聚丙烯基木塑复合材料增韧改性研究进展
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摘要
综述了聚丙烯基木塑复合材料(WPC)的配方组成,分析了其传统制备工艺以及当前用于制备该WPC的3种新型工艺,其中亚临界流体辅助反应挤出技术在WPC的制备中是一种全新的制备方法,为制备高性能WPC提供了新途径。
This paper introduced the formulation,compositions and traditional processing methods of wood plastic composites(WPC) and also analyzed the latest three processing technologies,in which the subcritical fluid-assisted reactive extrusion technology was considered as a novel processing method for the preparation of WPC.These technologies provide a new route for the preparation of high-performance WPC.
This paper introduced the formulation,compositions and traditional processing methods of wood plastic composites(WPC) and also analyzed the latest three processing technologies,in which the subcritical fluid-assisted reactive extrusion technology was considered as a novel processing method for the preparation of WPC.These technologies provide a new route for the preparation of high-performance WPC.
引文
[1]Fang L,Chang L,Guo W,et al.Influence of Silane Surface Modification of Veneer on Interfacial Adhesion of Wood-Plastic Plywood[J].Appl Surf Sci,2014,288:682-689.
[2]Ratanawilai T,Nakawirot K,Deachsrijan A,et al.Influence of Wood Species and Particle Size on Mechanical and Thermal Properties of Wood Polypropylene Composites[J].Fiber Polym,2014,15(10):2160-2168.
[3]Petchwattana N,Covavisaruch S.Mechanical and Morphological Properties of Wood Plastic Biocomposites Prepared from Toughened Poly(lactic acid)and Rubber Wood Sawdust(Hevea brasiliensis)[J].J Bionic Eng,2014,11(4):630-637.
[4]Sharma R,Maiti S N.Effects of Crystallinity of Polypropylene(PP)on the Mechanical Properties of PP/StyreneEthylene-Butylene-Styrene-G-Maleic Anhydride(SEBS-GMA)/Teak Wood Flour(TWF)Composites[J].Polym Bull,2015,72(3):627-643.
[5]Nasser R A,Aref I M.The Performance and Properties of Wood-Polypropylene Panels as Affected by Wood Aqueous Extraction[J].Forest Prod J,2014,64(5/6):192-198.
[6]Seo Y W,Kim D S.Effects of Wood Flour Size on the Physical Properties of Polypropylene/Wood Flour Composites[J].Polym-Korea,2014,38(3):327-332.
[7]朱礼智,曹金珍,张艳君,等.毛白杨木粉/聚丙烯复合材料界面相容性的介电弛豫解析[J].复合材料学报.2015,(6):1641-1648.Zhu Lizhi,Cao Jinzhen,Zhang Yanjun,et al.Analysis of Dielectric Relaxation on Interfacial Compatibility of Poplar Wood Flour/Polypropylene Composite[J].Acta Materiae Compositae Sinica,2015,(6)-1641-1648.
[8]Tonoli GHD,Belgacem M N,Siqueira G,et al.Processing and Dimensional Changes of Cement Based Composites Reinforced with Surface-Treated Cellulose Fibres[J].Cement Concrete Comp,2013,37:68-75.
[9]Sobczak L,Steiner M,Schausberger A,et al.PP-based WPCs Influence of the Molar Mass of Matrix and Coupling Agent[J].Polym Composite,2013,34(3):343-353.
[10]Jahani Y.The Effect of Epoxy-Polyester Hybrid Resin on Mechanical Properties,Rheological Behavior,and Water Absorption of Polypropylene Wood Flour Composites[J].Polym EngSci,2007,47(12):2041-2048.
[11]何阳,黄锐,郑德.β晶型聚丙烯研究进展[J].高分子通报,2008,(1):24-32.He Yang,Huang Rui,Zheng De.Advances inβ-forms Polypropylene[J].Chinese Polymer Bulletin,2008,(1):24-32.
