二氧化钛纳米管制备及其光催化降解有机物应用研究进展
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摘要
介绍了近年国内外二氧化钛纳米管的几种制备方法,有水热合成法、模板法和阳极氧化法,叙述了二氧化钛纳米管光催化氧化技术在有机污染物降解方面的研究进展。认为今后的研究和发展方向为:优化二氧化钛纳米管光催化反应光谱可利用的范围,提高二氧化钛纳米管的催化活性,探索二氧化钛纳米管光催化氧化降解有机污染物中的优化条件,加强专门针对降解有机污染物的二氧化钛纳米管的研究,进一步的研究反应机理,加强对二氧化钛纳米管在各个领域应用的探索,并转化为实际工程应用。
The preparation methods of titanium dioxide nanotubes, including the hydrothermal synthesis, the template method and anodic oxidation method were described, and the latest research progress of photocatalytic oxidation technology in organic pollutants degradation were summarized. The direction of future research and development focused on the photocatalytic reaction optimization spectral range, improving the catalytic activity of titanium dioxide nanotube, optimization of the conditions of titania nanotube photocatalytic oxidative degradation for organic pollutants and exploration the mechanism of photocatalytic degradation, and the technical studies titania nanotubes in various areas of application and the practical application of the combination.
The preparation methods of titanium dioxide nanotubes, including the hydrothermal synthesis, the template method and anodic oxidation method were described, and the latest research progress of photocatalytic oxidation technology in organic pollutants degradation were summarized. The direction of future research and development focused on the photocatalytic reaction optimization spectral range, improving the catalytic activity of titanium dioxide nanotube, optimization of the conditions of titania nanotube photocatalytic oxidative degradation for organic pollutants and exploration the mechanism of photocatalytic degradation, and the technical studies titania nanotubes in various areas of application and the practical application of the combination.
引文
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[35]王秀芹,李政一.Ti O2对有机磷农药乐果光催化降解的影响[J].安全与环境学报,2008,8(3):82-84.
[36]孙莉,白书立,姜庆叶,等.钆掺杂二氧化钛纳米管光催化降解制药废水[J].工业用水与废水,2013,44(1):49-53.
[37]李迪,李雪瑾,殷伟平,等.难降解有机污染物与葡萄糖的光电催化协同氧化作用[J].环境化学,2013,32(1):37-41.
[38]W Ahn,S Sheeley,T Rajh,et al.Photocatalytic reduction of 4-nitrophenol with arginine-modified titanium dioxide nanoparticles[J].Applied Catalysis B Environmental,2007,74(1/2):103-110.
[2]Carey J H,Lawrence J,Tosine H M.Photodechlorination of PCB's in the presence of titanium dioxide in aqueous suspensions[J].Bulletin of Environmental Contamination and Toxicology,1976,16(6):697-701.
[3]Hoyer P,Formation of a Titanium Dioxide Nanotube Array[J].Langmuir,1996,12:14ll-1413.
[4]Jung J H,Kobayashi H,Kjeld J C van Bonlinel,et a1.Creation of novel hehcal ribbon and double-layered nanotube Ti O2structures using organogel template[J].Chem Mater,2002,14:1445-1447.
[5]Su H L,Dong Q,Han J,et al.Biogenic synthesis and photocatalysis of Pd-Pd O nanoclusters reinforced hierarchical Ti O2films with interwoven and tubular conformations[J].Biomacromolecules,2008,9:499-504.
[6]Chunming Huang,Xueqin Liu,Yanping Liu.Room temperature ferromagnetism of Co-doped Ti O2nanotube arrays prepared by solgeltemplate synthesis[J].Chemical Physics Letters,2006,432:468-472.
[7]田玉明.徐明霞,刘祥志,等.糖葫芦状二氧化钛纳米线阵列的制备及其光催化性能[J].催化学报,2006,27(8):703-707.
[8]李华基,孟翠,薛寒松,等.氧化铝模板法制备Ce掺杂二氧化钛纳米管[J].铝加工,2009(2):8-11.
[9]Brinda B L,Peter K D,Charles R M.Sol-Gel Template Synthesis of Semiconductor Nanostructures[J].Chem Mater,1997,9(3):857-862.
[10]Michailowski A,Aimawlawi D.Highly regular anatase nanotubule arrays fabricated in porous anodic templates[J].Chem Phys Lett,2001,349(1/2):1-5.
[11]李咏,宋伟明,韩雪佳,等.软模板法制备二氧化钛纳米晶及表征[J].人工晶体学报,2014,43(4):924-928.
[12]张青红,高濂,郑珊,等.制备均一形貌的长二氧化钛纳米管[J].化学学报,2002,60(8):1439-1444.
