temperature titanium alloys are proposed.
The manufacturing technology of high temperature titanium alloys,as the core and key of advanced aeroengine technology,is paid great attention recently. The development of new high temperature titanium alloys,fireproof titanium alloys and Ti-Al system intermetallics alloys are briefly reviewed. A comprehensive introduction to the basic situation of the manufacturing technologies,such as,large scale ingot preparing,ingot extrusion breakdown,blisk die forging,ring rolling of these new alloys and research advances therein is given in this work. Key issues need to pay more attention and further development suggestions in application research of high temperature titanium alloys are proposed.
引文
[1]黄旭,李臻熙,黄浩.高推重比航空发动机用新型高温钛合金研究进展[J].中国材料进展,2011,30(6):21
[2]王清江,刘建荣,杨锐.高温钛合金的现状与前景[J].航空材料学报,2014,34(4):1-26.
[3]蔡建明,曹春晓.新一代600℃高温钛合金材料的合金设计及应用展望[J].航空材料学报,2014,34(4):27-36.
[4]蔡建明,弭光宝,高帆,等.航空发动机用先进高温钛合金材料技术研究与发展[J].材料工程,2016,44(8):1-10.
[5]蔡建明,李臻熙,马济民,等.航空发动机用600℃高温钛合金的研究与发展[J].材料导报,2005,19(1):50-53.
[6]Mi G B,Huang X,Cai J M,et al.Fireproof property and its mechanism of a new high temperature titanium alloy[C]//Proceedings of the 13th World Conference on Titanium.San Diego:WILEY-TMS,2016:745-751.
[7]曹京霞,黄旭,弭光宝,等.Ti-V-Cr系阻燃钛合金应用研究进展[J].航空材料学报,2014,34(4):92-97.
[8]弭光宝,黄旭,曹京霞,等.Ti-V-Cr系阻燃钛合金的抗点燃性能及其理论分析[J].金属学报,2014,50(5):575-586.
[9]弭光宝,曹春晓,黄旭,等.Ti-V-Cr系阻燃钛合金的非等温氧化行为及阻燃性能预测[J].材料工程,2016,44(1):1-10.
[10]弭光宝,黄旭,曹京霞,等.摩擦点火Ti-V-Cr阻燃钛合金燃烧产物的组织特征[J].物理学报,2016,65(5):056103.
[11]赵永庆,辛社伟,吴欢,等.热处理对Ti40阻燃钛合金热稳定性能的影响[J].稀有金属材料与工程,2008,37(4):660-664.
[12]Zhu Y C,Zeng W D,Zhao Y Q,et al.Effect of processing parameters on hot deformation behavior and microstructural evolution during hot compression of Ti40 titanium alloy[J].Materials Science and Engineering A,2012,552:384-391.
[13]曹京霞,许剑伟,黄旭.中等Nb含量的(α2+O+B2)三相Ti3Al基合金的研究[J].稀有金属,2006,30(专辑1):13-17.
[14]Zhou Y,Cao J X,Huang X,et al.Effects of aging temperature on the microstructure and mechanical properties of a Ti2Al Nb based alloy[J].Materials Science Forum,2016,849:368-375.
[15]卢斌,杨锐.Mo对Ti2Al Nb基合金显微组织和力学性能的影响[J].稀有金属材料与工程,2008,37(增刊3):61-63.
[16]张建伟,李世琼,梁晓波,等.Ti3Al和Ti2Al Nb基合金的研究与应用[J].中国有色金属学报,2010,20(专辑1):336-341.
[17]沈军,冯艾寒.Ti2Al Nb基合金微观组织调制及热成形研究进展[J].金属学报,2013,49(11):1286-1294.
[18]高帆,王新英,王磊,等.变形Ti Al合金全层片组织细化及拉伸性能[J].稀有金属材料与工程,2012,41(10):1846-1850.
[19]He W W,Tang H P,Liu H Y,et al.Microstructure and tensile properties of containerless near-isothermally forged Ti Al alloys[J].Transactions of Nonferrous Metals Society of China,2011,21(12):2605-2609.
[20]杨锐.钛铝金属间化合物的进展与挑战[J].金属学报,2015,51(2):129-147.
[21]孙欢迎,曹京霞,王宝,等.应用加工图技术优化阻燃钛合金高温变形工艺[J].稀有金属材料与工程,2013,42(11):2351-2355.
[22]Cai J M,Huang X,Cao C X,et al.Thermal stability of TG6 titanium alloy and its partial resumption at high temperature[J].Rare Metal Materials and Engineering,2010,39(11):1893-1898.
[23]段锐,张华,蔡建明,等.显微组织对近α型TG6钛合金高温蠕变变形行为的影响[J].中国有色金属学报,2010,20(专辑1):11-15.
[24]赵亮,刘建荣,王清江,等.析出相对Ti60钛合金蠕变和持久性能的影响[J].材料研究学报,2009,23(1):1-5.
[25]Irving B.Sparks begin to fly in nonconventional friction welding and surfacing[J].Welding Journal,1993,72(5):37-40.
[26]姚希珍,胡泽.钛合金整体叶盘线性摩擦焊技术综述[J].航空制造技术,2011(16):43-47.
[27]姚泽坤,梁新民,郭鸿镇,等.热力因素对合金元素在Ti-24Al-15Nb-1.5Mo/TC4焊接界面上扩散规律的影响[J].稀有金属材料与工程,2005,34(6):907-911.
[28]刘莹莹,姚泽坤,杨航航,等.热处理对Ti3Al/TC11双合金盘拉伸性能与组织的影响[J].航空材料学报,2009,29(4):21-26.