[12]祝宝东,张爽,朱泓宇,等.β成核剂含量和退火处理对改性聚丙烯力学性能的影响[J].中国塑料,2015,29(4):93-97.Zhu Baodong,Zhang Shuang,Zhu Hongyu,et al.Influence ofβ-Nucleating Agent Coutents and Annealing Treatment on Mechancal Properties of Modified Polypropylene[J].China Plastics,2015,29(4):93-97.
[13]Lotz B Alpha and Beta Phases of Isotactic Polypropylene:a Case of Growth Kinetics'Phase Reentrency'in Polymer Crystallization[J].Polymer,1998,39(19):4561-4567.
[14]Tjong S C,Shen J S,Li R.Morphological Behaviour and Instrumented Dart Impact Properties of Beta-CrystallinePhase[J].Polymer,1996,37(12):2309-2316.
[15]秦亚伟,郭绍辉,冯嘉春,等.聚丙烯的β晶型及β成核剂的研究进展[J].中国塑料,2006,20(3):7-13.Qin Yawei,Guo Shaohui,Feng Jiachun,et al.Advances inβ-Forms Polypropylene andβ-Nuceating Agents[J].China Plastics,2006,20(3):7-13.
[16]黄浪,王海刚,王清文.β-成核剂对聚丙烯/木粉复合材料结晶与力学性能的影响[J].高分子材料科学与工程,2015,31(1):83-87.Huang Lang,Wang Haigang,Wang Qingwen.Influence ofβNucleating Agent on the Crystallization and Mechanical Properties of PP/Wood Flour Composites[J].Polymer Materials Science&Engineering,2015,31(1):83-87.
[17]李玉林,何培新.高分子合金增韧机理的研究进展[J].高分子材料科学与工程,2002,18(5):26-30.Li Yulin,He Peixin.Advances in Studies on Toughening Mechanisms of Polymer Alloys[J].Polymer Materials Science&Engineering,2002,18(5):26-30.
[18]Keledi G.Tensile and Impact Properties of Three-Component PP/Wood/Elastomer Composites[J].Express Polym Lett,2012,6(3):224-236.
[19]Hristov V N,Vasileva S T,Krumova M,et al.Deformation Mechanisms and Mechanical Properties of Modified Polypropylene/Wood Fiber Composites[J].Polym Composite,2004,25(5):521-526.
[20]Sharma R,Maiti S N.Effects of Crystallinity of Polypropylene(PP)on the Mechanical Properties of PP/Styrene-Ethylene-Butylene-Styrene-g-Maleic Anhydride(SEBSg-MA)/Teak Wood Flour(TWF)Composites[J].Polym Bull,2015,72(3):627-643.
[21]Jonoobi M,Oladi R,Davoudpour Y,et al.Different Preparation Methods and Properties of Nanostructured Cellulose from Various Natural Resources and Residues:A Review[J].Cellulose,2015,22(2):935-969.
[22]张文栓,徐洪霞,杨超,等.纳米粒子增强增韧聚合物的研究进展[J].工程塑料应用,2000,28(6):45-47.Zhang Wenshuan,Xu Hongxia,Yang Chao,et al.Advance in the Research of Polymers Being Reinforced and Toughened by Nano-Particle[J].Engineering Plastics Application,2000,28(6):45-47.
[23]姜锋.木塑复合材料增韧性能的研究[D].北京:中国林业科学研究院,2007.
[24]赫丽华,宁荣昌,孔杰.纳米粒子在聚合物增强增韧中的应用[J].工程塑料应用,2002,30(4):53-55.He Lihua,Ning Rongchang,Kong Jie.Application of Nanoparticle in the Polymer Toughening and Reinforcing[J].Engineering Plastics Application,2002,30(4):53-55.
[25]Chaharmahali M,Hamzeh Y,Ebrahimi G,et al.Effects of Nano-graphene on the Physico-Mechanical Properties of Bagasse/Polypropylene Composites[J].Polym Bull,2014,71(2):337-349.
[26]Nourbakhsh A,Ashori A,Kargarfard A.Evaluation of Multi-walled Carbon Nanotubes as Reinforcement for Natural Fiber-based Composites[J].Polym Composite,2015:3269-3274.