[13]张振江,白书立,王子波,等.氮掺杂二氧化钛纳米管对染料废水的光催化降解性能[J].扬州大学学报:自然科学版,2012,15(1):20-23.
[14]王芹,等.氧化钛纳米管的合成机理与表征[J].材料开发与应用,2004,19(5):9-12.
[15]时金金,郭元茹,潘清江.以碱木质素胺盐为模板制备纳米二氧化钛及其光催化性能研究[J].森林工程,2015,31(3):54-56.
[16]孙艳,闫康平.Ti O2纳米管双室光电化学池光催化制氢的研究[J].无机化学学报,2014,30(12):2740-2746.
[17]Liu J,Liu ZY,Zhang T R,et al.Low-temperature crystallization of anodized Ti O2nanotubes at the solid-gas interface and their photoelectrochemical properties[J].Nanoscale,2013,5(13):6139.
[18]Menendez R,Alvarez P,Botas C,et al.Seltf-organized amorpous titania nanotubes with deposited grapheme film like a new heterostructured eletrode for lithum ion batte-ries[J].J Power Sources,2014,248:886.
[19]石蕊,王敏.含水量对Ti O2纳米管形貌控制参数的影响[J].强激光与粒子束,2015,27(2):1-7.
[20]S K Mohapatra,M Misra,V K Mahajan,et al.A novel method for the synthesis of titania nanotubes using sonoeleetrochemical method and its application for photoelectrochemical Splitting of water[J].Journal of Catalysis,2007,246:362-369.
[21]Xiaobo Chen,Maria Sohriver,Timothy Suen.Fabrication of 10 nm diameter Ti O2nanotube arrays by titanium anodization[J].Thin Solid Films,2007,515:8511-851.
[22]Que Anh Nguyen,Y V Bhargava,T M Devine.Titania nanotube formation in chloride and bromide containing eleetrolytes[J].Electrochemistry Communications,2008(10):471-475.
[23]Thompson T L,Yates J T.Surface science studies of the photoactivation of Ti O2-new photochemical processes[J].Chem Rev,2006,106(10):4428-4453.
[24]Hoffmann M R,Martin S T,Bahnemann D W.Environmental applications of semiconductor photocatalysis[J].Chem.Rev,1995,95(1):69-69.
[25]Fujishima A,Zhang X,Try k D A.Ti O2photocatalysis and related surface phenomena[J].Surf Sci Rep,2008,63(12):515-582.
[26]Xie Y B.Photoelectrochemical application of nanotubular titania photoanode[J].Electrochim Acta,2006,51(17):3399-3406.
[27]Lai Y K,Sun L,Chen Y C J,et al.Effects of structure of Ti O2nanotube array on ti substrate on its photocatalytic activity[J].Electrochem Soc,2006,153(7):123-127.
[28]胡春光,辛言君.Ti O2/Ti纳米管光电极制备及光催化性能研究[J].水处理技术,2015,41(8):58-66.
[29]张忠铭,钟福新,莫德清,等.氮掺杂Ti O2纳米管阵列的制备及其光催化性能[J].化工新型材料,2014,42(7):156-158.
[30]王晨,衣守志,王雯彦,等.Ti O2纳米管光电催化降解酸性橙染料[J].化工环保,2012,32(4):381-385.
[31]冯丽娜,刘勇健.Ti O2/活性炭光催化技术应用于印染废水深度处理的研究[J].应用化工,2009,38(3):392-394.
[32]滕洪辉,张影,宁军博,等.二氧化钛纳米管光催化降解水中百草枯[J].环境工程学报,2014,8(3):816-820.
[33]王平,杨静,史娟华,等.二氧化硅/二氧化钛复合材料合成条件对其处理含氰废水性能的影响[J].有色金属:冶炼部分,2014(1):71-74.
[34]Aungpradit T,Sutthivaiyakit P,Martens D,et al.Photocatalytic degradation of triazophos in aqueous titanium dioxide suspension:Identification of intermediates and degradation pathways[J].Journal of Hazardous Materials,2007,146(1/2):204-213.
[35]王秀芹,李政一.Ti O2对有机磷农药乐果光催化降解的影响[J].安全与环境学报,2008,8(3):82-84.
[36]孙莉,白书立,姜庆叶,等.钆掺杂二氧化钛纳米管光催化降解制药废水[J].工业用水与废水,2013,44(1):49-53.
[37]李迪,李雪瑾,殷伟平,等.难降解有机污染物与葡萄糖的光电催化协同氧化作用[J].环境化学,2013,32(1):37-41.
[38]W Ahn,S Sheeley,T Rajh,et al.Photocatalytic reduction of 4-nitrophenol with arginine-modified titanium dioxide nanoparticles[J].Applied Catalysis B Environmental,2007,74(1/2):103-110.