[29]Qin C,Yao Z K,Li Y Z,et al.Effect of hot working on microstructure and mechanical properties of TC11/Ti2Al Nb dual-alloy joint welded by electron beam welding process[J].Transactions of Nonferrous Metals Society of China,2014,24(11):3500-3508.
[30]李凯,郭鸿镇,赵张龙,等.变形量对Ti2Al Nb/Ti60双合金焊接接头组织和力学性能的影响[J].热加工工艺,2014,43(9):1-5.
[2]王清江,刘建荣,杨锐.高温钛合金的现状与前景[J].航空材料学报,2014,34(4):1-26.
[3]蔡建明,曹春晓.新一代600℃高温钛合金材料的合金设计及应用展望[J].航空材料学报,2014,34(4):27-36.
[4]蔡建明,弭光宝,高帆,等.航空发动机用先进高温钛合金材料技术研究与发展[J].材料工程,2016,44(8):1-10.
[5]蔡建明,李臻熙,马济民,等.航空发动机用600℃高温钛合金的研究与发展[J].材料导报,2005,19(1):50-53.
[6]Mi G B,Huang X,Cai J M,et al.Fireproof property and its mechanism of a new high temperature titanium alloy[C]//Proceedings of the 13th World Conference on Titanium.San Diego:WILEY-TMS,2016:745-751.
[7]曹京霞,黄旭,弭光宝,等.Ti-V-Cr系阻燃钛合金应用研究进展[J].航空材料学报,2014,34(4):92-97.
[8]弭光宝,黄旭,曹京霞,等.Ti-V-Cr系阻燃钛合金的抗点燃性能及其理论分析[J].金属学报,2014,50(5):575-586.
[9]弭光宝,曹春晓,黄旭,等.Ti-V-Cr系阻燃钛合金的非等温氧化行为及阻燃性能预测[J].材料工程,2016,44(1):1-10.
[10]弭光宝,黄旭,曹京霞,等.摩擦点火Ti-V-Cr阻燃钛合金燃烧产物的组织特征[J].物理学报,2016,65(5):056103.
[11]赵永庆,辛社伟,吴欢,等.热处理对Ti40阻燃钛合金热稳定性能的影响[J].稀有金属材料与工程,2008,37(4):660-664.
[12]Zhu Y C,Zeng W D,Zhao Y Q,et al.Effect of processing parameters on hot deformation behavior and microstructural evolution during hot compression of Ti40 titanium alloy[J].Materials Science and Engineering A,2012,552:384-391.
[13]曹京霞,许剑伟,黄旭.中等Nb含量的(α2+O+B2)三相Ti3Al基合金的研究[J].稀有金属,2006,30(专辑1):13-17.
[14]Zhou Y,Cao J X,Huang X,et al.Effects of aging temperature on the microstructure and mechanical properties of a Ti2Al Nb based alloy[J].Materials Science Forum,2016,849:368-375.
[15]卢斌,杨锐.Mo对Ti2Al Nb基合金显微组织和力学性能的影响[J].稀有金属材料与工程,2008,37(增刊3):61-63.
[16]张建伟,李世琼,梁晓波,等.Ti3Al和Ti2Al Nb基合金的研究与应用[J].中国有色金属学报,2010,20(专辑1):336-341.
[17]沈军,冯艾寒.Ti2Al Nb基合金微观组织调制及热成形研究进展[J].金属学报,2013,49(11):1286-1294.
[18]高帆,王新英,王磊,等.变形Ti Al合金全层片组织细化及拉伸性能[J].稀有金属材料与工程,2012,41(10):1846-1850.
[19]He W W,Tang H P,Liu H Y,et al.Microstructure and tensile properties of containerless near-isothermally forged Ti Al alloys[J].Transactions of Nonferrous Metals Society of China,2011,21(12):2605-2609.
[20]杨锐.钛铝金属间化合物的进展与挑战[J].金属学报,2015,51(2):129-147.
[21]孙欢迎,曹京霞,王宝,等.应用加工图技术优化阻燃钛合金高温变形工艺[J].稀有金属材料与工程,2013,42(11):2351-2355.
[22]Cai J M,Huang X,Cao C X,et al.Thermal stability of TG6 titanium alloy and its partial resumption at high temperature[J].Rare Metal Materials and Engineering,2010,39(11):1893-1898.
[23]段锐,张华,蔡建明,等.显微组织对近α型TG6钛合金高温蠕变变形行为的影响[J].中国有色金属学报,2010,20(专辑1):11-15.
[24]赵亮,刘建荣,王清江,等.析出相对Ti60钛合金蠕变和持久性能的影响[J].材料研究学报,2009,23(1):1-5.
[25]Irving B.Sparks begin to fly in nonconventional friction welding and surfacing[J].Welding Journal,1993,72(5):37-40.
[26]姚希珍,胡泽.钛合金整体叶盘线性摩擦焊技术综述[J].航空制造技术,2011(16):43-47.
[27]姚泽坤,梁新民,郭鸿镇,等.热力因素对合金元素在Ti-24Al-15Nb-1.5Mo/TC4焊接界面上扩散规律的影响[J].稀有金属材料与工程,2005,34(6):907-911.
[28]刘莹莹,姚泽坤,杨航航,等.热处理对Ti3Al/TC11双合金盘拉伸性能与组织的影响[J].航空材料学报,2009,29(4):21-26.
[29]Qin C,Yao Z K,Li Y Z,et al.Effect of hot working on microstructure and mechanical properties of TC11/Ti2Al Nb dual-alloy joint welded by electron beam welding process[J].Transactions of Nonferrous Metals Society of China,2014,24(11):3500-3508.
[30]李凯,郭鸿镇,赵张龙,等.变形量对Ti2Al Nb/Ti60双合金焊接接头组织和力学性能的影响[J].热加工工艺,2014,43(9):1-5.