[27]张文杰.硅烷偶联剂对PP基木塑复合材料力学性能的影响[J].科技信息,2013(13):3,30.Zhang Wenjie.Effect of Silane Coupling Agent on the Mechanical Properties of PP-based Wood Plastic Composite[J].Science&Technology Information,2013,(13):3,30.
[28]Rojo E,Virginia Alonso M,Del Saz-Orozco B,et al.Optimization of the Silane Treatment of Cellulosic Fibers From Eucalyptus Wood Using Response Surface Methodology[J].J Appl Polym Sci,2015,132(4215726).
[29]Taghiyari H R,Karimi A,Tahir P M.Organo-Silane Compounds in Medium Density Fiberboard:Physical and Mechanical Properties[J].Journal of Forestry Research,2015,26(2):495-500.
[30]Zhang H.Effect of a Novel Coupling Agent,Alkyl Ketene Dimer,on the Mechanical Properties of Wood-Plastic Composites[J].Mater Design,2014,59:130-134.
[31]Wang K,Wang S,Wu F,et al.A New Strategy for Preparation of Long-Chain Branched Polypropylene via Reactive Extrusion with Supercritical CO_2 Designed for An Improved Foaming Approach[J].J Mater Sci,2016,51(5):2705-2715.
[32]Isayev A I,Kumar R,Lewis T M.Ultrasound Assisted Twin Screw Extrusion of Polymer-Nanocomposites Containing Carbon Nanotubes[J].Polymer,2009,50(1):250-260.
[33]张云灿,沈韦韦,武懿嘉,等.一种亚临界醇挤出应力诱导硫化橡胶粉脱硫化反应的方法:中国,103834058A[P].2014-06-04.
[34]张云灿,武懿嘉,史长平,等.一种亚临界水挤出法应力诱导硫化橡胶粉脱硫化反应的方法:中国,103073741A[P].2013-05-01.
[35]孔维荣,李玉华,武懿嘉,等.亚临界流体挤出法复合诱导EPDM废胶粉脱硫化及动态交联热塑性弹性体制备[J].高分子通报,2015,(3):36-44.Kong Weirong,Li Yuhua,Wu Yijia,et al.Effects of Shear Stress and Subcritical Fluids on Devulcanization of Waste EPDM Rubber and Preparation of Dynamically Crosslinked Thermoplastic Elastomers[J].Chinese Polymer Bulletin,2015,(3):36-44.
[36]沈韦韦,武懿嘉,张云灿.亚临界流体挤出法对天然橡胶基轮胎胶粉脱硫化反应的影响[J].合成橡胶工业,2015,38(3):226-232.Shen Weiwei,Wu Yijia,Zhang Yuncan.Effect of Subcritical Fluids on Devulcanization of Natural Rubber-Based Ground Tire Rubber in a Twin Screw Extruder[J].China Synthetic Rubber Industry,2015,38(3):226-232.
[37]武懿嘉,沈韦韦,张云灿.亚临界流体与高剪切应力对EPDM废胶粉脱硫反应的影响[J].高分子材料科学与工程,2015,31(2):119-123.Wu Yijia,Shen Weiwei,Zhang Yuncan.Effects of High Shear Stress and Subcritical Fluids on the Devulcanization Reaction of Waste EPDM Rubber[J].Polymer Materials Science&Engineering,2015,31(2):119-123.
[38]沈韦韦,怀乐,张云灿.亚临界水挤出法复合诱导丁苯橡胶基轮胎胶脱硫化及其对热塑性弹性体性能的影响[J].中国塑料,2013,(5):87-94.Shen Weiwei,Huai Le,Zhang Yuncan.Effect of High Shear and Subcritical Water on Devulcanization of SBR based Ground Tire Rubber and Properties of Dynamic Vulcanized Thermoplastic Elastomers[J].China Plastics,2013,(5):87-94.
[39]张玲,曹金星,曹明浪,等.一种亚临界醇挤出制备木塑复合材料的方法:中国,105778547A[P].2016-07-20.
[40]李玉华,孔维荣,张玲,等.亚临界水挤出法制备ABS/木粉复合材料力学性能研究[J].中国塑料,2015,29(1):42-47.Li Yuhua,Kong Weirong,Zhang Ling,et al.Mechanical Properties of ABS/Wood Powder Composite Prepared by a Twin-screw Extruder with Subcritical Water[J].China Plastics,2015,29(1):42-47.
[41]张玲,李玉华,曹明浪,等.一种亚临界水挤出制备木塑复合材料的方法:中国,104497471A[P].2015-04-08.
[2]Ratanawilai T,Nakawirot K,Deachsrijan A,et al.Influence of Wood Species and Particle Size on Mechanical and Thermal Properties of Wood Polypropylene Composites[J].Fiber Polym,2014,15(10):2160-2168.
[3]Petchwattana N,Covavisaruch S.Mechanical and Morphological Properties of Wood Plastic Biocomposites Prepared from Toughened Poly(lactic acid)and Rubber Wood Sawdust(Hevea brasiliensis)[J].J Bionic Eng,2014,11(4):630-637.
[4]Sharma R,Maiti S N.Effects of Crystallinity of Polypropylene(PP)on the Mechanical Properties of PP/StyreneEthylene-Butylene-Styrene-G-Maleic Anhydride(SEBS-GMA)/Teak Wood Flour(TWF)Composites[J].Polym Bull,2015,72(3):627-643.
[5]Nasser R A,Aref I M.The Performance and Properties of Wood-Polypropylene Panels as Affected by Wood Aqueous Extraction[J].Forest Prod J,2014,64(5/6):192-198.
[6]Seo Y W,Kim D S.Effects of Wood Flour Size on the Physical Properties of Polypropylene/Wood Flour Composites[J].Polym-Korea,2014,38(3):327-332.
[7]朱礼智,曹金珍,张艳君,等.毛白杨木粉/聚丙烯复合材料界面相容性的介电弛豫解析[J].复合材料学报.2015,(6):1641-1648.Zhu Lizhi,Cao Jinzhen,Zhang Yanjun,et al.Analysis of Dielectric Relaxation on Interfacial Compatibility of Poplar Wood Flour/Polypropylene Composite[J].Acta Materiae Compositae Sinica,2015,(6)-1641-1648.
[8]Tonoli GHD,Belgacem M N,Siqueira G,et al.Processing and Dimensional Changes of Cement Based Composites Reinforced with Surface-Treated Cellulose Fibres[J].Cement Concrete Comp,2013,37:68-75.
[9]Sobczak L,Steiner M,Schausberger A,et al.PP-based WPCs Influence of the Molar Mass of Matrix and Coupling Agent[J].Polym Composite,2013,34(3):343-353.
[10]Jahani Y.The Effect of Epoxy-Polyester Hybrid Resin on Mechanical Properties,Rheological Behavior,and Water Absorption of Polypropylene Wood Flour Composites[J].Polym EngSci,2007,47(12):2041-2048.
[11]何阳,黄锐,郑德.β晶型聚丙烯研究进展[J].高分子通报,2008,(1):24-32.He Yang,Huang Rui,Zheng De.Advances inβ-forms Polypropylene[J].Chinese Polymer Bulletin,2008,(1):24-32.
[12]祝宝东,张爽,朱泓宇,等.β成核剂含量和退火处理对改性聚丙烯力学性能的影响[J].中国塑料,2015,29(4):93-97.Zhu Baodong,Zhang Shuang,Zhu Hongyu,et al.Influence ofβ-Nucleating Agent Coutents and Annealing Treatment on Mechancal Properties of Modified Polypropylene[J].China Plastics,2015,29(4):93-97.
[13]Lotz B Alpha and Beta Phases of Isotactic Polypropylene:a Case of Growth Kinetics'Phase Reentrency'in Polymer Crystallization[J].Polymer,1998,39(19):4561-4567.
[14]Tjong S C,Shen J S,Li R.Morphological Behaviour and Instrumented Dart Impact Properties of Beta-CrystallinePhase[J].Polymer,1996,37(12):2309-2316.
[15]秦亚伟,郭绍辉,冯嘉春,等.聚丙烯的β晶型及β成核剂的研究进展[J].中国塑料,2006,20(3):7-13.Qin Yawei,Guo Shaohui,Feng Jiachun,et al.Advances inβ-Forms Polypropylene andβ-Nuceating Agents[J].China Plastics,2006,20(3):7-13.
[16]黄浪,王海刚,王清文.β-成核剂对聚丙烯/木粉复合材料结晶与力学性能的影响[J].高分子材料科学与工程,2015,31(1):83-87.Huang Lang,Wang Haigang,Wang Qingwen.Influence ofβNucleating Agent on the Crystallization and Mechanical Properties of PP/Wood Flour Composites[J].Polymer Materials Science&Engineering,2015,31(1):83-87.
[17]李玉林,何培新.高分子合金增韧机理的研究进展[J].高分子材料科学与工程,2002,18(5):26-30.Li Yulin,He Peixin.Advances in Studies on Toughening Mechanisms of Polymer Alloys[J].Polymer Materials Science&Engineering,2002,18(5):26-30.
[18]Keledi G.Tensile and Impact Properties of Three-Component PP/Wood/Elastomer Composites[J].Express Polym Lett,2012,6(3):224-236.
[19]Hristov V N,Vasileva S T,Krumova M,et al.Deformation Mechanisms and Mechanical Properties of Modified Polypropylene/Wood Fiber Composites[J].Polym Composite,2004,25(5):521-526.
[20]Sharma R,Maiti S N.Effects of Crystallinity of Polypropylene(PP)on the Mechanical Properties of PP/Styrene-Ethylene-Butylene-Styrene-g-Maleic Anhydride(SEBSg-MA)/Teak Wood Flour(TWF)Composites[J].Polym Bull,2015,72(3):627-643.
[21]Jonoobi M,Oladi R,Davoudpour Y,et al.Different Preparation Methods and Properties of Nanostructured Cellulose from Various Natural Resources and Residues:A Review[J].Cellulose,2015,22(2):935-969.
[22]张文栓,徐洪霞,杨超,等.纳米粒子增强增韧聚合物的研究进展[J].工程塑料应用,2000,28(6):45-47.Zhang Wenshuan,Xu Hongxia,Yang Chao,et al.Advance in the Research of Polymers Being Reinforced and Toughened by Nano-Particle[J].Engineering Plastics Application,2000,28(6):45-47.
[23]姜锋.木塑复合材料增韧性能的研究[D].北京:中国林业科学研究院,2007.
[24]赫丽华,宁荣昌,孔杰.纳米粒子在聚合物增强增韧中的应用[J].工程塑料应用,2002,30(4):53-55.He Lihua,Ning Rongchang,Kong Jie.Application of Nanoparticle in the Polymer Toughening and Reinforcing[J].Engineering Plastics Application,2002,30(4):53-55.
[25]Chaharmahali M,Hamzeh Y,Ebrahimi G,et al.Effects of Nano-graphene on the Physico-Mechanical Properties of Bagasse/Polypropylene Composites[J].Polym Bull,2014,71(2):337-349.
[26]Nourbakhsh A,Ashori A,Kargarfard A.Evaluation of Multi-walled Carbon Nanotubes as Reinforcement for Natural Fiber-based Composites[J].Polym Composite,2015:3269-3274.
[27]张文杰.硅烷偶联剂对PP基木塑复合材料力学性能的影响[J].科技信息,2013(13):3,30.Zhang Wenjie.Effect of Silane Coupling Agent on the Mechanical Properties of PP-based Wood Plastic Composite[J].Science&Technology Information,2013,(13):3,30.
[28]Rojo E,Virginia Alonso M,Del Saz-Orozco B,et al.Optimization of the Silane Treatment of Cellulosic Fibers From Eucalyptus Wood Using Response Surface Methodology[J].J Appl Polym Sci,2015,132(4215726).
[29]Taghiyari H R,Karimi A,Tahir P M.Organo-Silane Compounds in Medium Density Fiberboard:Physical and Mechanical Properties[J].Journal of Forestry Research,2015,26(2):495-500.
[30]Zhang H.Effect of a Novel Coupling Agent,Alkyl Ketene Dimer,on the Mechanical Properties of Wood-Plastic Composites[J].Mater Design,2014,59:130-134.
[31]Wang K,Wang S,Wu F,et al.A New Strategy for Preparation of Long-Chain Branched Polypropylene via Reactive Extrusion with Supercritical CO_2 Designed for An Improved Foaming Approach[J].J Mater Sci,2016,51(5):2705-2715.
[32]Isayev A I,Kumar R,Lewis T M.Ultrasound Assisted Twin Screw Extrusion of Polymer-Nanocomposites Containing Carbon Nanotubes[J].Polymer,2009,50(1):250-260.
[33]张云灿,沈韦韦,武懿嘉,等.一种亚临界醇挤出应力诱导硫化橡胶粉脱硫化反应的方法:中国,103834058A[P].2014-06-04.
[34]张云灿,武懿嘉,史长平,等.一种亚临界水挤出法应力诱导硫化橡胶粉脱硫化反应的方法:中国,103073741A[P].2013-05-01.
[35]孔维荣,李玉华,武懿嘉,等.亚临界流体挤出法复合诱导EPDM废胶粉脱硫化及动态交联热塑性弹性体制备[J].高分子通报,2015,(3):36-44.Kong Weirong,Li Yuhua,Wu Yijia,et al.Effects of Shear Stress and Subcritical Fluids on Devulcanization of Waste EPDM Rubber and Preparation of Dynamically Crosslinked Thermoplastic Elastomers[J].Chinese Polymer Bulletin,2015,(3):36-44.
[36]沈韦韦,武懿嘉,张云灿.亚临界流体挤出法对天然橡胶基轮胎胶粉脱硫化反应的影响[J].合成橡胶工业,2015,38(3):226-232.Shen Weiwei,Wu Yijia,Zhang Yuncan.Effect of Subcritical Fluids on Devulcanization of Natural Rubber-Based Ground Tire Rubber in a Twin Screw Extruder[J].China Synthetic Rubber Industry,2015,38(3):226-232.
[37]武懿嘉,沈韦韦,张云灿.亚临界流体与高剪切应力对EPDM废胶粉脱硫反应的影响[J].高分子材料科学与工程,2015,31(2):119-123.Wu Yijia,Shen Weiwei,Zhang Yuncan.Effects of High Shear Stress and Subcritical Fluids on the Devulcanization Reaction of Waste EPDM Rubber[J].Polymer Materials Science&Engineering,2015,31(2):119-123.
[38]沈韦韦,怀乐,张云灿.亚临界水挤出法复合诱导丁苯橡胶基轮胎胶脱硫化及其对热塑性弹性体性能的影响[J].中国塑料,2013,(5):87-94.Shen Weiwei,Huai Le,Zhang Yuncan.Effect of High Shear and Subcritical Water on Devulcanization of SBR based Ground Tire Rubber and Properties of Dynamic Vulcanized Thermoplastic Elastomers[J].China Plastics,2013,(5):87-94.
[39]张玲,曹金星,曹明浪,等.一种亚临界醇挤出制备木塑复合材料的方法:中国,105778547A[P].2016-07-20.
[40]李玉华,孔维荣,张玲,等.亚临界水挤出法制备ABS/木粉复合材料力学性能研究[J].中国塑料,2015,29(1):42-47.Li Yuhua,Kong Weirong,Zhang Ling,et al.Mechanical Properties of ABS/Wood Powder Composite Prepared by a Twin-screw Extruder with Subcritical Water[J].China Plastics,2015,29(1):42-47.
[41]张玲,李玉华,曹明浪,等.一种亚临界水挤出制备木塑复合材料的方法:中国,104497471A[P].2015-04-08.